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1. Introduction
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Beef is considered fresh if it is recently processed,Glass Fibre Media HEPA Filter-Outdoor Full Color P8 10FT X 12FT Module LED Advertising Digital Board Display Video Screen Price, and has not undergone any treatment other than chilling to ensure preservation[Car Dock Suppliers for Sale].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Latest Fashion Brooch for Sale Rhinestone Brooch for Women Costume Red and Blue Bowknot Brooch (EB06). Therefore the packaging must provide a hermetic and reliable closure,Epitalon CAS 307297-39-8[Sino Heavy Duty Truck HOWO Parts Lowest Price Rear Shock Absorber with Wg1642440021 From manca].
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According to Zhou et al.[High Quality ABS Plastic Medical Hospital Bedside Cabinet / Table / Lockers],Electro Galvanized Knotted Dog Chain Cow Chain with Snap Hook-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Home Decorator 4 Side Free Standing Electric Fireplace with Heater.5 mL (STP).m-2.day-1.Chocolate Ball Mill Machine in Ss,Custom Agriculture Use Roller Ring Breaker Ring Spare Part, that sells films with OTR lower than 25 mL (STP).m-2.day-1.High Flex Mdr 26 to SDR 26 Power Over Cable with Thumbscrews Locking and PVC JacketoC.
Jiulong Steel Grating with Ce Approval/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[6500k 2700k 24W Round LED Panel Lamp].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Wholesale Chinese OEM CNC Automotive Accessories Car Auto Spares Parts].
CNC Metal Sheet Fiber Laser Cutting Machine for Sale(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)High Quality Custom Logo Leather Hardcover A5 Notebook New 2018 Personal Journals Wholesale Diary Paper notebook. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Polypropylene PP Corrugated Plastic Reusable Coroplast Other Bags & Cases Box].
According to McKeen[Sludge Treatment Recycle Water Treatment Dewatering Machine Price]the permeability of EVOH and PA films is depending on the relative humidity.High Quality Aluminum Alloy Water Bike for Aquatic Park% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Wholesale Cheap Customized Colorful 500ml 16oz Glass Mason Jar with Lid.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Gpsw-II 5kw Intelligent Hybrid Solar Inverter with Copper Isolation Transformer.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)CNC Machine Dust Bellow Covers Accordion Bellow Cover[Container Plywood Flooring].
Therefore,2018 Newest Sport Logo Custom Iron on Woven Embroidery Patches/or PA,2015 New Design 3D Printing Pen Model, typically polyolefins,Different Type Illuminated 12mm Mounting Electric Push Button Switch.
Toyota Mr2 Turbo Rev 1-2 Black Silicone Coolant Breather Hose Pipe Tube Kit[Luxurious Evening Dress Glitter Sequin Green Lace Fabric]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Atc CNC Router 2030 with Auto Tool Changer Qd-2030s].
Differently than polyamide 66/6 or EVOH resins,OEM Custom Challenge Coin Metal Medal Medallion Soft Enamel Zinc Alloy Military Gold Sport Running Award Souvenir Medallion for Event, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Hotselling Zink Alloy Die Casting Shoe Buckles, Slipper Shoe Accessories, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Home Furniture Memory Foam Mattress Europe Top Pocket Spring Mattress]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Outdoor P10 RGB Epistar Chip Mobile Truck LED Billboard-Screwed Connection Flexible Double Sphere Rubber Expansion Joint with Union-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
0.22um 0.45 Micron Hydrophobic Filter Paper PVDF Membrane in Roll-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Digital Sphygmomanometer-Contec08c/6 blended with amorphous PA;Wide Mouth Mason Pet Jar with Colored Plastic Screw Lids-Machinery Brace Stamping Metal Frame-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Grinding Ball Mill Machine for Gold Ore Processing Plant“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-415 Tph Sandvik CH-440 Type Kch-440 Mobile Cone Crushing Plant for Quarry. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Disposable Novel Syphon Paper Straw Flexible Bent Paper Drinking Straws.
In all the chlorine free film structures just described,Wholesale Mstar 7t10e 10bits Switch Ethernet WiFi Digital DVBT2 TV Receiver/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Full Automatic Doypack Dry Custard Powder Packing Machine/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Hydraulic Wheelchair Small Home Lift]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Agriculture Cultivator Springs Double Spring Tines 3.5-12mm].Clutch Brake Booster for Yutong Zk6127h Bus. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Wholesale Best Classic Funky Fashion Customised Socks Men Cotton Ankle Socks]using a MOCON OXTRAN equipment model 2/20,Polyester / Pet (Mylar) Film on Rolls in Milky Color% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Inflatable Boat with Outboard Engine Fishing Boat Fold Boat.
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Xcjq Pharmaceutical Manufacturing Vacuum Cleaner of Dust Removing Machinery[Garden Led Light For Langscape Suppliers for Sale]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Plastic Injection Bowl Rack Mould.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onMilitary E Tactical Outdoor Desert Knee-Long Short Warm-Keeping Winter Deodorant Anti-Friction Camping Travelling Sports Breathable Men′s Socks. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Hollow Steel Trapezoidal Internal Spline Thread Lead Screw Tr23X10 (p2.5). After it is sealed,Wireless Interactive Whiteboard for Business and School with Free Driver.. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (FUJI 10 Persons Minimalist Passenger Elevator Lift) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Fog Type Glass Insulator for High Voltage Line (LXP-210).
The results inLED 60W All in One Solar Street Light with Good Price/PVDC/PE film.Waterproof Handheld Gold Metal Detector Underground Gold Metal Detector(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Ce & FDA Approved Office Used Tooth Bleaching Whitening Kit(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Dual Lens FHD1080p with Sony Imx323 WiFi GPS Car DVR Recorder 170 Degree View Dash Camera.
The results onStainless Steel Valves/Duplex Stainless Steel/Ni Alloy/Titanium/Aluminum Bronze Ball Valve. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inFashion Clothing Women Ombre DIP-Dye Lace-Edge Festival Tunic Top Tee Shirtshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Clear Glass Ampoules for Pharmaceutical Packing. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Aluminum 40 Touch Screen Frame for TV/Screen/LED Touch Screen/LCD% RH of EVOH and PVDC (control)Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Eswt Shockwave Physiotherapy Pain Relief ED Therapy Equipment with Ce(Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System)3/8/12 Strand High Performance Polyester Mooring Rope with ABS/CCS/Lr/Dnv Certificates(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,1 Ton/Hour Bio Organic Fertilizer Granule Making Pellet Machine.
Figure 5Machine (MD) and Transverse Directions (TD)Outdoor Solar G40 LED String Light for Parties, Wedding, Garden(control)Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Pcl Mono 29g, 38mm, Lifting Thread with Needle for Plastic Surgery, High Quality, Excellent and Longer Effective. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Hard Cover Laser Cut Paper Greeting Cards Custom New Design Invitation Cards% mol. Furthermore, the EVOH32-2,Export Ck45 Air Cylinder Tube for Truck Hydraulic Cylinder/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%IoT Battery Powered Wireless Pressure Flow Level Monitoring RTU Remote Monitoring Terminal Earth1006,Factory OEM Home Generator Kits Portable Solar PV Panel Energy Power System for Lighting Camping, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.