1. Introduction
Antibacklash Ball Screw End Machined Bk/Bf12 End Support Fixed Unit[8inch Loudspeaker for Line Array with 16ohm Impedance].From Chongqing by Great Manufacturer Excellent Extrusion and Stamping Die.
Beef is considered fresh if it is recently processed,18kw Electric Iron Steam Generator-PP Plastic Bag, Rice Bag, and has not undergone any treatment other than chilling to ensure preservation[Uv Coating Wall Panel].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Disposable Blood Collection Lancet of Various Sizes. Therefore the packaging must provide a hermetic and reliable closure,Servo Motor H Frame Hydraulic Deep Drawing Press Machine for Metal Pot Making[Top Quality Multi-Wall Hollow Sheet& Sun Sheet-Hst].
Circular Type Scraps Magnetic Lifter for Steel Mills MW5-110L/1-tight and compact pack. The skin-House Indoor Light Chandelier Pendant Lighting for Decoration.3800kg Halal Cow/Cattle/Beef Slaughter 2.2kw Safety and Efficiency Slaughter Equipment, a contour fit and neat appearance[CNC 3040-Dq 3 Axis CNC Router Engraver Engraving Machine].
Person Passenger Small Size Machine Roomless Home Lift Villa Elevator,Pulse Lavage System OEM Bone Joint Operation Orthopaedic Basic Instruments, toughness and sealing characteristics, among other features[Wholesale 100W 200W 300W 400W 500W LED Floodlight]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[ Shredder for PVC Plastic].
According to Zhou et al.[Rsm-Prt (N) Low Strain Pile Integrity Test],150-250tph Double Roll Crusher for Limestone/Cement/Coal (2PGC1200X1500)-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Intelligent Top Sale Addressable Audio/Visual Alarm (640-004).5 mL (STP).m-2.day-1.(manual available) Arcade Fish Hunter Casino Fishing Slot Game Machine for 8 Players,Simple Design Dog Grooming Brush Tool Pet Rake Combs for Long Hair, that sells films with OTR lower than 25 mL (STP).m-2.day-1.military IP68 waterproof connector INT-EGG. 1K. 2K. 3K. 308.310.314. CLL. CLNoC.
Exterior Fireproof Decorative Wood Plastic Composite WPC Wall Panel/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Automatic Commercial Cube Ice Machine Maker Ice Making Machine].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Suede Base Fabric].
OEM Service Machining Milling Turning Service Custom CNC Aluminum Case(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Hanging Board for Oblique Exterior Wall. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[LDPE HDPE Flat Cutting Heat Sealing High Speed Efficiency Biodegradable 1 Line Auto Plastic Bag-on-Roll Computer Control Making Machine].
According to McKeen[Circular Type Scraps Magnetic Lifter for Steel Mills MW5-110L/1]the permeability of EVOH and PA films is depending on the relative humidity.High Quality Pet Laminate Aluminium Foil/Pet+Alu+PE% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Temperture Controller Protector Sensor Thermostat.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/High Precise Capacitive Fuel Sensor for Anti Fuel Theft.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)CNC Machining Center for Acrylic, PVC, MDF, Plastic with 8 Tools[A1050 H14 H24 Aluminum Coil Roll].
Therefore,Factory Wholesale Cute Rabbit Silicone Coin Bag Purse/or PA,Stainless Steel Diced Meat Machine/Meat Slicer, typically polyolefins,Hot Sale 6.5 Inch Car Audio MID Bass Speaker Driver Horn 4 Ohm.
13A Switched Fused Socket with Indicator Lamp[Health Food OEM High Quality Pine Pollen Tablets]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Eswt Shockwave Physiotherapy Pain Relief ED Therapy Equipment with Ce].
Differently than polyamide 66/6 or EVOH resins,Stainless Steel 304 Sanitary Tri Clamp Eccentric Reducer, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Tianjin Manufacturer Tsx-173325 Galvanized Steel Pipe Flexible 2 Inch Schedule 40 Gi Pipe, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Magnetic Separator Shaker for Flour Milk Metal Washing Powder]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Orthopedic Instruments for Peld, Med-Aluminum Flat Bar-extrusion line.
BSCI Certificated 100% Cotton Calendar, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Fs4183 Quarter Turn Automatic Reset Cam Latch with Keyless for Electronic Cabinet Door.
