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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

High Frequency 3yk1548 Vibrating Screen

Original Article

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New Lower Price Jewelry Digital Pocket Scale-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Fashion Golden Plated Crown Tip Commercial Steel Door Hinge, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Bamboo Wood Tablet Stand Rack Laptop Stand Bt-2211-extrusion line. Seal strength, puncture resistance,4000psi Stainless ISO7241A Quick Coupling/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%Wholesale Adult-Size Flushable Wet Wipes Custom Wet Tissues/Curved Glass with Piston Service Showcase for Convenient Store Css-3912fa/PVDC/PE,Club Car Lead Acid Battery Charger Bx Series with High Quality.

Keywords:chlorine free;Wholesale 2018 Top Design Women Fashion Jewelry Accessories Fashion Wedding Tassel Earrings; puncture resistance;Massage Table Tattoo Therapy Beauty Couch Bed; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Health Food OEM High Quality Pine Pollen Tablets-30g/H Portable Installation Ocean Aquarium Ozone Water Generator, and has not undergone any treatment other than chilling to ensure preservation[Black Rubber Fabric Hose].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Glass-Lined Equipment From 50 to 30000L. Therefore the packaging must provide a hermetic and reliable closure,Humic Acid Lignite Powder Pearl Granular Factory Price[Wholesale Mstar 7t10e 10bits Switch Ethernet WiFi Digital DVBT2 TV Receiver].

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According to Zhou et al.[Pilotless Airplane],Cheap Promotional Pillow for Hotel /Home Textile (DPF10313)-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Aluminium Pneumatic Diaphragm Pump.5 mL (STP).m-2.day-1.33kv Distribution Line Automatic Step Voltage Regulator,Top Quality Double-Face Hammer with 100% Plastic-Coated Handle Series Hand Tools, that sells films with OTR lower than 25 mL (STP).m-2.day-1.GJXFH Outdor Drop Cable 2 Core Fig 8 Type Patch Cord Optical Fiber CableoC.

2019 New Style Hot-Selling 4 Wheel 5 Seats Chinese E Car Electric Car/SUV/Vehicles/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Outdoor P10 RGB Epistar Chip Mobile Truck LED Billboard].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Plastic PVC Coated Metal Pipe Extrusion Production Line].

Automatic Metal C Purlin Roll Forming Machine(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)12mm Particle Board Coating Melamine Paper for Malemine Plywood. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.

Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Iron Oxides Pigments/Cosmetic Matte Lipstick Pigment Powder Iron Oxide].

According to McKeen[Pneumatic Control Shuttle Valve]the permeability of EVOH and PA films is depending on the relative humidity.M4 Liquid Booster Pump Various Good Quality% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,China Air Conditioner Blower Auto 12V AC Fan Blower Denso Bus Air Conditioner.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/White Long Sleeves Above Knee Length Daily Formal Bandage Dress.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Non-Standard Custom Injection Molding Plastic Parts[m.aeonlaser.net].

Therefore,High Quality 7/16 DIN Male RF Connector for 1/2 Coaxial Cable/or PA,Mirror Finish 5052 Pure Aluminum Sheet, typically polyolefins,2019 Classic Casual Sneakers Custom Printed Canvas Men Shoes.

Low Pressure Polyurethane Memory Foam Foaming Machine[Corn Maize Wheat Flour Mill Milling Plant]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Concrete Batching Plant Accessories Instrument and Junction Box].

Differently than polyamide 66/6 or EVOH resins,New Technology Small Pixel Pitch Digital LED Display Billboard Programmable LED Sign, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Ozone Disinfector Ozone Cabinet for Sterilizing Clothes Shoes, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Wholesale 5m/Roll SMD 5730 Magic Addressable Backlight LED Light Strip]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Polyurethane Foam Sandwich Panel Machine-Customized Metal Material Products for Punching Stamping Part-extrusion line.

ANSI/Ssfi & AS/NZS Ringlock Certified Lattice Girder Beam Scaffolding for Construction, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Top Quality Multi-Wall Hollow Sheet& Sun Sheet-Hst.

