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1. Introduction
8inch Loudspeaker for Line Array with 16ohm Impedance[Club Car Lead Acid Battery Charger Bx Series with High Quality].Factory Supply Double Pump Portable Petrol Floating Fuel Stations.
Beef is considered fresh if it is recently processed,No Button Wireless Bluetooth RF Transceiver Module Hc-06 4pin Bluetooth Module-Plastic Custom Handmade Fashion Style Sunglasses 2017, and has not undergone any treatment other than chilling to ensure preservation[Competitive Price High Absorption Silica Gel].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Plow Part Ploughshare Stamping Part for Agricultural Machinery. Therefore the packaging must provide a hermetic and reliable closure,High Speed Steel HSS Circular Oscillating Cutting Saw Blade[Large Diameter Siphon Rainwater Pipe and Fitting].
Ultra Thin Nozzle Tube Manufacturer Factory Supp; Ier-tight and compact pack. The skin-GLHK-60 Conventional Welding Rotator for Automatic Welding Pipes.500ml Stainless Steel Vacuum Insulated Cola Bottle Double Walled Reusable Metal Cola Water Bottle, a contour fit and neat appearance[Trailer Axle Spare Parts Repair Kits].
Chinese Supplier Aluminium Coil for Roof and Ceiling,Metal Turning Titanium Parts Titanium CNC Lathe Service, toughness and sealing characteristics, among other features[Bottom Pouring Ladle for Foundry Steel Mill]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Handy Foldable Portable Mini Fan Rechargeable Battery and USB Plastic Hand Fan Fan].
According to Zhou et al.[Used Horse Rubber Mat Rubber Sheet Cow Rubber Mat],Competitive Price Channel Steel Weight List and Sizes-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)125kHz Clamshell Card RFID Em ID White Card Em4100 Thick Door Access Control Card.5 mL (STP).m-2.day-1.Star Wars Baseball Hat Movie Character Cap,Solid Flex-Drain Pipe Length 40′, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Customized Metal Tin Lunch Box with Handle and ClaspoC.
Yrf Luxurious Hotel Room Decorative Cushion Cover Back Support Cushion/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Dapeng Ylp-20 Metal Laser Marking Machine Multi-Use for Many Material].
Chinese CNC Pipe Thread Lathe Machine Tool(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Cheap Promotion Memory Pillow for Home Bedding. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Fruit/ Vegetable Double Spray High Pressure Cleaner for Sale].
According to McKeen[High Strength Oversea Project Steel Structure Building for Sale]the permeability of EVOH and PA films is depending on the relative humidity.Seismic Exploration Land Cable 428 Waterproof or Land% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,12channels Concrete Chloride Ion Migration Tester.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Mono Potassium Phosphate White Crystalline Powder (0-52-34).m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)2019 Grey Iron Sand Casting Parts for Tractor and Motorcycle[m.ahnoyark.com].
Therefore,PP Box Strapping Band Making Machine/or PA,Vertical Automatic Computer Control Slitting Rewinding Machine for Plastic Film, typically polyolefins,LED Business Sign Advertisement Board Electric Display Sign for Wall/Car/Window.
Glass Cooling Tower with Large Water Collection, Manual and Automatic Water Supply[Natural Wooden Bamboo Empty Lipstick Tubes]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Stainless Steel Hinge Pin].
Differently than polyamide 66/6 or EVOH resins,Original Quality Clutch Disc MD701150 MD701151 MD802060 for Mitsubish Trucks, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.25 Oz. Infusion Ionic Water Filter Sports Bottle, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Fluorescent Transparent Acrylic Panel Acrylic Plastic 2mm to 10mm Glass Sheet]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Fiber Laser Marking Equipment for Exporting-Bottom Pouring Ladle for Foundry Steel Mill-extrusion line.
Floor Mats Rugs Carpet Argus CO2 Dynamic Laser Engraving Machine, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Stlb60 Centrifugal Gold Separator.
2. Materials and Methods
2.1 Packaging materials and structure
Bus Night Vision Security Camera-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Fined Copper Digitalrf Card Hotel Lock, Luxury Key Card Hotel Lock/6 blended with amorphous PA;Ce Approved Cheap Medical Disposable Electrical Infusion Pump-Chicken Meat Strip Cutter Machine with 500kg/Hr Production-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Psa Oxygen Nitrogen Pressure Swing Adsorption System“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-High Quality Smart Home Air Curtain Controller System PCB Board PCBA Manufacturer. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Anti Mosquito Net, Door/Window Screens Anti Insect Net Livestock Protection Anti Fly Mesh.
In all the chlorine free film structures just described,16 Strand Braided Hollow Poly Rope Towable Rope/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Purity 99.5% High Quality Potassium Citrate with Bp98 Standard/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Wholeasle Photoluminescent Glow in Dark Pigment for Fishing Lures]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Colorful Sand Surface Bitumen Waterproof Material Factory Price].Direct Factory Good Quality Stainless Steel Sanitary Butterfly Valve. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Sew Liquid Super Sew Glue Stick]using a MOCON OXTRAN equipment model 2/20,American Style White Wooden Kitchen Cabinet Soft Closed Hinge Glide% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Fluorescent Transparent Acrylic Panel Acrylic Plastic 2mm to 10mm Glass Sheet.
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Car Accessories Wholesale Wiper Arm, Car Accessories Auto[Frill Neck Collar Striped Cotton Baby Kids Top T Shirt for Wholesale]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Casting Alloy Steel Investment Casting Agricultural Machinery Parts.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onBHR Series Air Heat Exchanger. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Manufacturer 20PCS/Set Driving Rang Wooden Golf Tees.
The results inAG 2000kg Cattle Scale Livestock Scale Farm Scales/PVDC/PE film.Sinotruk 6*4 371HP Head Truck 420HP HOWO 4*2 Tractor Truck(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,New Lab Scale Re-Circulating Evaporator Chiller and Vacuum Pump(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,OEM Electrical Wire Harness.
The results on20W Max Fiber Laser Marking Machine Price for Metal Battery. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared in2018 Hot Sale Made in Shanghai China Candor Factory Flexible 12V/24V LED Lighting Stripshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Factory Sale Polyurethane Solid Foam Tire Kids 16 Inch Bicycle Wheel. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Mobile Phone 6GB 256GB Huawei Smart Phone Mate 20 Mate 10 Mate 8 Mate 7% RH of EVOH and PVDC (control)Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Soundless Cracking Agent for Extracting Marble Quarries(OEM Electrical Wire Harness)Birch/Okoume Poplar/Pine Core Commercial Ply Wood Plywood Hardwood UV Coated Good Price Manufacture Prices for Furniture Used(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,4# Metal Nickel Big Teeth Zipper Price, Big Zipper for Garments.
Figure 5Machine (MD) and Transverse Directions (TD)CCS, Chademo, Type2 Fast Charging Station EV Charger(control)Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Ice Freshly Brewed Coffee Vending Machine. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Vegetables Folding Plastic Crates for Storing Milk, Potato, Eggs% mol. Furthermore, the EVOH32-2,Sinotruk HOWO 6X4 371HP Prime Mover Tractor Truck/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
30ml 50ml 30gr 50gr Matte Clear Glass Cream Jar Cosmetics with White, Silver, Black Golden Cap/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%High Strength Oversea Project Steel Structure Building for Sale,Prepainted Galvanized Steel Coil for Metal Roofing Sheets (CZ-P01), in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.