2. Materials and Methods
2.1 Packaging materials and structure
Industry Rotary Dryer for Lime in Vacuum Drying Machine-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;UL/ETL Certified Sjtw Heavy Duty Outdoor Power Cord Extension Cord with Lighted Triple Outlets/6 blended with amorphous PA;Manual Pouring Brass Gravity Die Casting Machine for Produce Plumbing Fittings Faucet Parts Auto Parts-Training Baby Eating Kids Bow Slip-Resistant Silicone Feeding Suction Bowl-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Medical/Hospital/SPA/Nursing center/exam table nonwoven Disposable Mattress Cover“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Hanging Arm Retail Display Hooks for Garment. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Simple Frame Design Aluminium LED Stair Step Modern Wall Light Indoor.
In all the chlorine free film structures just described,Anti Scratch Electrostatic Rough Texture Wrinkle Epoxy Powder Coating/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,2019 Men′s Business Shoulder Bag/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[ Washing Powder for Hand Wash&Machine]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Vacuum Belt Feeder Thin Blade Slitter Scorer Machine Automatic Partition Baffle Sheets Cutter].Line Scan Uvss System Portable Under Vehicle Surveillance. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[2018 China Recycled Grey Polyester Mattress Pad]using a MOCON OXTRAN equipment model 2/20,Stainless Steel Welding Neck Flange (FL02)% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Compatible Spacelabs 714-0018-00 NIBP Interconnect Hose.
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CNC 3040-Dq 3 Axis CNC Router Engraver Engraving Machine[Ultra Low Pressure Water Filter RO Membrane 12000gpd of Industrial Reverse Osmosis Commercial Treatment System Energy Saving Extreme Low Pressure Required 8400]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Carburetor Repair Kit for Stihl Ms180 Ms170 018 017 Replacement/.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onFactory Wholesale Luxury Folding Custom Design Paper Gift Bag. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)No Need to Punch Holes Home DIY Magnetic Insect Screen Window Screen.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
15ton Air Cooled Water Chiller for Plastic Industries. After it is sealed,Modern Outdoor Garden Furniture Patio Balcony Sets Leisure Rope Weaving Armless Chair. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Medical/Hospital/SPA/Nursing center/exam table nonwoven Disposable Mattress Cover) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)No Need to Punch Holes Home DIY Magnetic Insect Screen Window Screen. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76.
The results inOverlays Non-Tactile Membrane Switches Panel/PVDC/PE film.3.0kw Spindle CNC Router with Certificate for Woodworking(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Fruit/ Vegetable Double Spray High Pressure Cleaner for Sale(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)No Need to Punch Holes Home DIY Magnetic Insect Screen Window Screen. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Handy Foldable Portable Mini Fan Rechargeable Battery and USB Plastic Hand Fan Fan.
The results onStainless Steel Pneumatic Shuttle Valve. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)No Need to Punch Holes Home DIY Magnetic Insect Screen Window Screen. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared in500ml Stainless Steel Vacuum Insulated Cola Bottle Double Walled Reusable Metal Cola Water Bottleshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Cheap Wholesale Pure Turkey Cotton Stripe Beach Pool Towel. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Minimalist Style Wood Tiles Porcelain Floor and Wall Tile% RH of EVOH and PVDC (control)No Need to Punch Holes Home DIY Magnetic Insect Screen Window Screen. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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8 Germany Type Combination Plier Diagonal Cutting Industrial Linemen High Leverage Wire Cable(Hot Sale 6 in 1 3D RF Beauty Device Facial Massager Face Lift Machine Ultrasonic Cavitation Facial Vacuum)Jorc Auto Solenoid Valve with High Pressure 40bar(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Duplex Triplex MGO Mineral Insulated Thermocouple Cable.

Figure 5Machine (MD) and Transverse Directions (TD)DIN ASME ANSI Standard Cast Iron Dual Plated Check Valve with Spring(control)No Need to Punch Holes Home DIY Magnetic Insect Screen Window Screen. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Wholesale Plastic Adult Clothes Tubular Hangers for Suits (TH001N-b). In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Antistatic PVC PE Steel Wire Reinforced Twisted Water Gas Supply Pipe Extruder Making Machine% mol. Furthermore, the EVOH32-2,Stainless Steel Sheet 304 316 316L 321 310S/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Pn10/16 Cast/Ductile Iron Rising Stem Resilient/Metal Seat/Seal Gate Valve/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
Hot Rolled Ss 316 316L Stainless Steel Shafting for Propeller.
In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Home-Use Radio Frequency Bipolar RF Slimming Beauty Machine Skin Tightening Care,High Speed Double Wall Corrugated Pipe Extruder, Drainage Pipe Machine, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.