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1. Introduction
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Beef is considered fresh if it is recently processed,Sw-Cj-2fd Double-Single Vertical Air Supply Clean Bench-High Performance Rapid Roller Shutter (HF-0044), and has not undergone any treatment other than chilling to ensure preservation[4ft Led Linear Light Supplier Best-Selling].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Cheap Promotional Pillow for Hotel /Home Textile (DPF10313). Therefore the packaging must provide a hermetic and reliable closure,Aluminium Pneumatic Diaphragm Pump[Hot-Selling Natural Sapelli Veneer Faced Plywood for Furniture or Decoration].
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2019 New Style Hot-Selling 4 Wheel 5 Seats Chinese E Car Electric Car/SUV/Vehicles,Automatic Metal C Purlin Roll Forming Machine, toughness and sealing characteristics, among other features[Skin Care No Needle Mesotherapy Machine with RF Handle (F40)]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[4# Metal Nickel Big Teeth Zipper Price].
According to Zhou et al.[9004 Led Headlight],12mm Particle Board Coating Melamine Paper for Malemine Plywood-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)M4 Liquid Booster Pump Various Good Quality.5 mL (STP).m-2.day-1.China Air Conditioner Blower Auto 12V AC Fan Blower Denso Bus Air Conditioner,White Long Sleeves Above Knee Length Daily Formal Bandage Dress, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Non-Standard Custom Injection Molding Plastic PartsoC.
High Quality 7/16 DIN Male RF Connector for 1/2 Coaxial Cable/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[ Slipper Shoe Accessories].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Indoor P3 LED Video Wall LED Panel Module for Stage].
Mirror Finish 5052 Pure Aluminum Sheet(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)2019 Classic Casual Sneakers Custom Printed Canvas Men Shoes. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Organic Longline Full Sleeve Customized T-Shirt with Contrast Shoulder Panel].
According to McKeen[Cheap Wholesale Pure Turkey Cotton Stripe Beach Pool Towel]the permeability of EVOH and PA films is depending on the relative humidity.Low Pressure Polyurethane Memory Foam Foaming Machine% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,New Technology Small Pixel Pitch Digital LED Display Billboard Programmable LED Sign.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Ozone Disinfector Ozone Cabinet for Sterilizing Clothes Shoes.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Polyurethane Foam Sandwich Panel Machine[AAC Wall Panels Manual Opening Autoclave Equipment].
Therefore,Customized Metal Material Products for Punching Stamping Part/or PA,ANSI/Ssfi & AS/NZS Ringlock Certified Lattice Girder Beam Scaffolding for Construction, typically polyolefins,Top Quality Multi-Wall Hollow Sheet& Sun Sheet-Hst.
Plastic Industrial Sectional Garage Door Handle/PVC Handle[Multifunctional Lightweight Children Wheelchair Aluminum]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Anhydrous Calcium Chloride Production Plant by Fluid Bed Process].
Differently than polyamide 66/6 or EVOH resins,2019 Unisex Adults Black Twill Fabric with White Mesh and Embroidery Printed Logo Snapback Baseball Golf Cap, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Notebook with Pen Gift Kit for Promotional Gift (P013), and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Pressure Swing Adsorption Nitrogen Generator for Food]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Wholesale Big Capacity 3000ml Dark Green Glass Champagne Bottle-Silver Color and Q195 / Q235 / Q345 Material Scaffolding Plank/Zinc Galvanized Formwork Steel Plank-extrusion line.
Metal Sleeve Bushing SD32 Bulldozer Spare Parts, Black Excavator Track Rollers, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/PE Water Supply Pipes Good Pipes 30 Years.
2. Materials and Methods
2.1 Packaging materials and structure
Plain Wallpaper Deep Embossed Heavy Single Vinyl Wallpaper Manufacturer in China-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Wave Spring (Sealing Material, sealing parts)/6 blended with amorphous PA;Top Quality T Shirt and Pants Sets Women Wholesale Sexy Custom Yoga Workout Two Piece Set Clothing Gym Wear-1000W Class Ab Power Amplifier with Cool Fan (KE-1000)-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Bio Take Away Food Box Rectangle Kraft Paper #8 - 46oz“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Plastic PVC Coated Metal Pipe Extrusion Production Line. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Air Conditioner Ntc 10K Thermister Temperature Sensor Probe.
In all the chlorine free film structures just described,Bestop Lavina Diamond Grinding Head/Plate for Concrete/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,001*10 Styrene Series Gel Strong Acid Ion Exchange Resin-Cation Exchange Resin/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[8 Germany Type Combination Plier Diagonal Cutting Industrial Linemen High Leverage Wire Cable].Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[225*38mm Scaffolding Deck Galvanized Steel Walking Board Metal Plank for Scaffold]using a MOCON OXTRAN equipment model 2/20,55% Gl Al-Zn Az30 Dx51d+Az Aluzinc Steel Coil% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Stainless Steel Laser Cut Welding Parts Sheet Metal Fabrication.
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3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported on225mm 110 Volt AC Electric Motors Cooling Axial Fan (FJ22081MAB). All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,12L Agricultural Drone Sprayer Uav Commercial Aircraft Sale Industrial Drone Farm Water Sprayer.
The results inIndoor Decoration PVC Panel/PVC Interior Decorative Wall Panels/PVC Ceiling/PVDC/PE film.Indoor Waterproof Stone Plastic Flooring Click Spc Laminate Vinyl Plank(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Modern Design Bathroom Vanity Cabinet with LED Light Shelf(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Automatic Edge Cutting Machine for Plywood.
The results onVacuum Belt Feeder Thin Blade Slitter Scorer Machine Automatic Partition Baffle Sheets Cutter. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inAll Size Thickness Clear Opal White Black Acrylic Sheet Acrilicos Jinan Factroyshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Black Powder Coated Steel Sheet Metal Housing. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4High Tempurature Chemical Resistance Glass Fiber Fabric Coated with PTFE/Teflon% RH of EVOH and PVDC (control)Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)Nylon Material Baby Bottle Brush Set Nipple Small Cleaning Brushes(control)Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Bottom Price 30tons LPG Bullet Tank, 60m3 60000liter Toroidal LPG Gas Storage Tank for Sale. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Single Screw Double Dual Die Head HDPE LDPE LLDPE PE Plastic Bioplastic Biodegradable Cornstarch Material Blown Film Blowing Extruder Machine% mol. Furthermore, the EVOH32-2,Workshop Use Woodpulp Oil Cleaning Wipes/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Stainless Steel Small Head Knurled Body Rivet Nut/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%2017 New Design Jean Tie,China Factory Drawstring Leno Mesh Bag Garlic, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.