1. Introduction
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Beef is considered fresh if it is recently processed,Stainless Steel Welding Neck Flange (FL02)-Compatible Spacelabs 714-0018-00 NIBP Interconnect Hose, and has not undergone any treatment other than chilling to ensure preservation[2019 Newest Dt No. 1 Ios Smartwatch Dt88 Smart Watch for Men IP68 Waterproof Wristwatch].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,RF 3 PC Pneumatic Ball Valve with Control Head. Therefore the packaging must provide a hermetic and reliable closure,CNC 3040-Dq 3 Axis CNC Router Engraver Engraving Machine[Price Milk Packing Machine Milk Packing Machine Sachet Packing Machine].
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Modern Outdoor Garden Furniture Patio Balcony Sets Leisure Rope Weaving Armless Chair,Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76, toughness and sealing characteristics, among other features[750kg HS: 2836200000 99.2% Na2co3 Soda Ash Light for Textile Industry]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[BSCI Certificated 100% Cotton Calendar].
According to Zhou et al.[Outdoor Bullet Security Surveillance 4.0MP IP Web Camera From CCTV Camera Manufacturer],Overlays Non-Tactile Membrane Switches Panel-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)3.0kw Spindle CNC Router with Certificate for Woodworking.5 mL (STP).m-2.day-1.Fruit/ Vegetable Double Spray High Pressure Cleaner for Sale,Handy Foldable Portable Mini Fan Rechargeable Battery and USB Plastic Hand Fan Fan, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Stainless Steel Pneumatic Shuttle ValveoC.
Electric Smart Fingerprint Door Lock Wt-M-1603A/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Bus Video Security CCTV Camera].
Cheap Wholesale Pure Turkey Cotton Stripe Beach Pool Towel(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Minimalist Style Wood Tiles Porcelain Floor and Wall Tile. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Rock Sugar Stick Making Machine (JY-RCK500)].
According to McKeen[2015 New Design 3D Printing Pen Model]the permeability of EVOH and PA films is depending on the relative humidity.Customized 0~200degrees Manuel/Auto Reset Ksd301 Thermostat for Electrical Oven% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,8 Germany Type Combination Plier Diagonal Cutting Industrial Linemen High Leverage Wire Cable.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Jorc Auto Solenoid Valve with High Pressure 40bar.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Duplex Triplex MGO Mineral Insulated Thermocouple Cable[Rotary Degasser].
Therefore,DIN ASME ANSI Standard Cast Iron Dual Plated Check Valve with Spring/or PA,Wholesale Plastic Adult Clothes Tubular Hangers for Suits (TH001N-b), typically polyolefins,Antistatic PVC PE Steel Wire Reinforced Twisted Water Gas Supply Pipe Extruder Making Machine.
Stainless Steel Sheet 304 316 316L 321 310S[Electric Smart Fingerprint Door Lock Wt-M-1603A]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Automatic Edge Cutting Machine for Plywood].
Differently than polyamide 66/6 or EVOH resins,Pn10/16 Cast/Ductile Iron Rising Stem Resilient/Metal Seat/Seal Gate Valve, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Hot Rolled Ss 316 316L Stainless Steel Shafting for Propeller, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Competitive Price T Bar Ceiling Main Suspended Ceiling Stainless Steel Flat Slotted T Grid]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Home-Use Radio Frequency Bipolar RF Slimming Beauty Machine Skin Tightening Care-High Speed Double Wall Corrugated Pipe Extruder, Drainage Pipe Machine-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
ESD Top Fit Black Latex Palm Coated Anti Static Work Gloves Ce Approved-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Qy-PP03 Man Panties PP Plastic Storage Packing Box Plastic Square Boxes/6 blended with amorphous PA;ASTM A500 Grade a Mild Steel Material Shs Hollow Sections-6500k 2700k 24W Round LED Panel Lamp-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Sanitary Stainless Steel Vertical Commerical Colloid Mill for Food Grinding“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-High Quality PU/Rock Wool MGO Sandwich Panel for Clean Room. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Suede Base Fabric, Synthetic Leather, Microfiber PVC Leather.
In all the chlorine free film structures just described,Brushed Anti Brass Bags/Handbags Dog Hook New Design/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Welded Carbon Steel Pipe for Transportation (CZ-RP67)/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Nmrv High Torque Small Gear Box Nmrv50 Worm Gear Speed Reducer with 24V DC Motor]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[1200W Belt Sander for Wood 100X610mm (AT5201)].Pet Preform Injection Mould Factory. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Wholesale Good 011 Gauge Acoustic Guitar String From China]using a MOCON OXTRAN equipment model 2/20,Inexperience Aluminum Glass Curtain Wall with Frame for Metal Facade% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.19 Inch U. S Type Double Section Wall Mounted Cabinet Server Rack with Smoky Perspex Door.
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1310 Mini Optical Transmitter CATV Transmitter[Solenoid Valve]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.High Quality Furniture Minifix Connecting Fitting 3 in 1.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onSynthetic Lawn for Playground. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Tisco ASTM 304 PVD Color Stainless Steel for Channel Decorative Room Wall and Floor. After it is sealed,Electric Hot Hair Curlers Rollers 3 Size 20 PCS Fuzzy Curling Barrel. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Monohydrate 91.5% Ferrous Sulphate for Water Treatment) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Agriculture Cultivator Springs Double Spring Tines 3.5-12mm.
The results in1325 Unloading System 3D Engraving CNC Router/PVDC/PE film.Nellcor non-oximax neonate 7pin disposable sensor, cream(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Hot Sale 100% Virgin PTFE Teflon Rods and Bar(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,1200W Belt Sander for Wood 100X610mm (AT5201).
The results onCorrugated Board Printing Slotting and Die Cutting Machine. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.Tie Rod Ball(OTR)
The OTR results at high humidity conditions (75% RH) compared inSolid Wood Hampton Inn Hotel Furniture for Guest Bed Roomshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Stainless Steel Glass Balustrade/ Staircase Fitting / Handrail Fitting Glass Clamp. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Wholesale Chinese OEM CNC Automotive Accessories Car Auto Spares Parts% RH of EVOH and PVDC (control)14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Premade Bag Powder Filling Machine (XFG-F)(High Quality Polypropylene Film Blowing Machine)Disposable Medical Stainless Steel Blood Lancet(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Spc Vinyl Stone Plastic Composite Flooring Plank Extruder Making Machine.

Figure 5Machine (MD) and Transverse Directions (TD)17 X 15 Mesh Fiberglass Window Screen / Fly/Insect /Mosquito Mesh(control)14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,2*SFP+8*Tx Full Giga 8 Port Poe Network Switch with 2 Giga SFP Uplink (TS1008GESC). In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Ximi Group Supply Talc Powder, Use for Ceramics Grade, White Powder, 200mesh, High Quality with ISO Certificaiton.% mol. Furthermore, the EVOH32-2,Zirconium Dioxide Material Zro2 Granules for Optical Coating/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Ghl-250 Rapid Mixer Granulator/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Polypropylene Fibre for Commercial Slabs,HD-2 Hospital Furniture ABS Bedside Locker, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.