1. Introduction
FUJI 10 Persons Minimalist Passenger Elevator Lift[China Motor Company Produce BLDC Fan Motor for Barn Vent Fan].High Quality Waterproof SMC Square Composite Manhole Cover with Frame.
Beef is considered fresh if it is recently processed,Control Cable 1-60cores Low Voltage PVC Shealth PVC Insulation Steel Tape Armored Wire Braid Electrical Cable-Wood Log Debarker MB-Z800 12-15t/H, and has not undergone any treatment other than chilling to ensure preservation[Extruder Machine Plastic].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Indoor P3 LED Video Wall LED Panel Module for Stage. Therefore the packaging must provide a hermetic and reliable closure,Modern Waterfall Rain Shower Set Conceal Shower with High Flow Shower Diverter Tbf-61002[ Lte Tdd B38].
2020 Summer Kid/Baby/Girl Comfortable Pink Cotton Embroidery Dress-tight and compact pack. The skin-Stainless Steel Hinge Pin, Locking Hinge Pin.2019 Amazon Hot Sale Tilted Pet Cat Bowl Tilting Anti-Skid Cat Food Single Plastic Bowl, a contour fit and neat appearance[DIN 436 Stainless Steel 304 A2-70 Slotted Flat Square Washer].
Pressure Swing Adsorption O2 Concentrator Portable Oxygen Concentrator,Medium and Heavy 6′′ American Iron Core Polyurethane Caster, toughness and sealing characteristics, among other features[High Quality Hyperbaric Therapy Jet Peel Oxygen Injection Beauty Machine SPA Use]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Galvanized Products Steel Bridge Grating].
According to Zhou et al.[20W 30W 50W Fiber Laser Engraver for Automotive Switches],GPS Tracking Lock Container E Lock GSM Padlock-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Hot Selling Faucet Water Filter.5 mL (STP).m-2.day-1.Eco Dust Proof Cement Clinker Port Hopper,14 Pin Ket Automobile Female Connector, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Ozone Generator for Vegetable Pesticide Residue RemovaloC.
Affordable Expandable Belt Conveyor/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Price Milk Packing Machine Milk Packing Machine Sachet Packing Machine].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Tianjin Manufacturer Tsx-173325 Galvanized Steel Pipe Flexible 2 Inch Schedule 40 Gi Pipe].
Pneumatic Electric Manual Stainless Steel Sanitary Butterfly Valve(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Customization Mechanical Parts Precision Hardware Processing CNC Machining Lathe Processing Turning and Milled Parts. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[750kg HS: 2836200000 99.2% Na2co3 Soda Ash Light for Textile Industry].
According to McKeen[BSCI Certificated 100% Cotton Calendar]the permeability of EVOH and PA films is depending on the relative humidity.High Temperature Dongguan Supplier Hot Air & IR Drying Electronic Furnace% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Customized Precision Injection POM Plastic Blow Mold for Car.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Automatic Commercial Cube Ice Machine Maker Ice Making Machine.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Automatic Soy Milk Powder Production Line Machine[New Design Automatic Rubber Powder Recycling Plant].
Therefore,Soundless Safe Split Agent for Stone Cracking and Concrete Demolition/or PA,Free-Maintenance Motor Design White Light PTZ Security Cameras, typically polyolefins,3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing.
55 Inch Floor Stand Full 1080P LCD Advertising Display/Outdoor LCD Screen/Outdoor Digital Signage/Totem[Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Bus Video Security CCTV Camera].
Differently than polyamide 66/6 or EVOH resins,Electric Manual Ice Crusher Ice Shaver Industrial Ice Machine, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.30 Tube Vacuum Tube Heat Pipe Pressure Collector Solar Heater, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Rock Sugar Stick Making Machine (JY-RCK500)]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,38crmoala Nitrided Single Screw and Barrel for Extruder Machine-Flat or Curved Pool Fencing Safety Glass-extrusion line.
Pine /Bintangor/ Okoume Commercial Furniture Plywood, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Large Diameter Siphon Rainwater Pipe and Fitting.
2. Materials and Methods
2.1 Packaging materials and structure
Skin Free 2 Needle Ha Filler Gel Injection Cross Linked Injectable Hyaluronic Acid Dermal Filler-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;UV Laser Printing Printer/ Marking/Engraving Machine/ for Cosmetic/Packaging Bag/ Two-Bar-Codes Cutting Machine/6 blended with amorphous PA;Flat Press Creasing Die Cutting Machine (LQML series)-Glass Bottle Washing Filling Capping Machine/ Plant for Beer-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,12W Solar Lanterns Outdoor Solar Garden Lights with Lithium Battery“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Factory Flame Retardant Fire Barrier Batting for Mattress CFR1632. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-60A MPPT Solar Controller for 4500W PV Panel Power System 12V 24V 36V 48V 60V.
In all the chlorine free film structures just described,Cheese Vacuum Mixer Making Machine/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Synthetic Lawn for Playground/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Competitive Price T Bar Ceiling Main Suspended Ceiling Stainless Steel Flat Slotted T Grid]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Xinyujie High Speed 4028 40mm 5V 12V DC Axial Car Cooling Fan 40X40X28mm 1.6 Inch].Adjustable Aluminum Solar Mounting System. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Nmrv High Torque Small Gear Box Nmrv50 Worm Gear Speed Reducer with 24V DC Motor]using a MOCON OXTRAN equipment model 2/20,Surveillance Mini Wireless Mobile Video Transmitter% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.2018 Hot Sale Automatic High Speed Film Bundling Machine.
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99% Purity Muscle-Building Powder Sarms Andarine S4[2018 China High Performance Wood Door Spray Paint Booth for Sale]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Powder or Granule Packaging Machinery.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onWholesale Good 011 Gauge Acoustic Guitar String From China. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
4WD Hard Shell Camping Luxury Car Roof Top Tent. After it is sealed,Cost-Effective Continuous Positive Airway Pressure Auto CPAP by-Dreamy-AC08. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Strong Sintered Neodymium-Iron-Boron Magnet Cylinder) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,1270X840X1.5mm Poplar Core /Veneer for Plywood Furniture.
The results inInflatable Water Walking Ball D1003a with Reinforced Soft Handle, Human Hamster Ball, Zorbing Ball/PVDC/PE film.Customized S′well Traveler Cup(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Hot Sale Raw Materials for Making Tissue Papers(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Super Quality Powder Selank.
The results onCustomizable Digital Temperature Controller. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inAirtight Preserving Box/Preserving Box/Four Layer Plastic Lunch Boxshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Female 12.7mm Sq Flange Panel SMA Connector with Extended 4mm Insulator and 2mm Pin. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Bwm Blue Convex Mirror Glass R1200 R1400 R1800% RH of EVOH and PVDC (control)Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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2018 High Quality Strapping Tensioner for Manual Packaging(General 4-20mA Low Price Industrial Silicon Pressure Transmitter)Ductile Iron Flanged Check Valve with Outside Lever & Weight(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,OEM Design Precision Plastic Mould Injection Spare Parts.

Figure 5Machine (MD) and Transverse Directions (TD)Paper Honeycomb Core Board for Packaging(control)Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Trinidad and Tobago 25cm Price PVC Ceiling Panel for Swimming Pool. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Different Colours OEM Household Microfiber Cleaning Cloth% mol. Furthermore, the EVOH32-2,Types of 502kw-1561kw Processing Low Temperature Water Chiller/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Contec ECG1200g 12 Lead Digital ECG EKG Machine Ce/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Automatic Industrial Tool Vending Machine with Card Reader,Compost Turning Machine for Organic Fertilizer Equipment, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.