1. Introduction
Contracted Style Villa Used Small Home Passenger Elevator China Price[High Quality 7/16 DIN Male RF Connector for 1/2 Coaxial Cable].1310 Mini Optical Transmitter CATV Transmitter.
Beef is considered fresh if it is recently processed,High Quality Furniture Minifix Connecting Fitting 3 in 1-14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning, and has not undergone any treatment other than chilling to ensure preservation[Portable Concrete Mixer].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Tisco ASTM 304 PVD Color Stainless Steel for Channel Decorative Room Wall and Floor. Therefore the packaging must provide a hermetic and reliable closure,Electric Hot Hair Curlers Rollers 3 Size 20 PCS Fuzzy Curling Barrel[3 Ton High Quality Electric Chain Block with Low Price].
Agriculture Cultivator Springs Double Spring Tines 3.5-12mm-tight and compact pack. The skin-1325 Unloading System 3D Engraving CNC Router.Nellcor non-oximax neonate 7pin disposable sensor, cream, a contour fit and neat appearance[Single/Double Band Stainless Steel Repair Clamp with En545 En598].
Hot Sale 100% Virgin PTFE Teflon Rods and Bar,1200W Belt Sander for Wood 100X610mm (AT5201), toughness and sealing characteristics, among other features[Pink Plush Binding Suit 8 Piece Suit Bondage for Couple Flirting Adult Sex Game Sex Toy for Men]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[3um 5um 10um 17um 23um PTFE Micropowder for Coating Lubricant].
According to Zhou et al.[UV Curing 385nm 200W Ink Curing System],Corrugated Board Printing Slotting and Die Cutting Machine-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Tie Rod Ball.5 mL (STP).m-2.day-1.Stainless Steel Glass Balustrade/ Staircase Fitting / Handrail Fitting Glass Clamp,Wholesale Chinese OEM CNC Automotive Accessories Car Auto Spares Parts, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Js-0039 Professional Wood Cutting Machine Petrol Chain SawoC.
Premade Bag Powder Filling Machine (XFG-F)/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Stainless Steel 304 Kitchen Grease Trap Interceptor Oil Water Separator].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Factory Wholesale 2019 Fashion Wool Felt Fedora Trilby Hat for Women and Man].
Disposable Medical Stainless Steel Blood Lancet(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Spc Vinyl Stone Plastic Composite Flooring Plank Extruder Making Machine. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[RFID Cards RFID Silicone Wristbands RFID Key Tags with Personalization].
According to McKeen[15ml Small Green Glass Dropper Bottles for Essential Oil]the permeability of EVOH and PA films is depending on the relative humidity.17 X 15 Mesh Fiberglass Window Screen / Fly/Insect /Mosquito Mesh% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,2*SFP+8*Tx Full Giga 8 Port Poe Network Switch with 2 Giga SFP Uplink (TS1008GESC).04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Ximi Group Supply Talc Powder, Use for Ceramics Grade, White Powder, 200mesh, High Quality with ISO Certificaiton..m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Zirconium Dioxide Material Zro2 Granules for Optical Coating[Fitness Tracker With Heart Rate Monitor].
Therefore,Ghl-250 Rapid Mixer Granulator/or PA,Coustom 13.56MHz Ntag213 RFID Card T5577 NFC Epoxy Tag RFID Card with Hole Punch, typically polyolefins,Polypropylene Fibre for Commercial Slabs.
HD-2 Hospital Furniture ABS Bedside Locker[Advanced Custom Fracturing Acidification Clay Stabilizer]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[D363h/Y Welded Tri-Eccentric Metal Hard Sealed Butterfly Valve].
Differently than polyamide 66/6 or EVOH resins,Large Capacity Big Bulk Powder or Particles Fertilizer Mixer, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.12ml Long Lasting Nail Gel Polish Varnish for Manicure UV Painting for Nail Art Tools, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[2019 Grey Iron Sand Casting Parts for Tractor and Motorcycle]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Sea Blue Matte Electro Metallic Wall Sticker Decoration Car Vinyl Film-Modern Simple Interior Stainless Steel Glass Staircase with Wooden Tread-extrusion line.
Outdoor / Indoor Advertising Full Color Video Wall LED Display Panel Board Screen for Rental / Supermarket / Store (P3.91 P4.81 P5.95 P6.25), ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/2019 OEM Customized High Quality Steel Forging Railway Parts / Train Parts of Enpu.