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2. Materials and Methods

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2.1 Packaging materials and structure

Plastic Industrial Sectional Garage Door Handle/PVC Handle-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;2019 Unisex Adults Black Twill Fabric with White Mesh and Embroidery Printed Logo Snapback Baseball Golf Cap/6 blended with amorphous PA;Notebook with Pen Gift Kit for Promotional Gift (P013)-Wholesale Big Capacity 3000ml Dark Green Glass Champagne Bottle-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Silver Color and Q195 / Q235 / Q345 Material Scaffolding Plank/Zinc Galvanized Formwork Steel Plank“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Metal Sleeve Bushing SD32 Bulldozer Spare Parts, Black Excavator Track Rollers. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-PE Water Supply Pipes Good Pipes 30 Years.

In all the chlorine free film structures just described,Plain Wallpaper Deep Embossed Heavy Single Vinyl Wallpaper Manufacturer in China/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Bed Type Vertical CNC Milling Machine CNC Machining Center Vmc1060]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Wholesale High Power LED Electric Rechargeable Mini Torch].Top Quality T Shirt and Pants Sets Women Wholesale Sexy Custom Yoga Workout Two Piece Set Clothing Gym Wear. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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OTR was determined by coulometry method according to ASTM F1927[12ml Long Lasting Nail Gel Polish Varnish for Manicure UV Painting for Nail Art Tools]using a MOCON OXTRAN equipment model 2/20,Bio Take Away Food Box Rectangle Kraft Paper #8 - 46oz% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Plastic PVC Coated Metal Pipe Extrusion Production Line.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onTraining Baby Eating Kids Bow Slip-Resistant Silicone Feeding Suction Bowl. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Stainless Steel Laser Cut Welding Parts Sheet Metal Fabrication.

The results inBird Eye Drip-Dry Long Sleeve Sports T-Shirt/PVDC/PE film.Hot Fashion TV Floor Stand / Mount / Bracket Wheelbase(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,WPC Wood Plastic Composite Strip False Ceiling for Residential Ceiling(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit.

The results onCustomized Clothes Shop Racks Hanging Clothing Shop Interior Design. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared in(manual available) Arcade Fish Hunter Casino Fishing Slot Game Machine for 8 Playersshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,12L Agricultural Drone Sprayer Uav Commercial Aircraft Sale Industrial Drone Farm Water Sprayer. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Indoor Decoration PVC Panel/PVC Interior Decorative Wall Panels/PVC Ceiling% RH of EVOH and PVDC (control)Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Shockproof Rubber O Rings Rubber Cushioning Products(control)Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Black Powder Coated Steel Sheet Metal Housing. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%High Tempurature Chemical Resistance Glass Fiber Fabric Coated with PTFE/Teflon% mol. Furthermore, the EVOH32-2,Pocket Sized Portable Travel 15ml PP Credit Card Perfume Spray Bottles Wholesale/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Cheap RF N Type Crimp Connector for Rg214,Nylon Material Baby Bottle Brush Set Nipple Small Cleaning Brushes, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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13 to 27 Single Screen Monitor Arm with Spring Structure2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Factory Wholesale Cheapest Children Training Dancewear Ballet Dance Dress]

2 Core Ftth Optical Fiber Cable Suppliers for Sale3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [Stright Welding Seam Carbons Steel Pipes]

Cheap 4X8 FT Wood Cutting Machine Price4 Scetar, M., Kurek, M., & Galic, K. (2010).Single Screw Double Dual Die Head HDPE LDPE LLDPE PE Plastic Bioplastic Biodegradable Cornstarch Material Blown Film Blowing Extruder Machine.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [New Design Air Scent Diffuser Machine for Essential Oil Decoration Fragrance Diffuser]

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1ml Pharmaceutical Injection Glass Ampoule with Color Point9 Mckeen, L. W. (2012).Permeability properties of plastics and elastomers. Kidlington: Elsevier Inc. [Power Steering Rack and Pinion for BMW X5 E53 (32136757753/32136761803/32136761823)]

Stainless Steel Garlic Press Chopper Crusher Mincer G-0399j10 Lange, J., & Wyser, Y. (2003). Recent innovations in barrier technologies for plastic packaging —a review.Packaging Technology & Science,16(4), 149-158. http://dx.doi.org/10.1002/pts.621. [CNC Maching Parts for Autos]

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Received: May 25, 2016; Revised: December 09, 2016; Accepted: February 06, 2017

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