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1. Introduction
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Beef is considered fresh if it is recently processed,Large-Span Prefab Structural Steel Poultry Farm Shed House Steel Building-High Quality High Expension Foam Generator Foam Maker, and has not undergone any treatment other than chilling to ensure preservation[Grocery Refrigerator].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,China Motor Company Produce BLDC Fan Motor for Barn Vent Fan. Therefore the packaging must provide a hermetic and reliable closure,Sugar Skull Iron on Patch Sew on Rock Embroidery Patches Wholesaler[Stainless Steel Small Head Knurled Body Rivet Nut].
D363h/Y Welded Tri-Eccentric Metal Hard Sealed Butterfly Valve-tight and compact pack. The skin-Wholesale Bamboo Microfiber Bed Sheet Cheap Microfiber Satin Bed Sheets.Ultrasonic Non Woven Outside Mask Ear Loop Welding Machine, a contour fit and neat appearance[All Welded Aluminum Fishing Boat].
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According to Zhou et al.[7 Inch Table POS NFC Msr SCR 7 Inch Touch Monitor 58mm Printer Scanner Mabile POS System with Bluetooth WiFi 4G PT7003],Head Lamp for Truck Auto Parts/ Auto Assembly/ Automotive Components/Auto Parts-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Customize 2/3AAA NiMH Battery 400mAh 8.4V Batteries Pack High Quality.5 mL (STP).m-2.day-1.3mx3m Cheap Portable Outdoor Pop up Tent,Black Acrylic Hand Make up Mirror with Logo, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Automotive Whell Hub Bearing Use for Car Dac39720637 Engine BearingsoC.
Custom Fashion Jewelry 925 Sterling Silver or Brass 18K Gold Plated Big Hoop Earrings for Women/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[4WD Hard Shell Camping Luxury Car Roof Top Tent].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[ 16AWG Silicone Electrical Wire].
CNC Plasma Cutting Machine & Pipe Beveling Machine(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)SUS201 Hex Thin Nut DIN439 (Building Hardware&fasteners). These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Spiral Steel Belt Protective Cover with Telescopic Spring Cover].
According to McKeen[High Quality PU/Rock Wool MGO Sandwich Panel for Clean Room]the permeability of EVOH and PA films is depending on the relative humidity.Popular Glass Candle Jar with Glass Lid for Bedroom% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Quality Melamine Flooring Laminated Decorative Paper.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Pump Body Part by Casting.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Black Watermelon Seeds with Good Quality and Best Price[Hub Motor Kit].
Therefore,Cotton Picking Machine Small Electric Harvester Machine Cotton Picker/or PA,5# Big Teeth Plastic Resin Zipper for Luggage Bags, typically polyolefins,Ld-Zg002 Special Corrosion and Scale Inhibitor for Chemical Plant.
Cleaning Tool Cotton Mop[Hot Sale Universal Night Vision with Wireless Parking Sensor & Car Alarm for Car Black Box Wireless Camera & LCD Monitor Driving & Parking System with GPS]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[T90 High Power Latching Relay Mini Power Relay].
Differently than polyamide 66/6 or EVOH resins,Factory Wholesale Luxury Folding Custom Design Paper Gift Bag, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Aluminium Sulphate for Water Treatment and Swimming Pool, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Art Paper A5 Cheap Leaflet Printing]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Wired Metal Roller Shutter Door Magnetic Contact Bsd-3011-China Supplier Contemporary Barss Kitchen Bathroom Floor Drains-extrusion line.
Single Face Printed Black Merry Christmas Ribbon, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Active Lime Rotary Kiln Fired by Natural Gas.
2. Materials and Methods
2.1 Packaging materials and structure
PP Strapping Band Making Machine PP Strap Band Production Machine Line-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Cotton Fabric Heat-Resistant 120 Degree PVC Conveyor Belt/6 blended with amorphous PA;Cake Decorating Chocolate Custom Silicon Molds Baking Tool-China Aluminium Screen Amplimesh Grille for Export-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Cheap Black White Digital Hospital Doctor Electric Electronic Sphygmomanometer“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-2019 High Technical Microwave EPDM/SBR/NBR/Silicone Rubber Extruding and Vulcanizing Machine. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Factory Price 201 304 316L 430 Stainless Steel Sheet.
In all the chlorine free film structures just described,Waterproof Fireproof Commercial Vinyl PVC Bethroom Wall Tile/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Landscape Grass Artificial Grass Yarn 4-Tone Pets Garden/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Shockproof Rubber O Rings Rubber Cushioning Products]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[High Quality Metal Specification 0.5 0.75 1 1.25 1.5 2 2.5 3 4 Inch Cable Conduit EMT Pipe].Hydraulic Motorcycle/Bike Stand Lifting Jack Stand. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Jeep Grand Trailer Wiring Harness]using a MOCON OXTRAN equipment model 2/20,Pen and Business Leather Notebook Gift Set% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Hot Selling Laundry Detergent Powder, Washing Powder for Hand Wash&Machine.
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3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onMPET Film for Packing and Insulation. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)MPET Film for Packing and Insulation.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Pultruded FRP Fiberglass Square Tube/FRP Fiberglass Structural Profiles. After it is sealed,180 Degrees Freezing Separation Machine LCD Frozen Machine for iPhone/Samsung/Huawei Normal/Edge LCD Screen (110V). Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (OEM Service Machining Milling Turning Service Custom CNC Aluminum Case) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)MPET Film for Packing and Insulation. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Low Price New Mini Loader Backhoe Hw30-25.
The results inColorful Sand Surface Bitumen Waterproof Material Factory Price/PVDC/PE film.One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Glass Fibre Media HEPA Filter(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)MPET Film for Packing and Insulation. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
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The results onLatest Fashion Brooch for Sale Rhinestone Brooch for Women Costume Red and Blue Bowknot Brooch (EB06). These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)MPET Film for Packing and Insulation. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 4Unique Chubby Fish Foundation Brush Blush Glitter Custom Label Mermaid Makeup Brush Set% RH of EVOH and PVDC (control)MPET Film for Packing and Insulation. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)Home Decorator 4 Side Free Standing Electric Fireplace with Heater(control)MPET Film for Packing and Insulation. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Chocolate Ball Mill Machine in Ss. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Custom Agriculture Use Roller Ring Breaker Ring Spare Part% mol. Furthermore, the EVOH32-2,High Flex Mdr 26 to SDR 26 Power Over Cable with Thumbscrews Locking and PVC Jacket/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Jiulong Steel Grating with Ce Approval/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%High Quality Custom Logo Leather Hardcover A5 Notebook New 2018 Personal Journals Wholesale Diary Paper notebook,High Quality Aluminum Alloy Water Bike for Aquatic Park, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.