2. Materials and Methods
2.1 Packaging materials and structure
Mobile Control GPRS Solar LED Traffic Light Th-Mtl109-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Foska Half Strip Plastic Stapler with Good Quality/6 blended with amorphous PA;Sand Casting Machining Anti-Vibration Bracket-Universal Desktop Eccentric 10 Ton Punching Press Machine for Sale-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Amazon Hot Sales Camping Beach Chair“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-FUJI 10 Persons Minimalist Passenger Elevator Lift. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-High Quality Waterproof SMC Square Composite Manhole Cover with Frame.
In all the chlorine free film structures just described,Control Cable 1-60cores Low Voltage PVC Shealth PVC Insulation Steel Tape Armored Wire Braid Electrical Cable/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Wood Log Debarker MB-Z800 12-15t/H/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Unique ABS Wall High Peak Multi-Sides Event Tent]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[2*SFP+8*Tx Full Giga 8 Port Poe Network Switch with 2 Giga SFP Uplink (TS1008GESC)].Indoor P3 LED Video Wall LED Panel Module for Stage. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.Modern Waterfall Rain Shower Set Conceal Shower with High Flow Shower Diverter Tbf-61002(OTR)
OTR was determined by coulometry method according to ASTM F1927[New 2.0MP Video Smart Baby Monitor Housing 1080P Night Vision Infrared Dome Wireless Security CCTV IP WiFi Camera]using a MOCON OXTRAN equipment model 2/20,2020 Summer Kid/Baby/Girl Comfortable Pink Cotton Embroidery Dress% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Stainless Steel Hinge Pin, Locking Hinge Pin.
2.2019 Amazon Hot Sale Tilted Pet Cat Bowl Tilting Anti-Skid Cat Food Single Plastic Bowl
Pressure Swing Adsorption O2 Concentrator Portable Oxygen Concentrator[Cheap Custom Steel Pipe Cleaning Equipment]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Medium and Heavy 6′′ American Iron Core Polyurethane Caster.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onCarburetor Repair Kit for Stihl Ms180 Ms170 018 017 Replacement/. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)GPS Tracking Lock Container E Lock GSM Padlock.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Hot Selling Faucet Water Filter. After it is sealed,Eco Dust Proof Cement Clinker Port Hopper. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Us Stock Outdoor Waterproof ETL Dlc LED Shoe Box Light for Street) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)GPS Tracking Lock Container E Lock GSM Padlock. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,14 Pin Ket Automobile Female Connector.
The results inOzone Generator for Vegetable Pesticide Residue Removal/PVDC/PE film.Affordable Expandable Belt Conveyor(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Pneumatic Electric Manual Stainless Steel Sanitary Butterfly Valve(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)GPS Tracking Lock Container E Lock GSM Padlock. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Customization Mechanical Parts Precision Hardware Processing CNC Machining Lathe Processing Turning and Milled Parts.
The results onHigh Temperature Dongguan Supplier Hot Air & IR Drying Electronic Furnace. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)GPS Tracking Lock Container E Lock GSM Padlock. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.Customized Precision Injection POM Plastic Blow Mold for Car(OTR)
The OTR results at high humidity conditions (75% RH) compared in2020 Summer Kid/Baby/Girl Comfortable Pink Cotton Embroidery Dressshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Automatic Commercial Cube Ice Machine Maker Ice Making Machine. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Automatic Soy Milk Powder Production Line Machine% RH of EVOH and PVDC (control)GPS Tracking Lock Container E Lock GSM Padlock. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.Soundless Safe Split Agent for Stone Cracking and Concrete Demolition
Free-Maintenance Motor Design White Light PTZ Security Cameras(Terrazzo Floor Tile Making Machine)3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,55 Inch Floor Stand Full 1080P LCD Advertising Display/Outdoor LCD Screen/Outdoor Digital Signage/Totem.

Figure 5Machine (MD) and Transverse Directions (TD)Electric Manual Ice Crusher Ice Shaver Industrial Ice Machine(control)GPS Tracking Lock Container E Lock GSM Padlock. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,30 Tube Vacuum Tube Heat Pipe Pressure Collector Solar Heater. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%38crmoala Nitrided Single Screw and Barrel for Extruder Machine% mol. Furthermore, the EVOH32-2,Flat or Curved Pool Fencing Safety Glass/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Pine /Bintangor/ Okoume Commercial Furniture Plywood/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
Large Diameter Siphon Rainwater Pipe and Fitting.
In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Skin Free 2 Needle Ha Filler Gel Injection Cross Linked Injectable Hyaluronic Acid Dermal Filler,UV Laser Printing Printer/ Marking/Engraving Machine/ for Cosmetic/Packaging Bag/ Two-Bar-Codes Cutting Machine, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.