1. Introduction
Tianjin Manufacturer Tsx-173325 Galvanized Steel Pipe Flexible 2 Inch Schedule 40 Gi Pipe[3 Axis 250t/3200 CNC Press Brake with Delem Da52s CNC Press Brake 250 Tons].Orthopedic Instruments for Peld, Med.
Beef is considered fresh if it is recently processed,Aluminum Flat Bar-BSCI Certificated 100% Cotton Calendar, and has not undergone any treatment other than chilling to ensure preservation[Hyundai Car Mold Frame].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Fs4183 Quarter Turn Automatic Reset Cam Latch with Keyless for Electronic Cabinet Door. Therefore the packaging must provide a hermetic and reliable closure,Industry Rotary Dryer for Lime in Vacuum Drying Machine[Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine].
UL/ETL Certified Sjtw Heavy Duty Outdoor Power Cord Extension Cord with Lighted Triple Outlets-tight and compact pack. The skin-Manual Pouring Brass Gravity Die Casting Machine for Produce Plumbing Fittings Faucet Parts Auto Parts.Training Baby Eating Kids Bow Slip-Resistant Silicone Feeding Suction Bowl, a contour fit and neat appearance[Nails Making Machine Manufacturer From China].
Medical/Hospital/SPA/Nursing center/exam table nonwoven Disposable Mattress Cover,Hanging Arm Retail Display Hooks for Garment, toughness and sealing characteristics, among other features[8 Germany Type Combination Plier Diagonal Cutting Industrial Linemen High Leverage Wire Cable]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Flat or Curved Pool Fencing Safety Glass].
According to Zhou et al.[500 Watt Laser Cutter],Simple Frame Design Aluminium LED Stair Step Modern Wall Light Indoor-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Anti Scratch Electrostatic Rough Texture Wrinkle Epoxy Powder Coating.5 mL (STP).m-2.day-1.2019 Men′s Business Shoulder Bag,Line Scan Uvss System Portable Under Vehicle Surveillance, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Designer One Piece Kids Clothes Online Golden Luxury Lace Embroidery Summer Frock Designs Girls Party DressesoC.
Stainless Steel Welding Neck Flange (FL02)/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[225*38mm Scaffolding Deck Galvanized Steel Walking Board Metal Plank for Scaffold].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Customized S′well Traveler Cup].
Compatible Spacelabs 714-0018-00 NIBP Interconnect Hose(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)RF 3 PC Pneumatic Ball Valve with Control Head. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Leopard Yoga Set Sportswear for Women Fitness Clothing].
According to McKeen[Wheel Loader Seal Ring (80A0016) for Liugong Loader]the permeability of EVOH and PA films is depending on the relative humidity.CNC 3040-Dq 3 Axis CNC Router Engraver Engraving Machine% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Carburetor Repair Kit for Stihl Ms180 Ms170 018 017 Replacement/.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/No Need to Punch Holes Home DIY Magnetic Insect Screen Window Screen.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)15ton Air Cooled Water Chiller for Plastic Industries[Screw Earth Ground Anchor].
Therefore,Modern Outdoor Garden Furniture Patio Balcony Sets Leisure Rope Weaving Armless Chair/or PA,Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76, typically polyolefins,Overlays Non-Tactile Membrane Switches Panel.
3.0kw Spindle CNC Router with Certificate for Woodworking[225mm 110 Volt AC Electric Motors Cooling Axial Fan (FJ22081MAB)]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[White High-End Acrylic Plastic Cosmetic Packaging Emulsion Bottles and Cream Jar].
Differently than polyamide 66/6 or EVOH resins,Fruit/ Vegetable Double Spray High Pressure Cleaner for Sale, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Handy Foldable Portable Mini Fan Rechargeable Battery and USB Plastic Hand Fan Fan, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Complete Palm Oil Milling Processing Machine Palm Oil Extractor]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Stainless Steel Pneumatic Shuttle Valve-Electric Smart Fingerprint Door Lock Wt-M-1603A-extrusion line.
Cheap Wholesale Pure Turkey Cotton Stripe Beach Pool Towel, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Minimalist Style Wood Tiles Porcelain Floor and Wall Tile.
2. Materials and Methods
2.1 Packaging materials and structure
Customized 0~200degrees Manuel/Auto Reset Ksd301 Thermostat for Electrical Oven-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;8 Germany Type Combination Plier Diagonal Cutting Industrial Linemen High Leverage Wire Cable/6 blended with amorphous PA;Jorc Auto Solenoid Valve with High Pressure 40bar-Duplex Triplex MGO Mineral Insulated Thermocouple Cable-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,DIN ASME ANSI Standard Cast Iron Dual Plated Check Valve with Spring“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Wholesale Plastic Adult Clothes Tubular Hangers for Suits (TH001N-b). The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Antistatic PVC PE Steel Wire Reinforced Twisted Water Gas Supply Pipe Extruder Making Machine.
In all the chlorine free film structures just described,Stainless Steel Sheet 304 316 316L 321 310S/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Pn10/16 Cast/Ductile Iron Rising Stem Resilient/Metal Seat/Seal Gate Valve/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[3mx3m Cheap Portable Outdoor Pop up Tent]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Small Size/Type/Model CNC CO2 Laser Cutting Engraving Cutter Manufacture/Factory].Hot Rolled Ss 316 316L Stainless Steel Shafting for Propeller. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[High Quality P3/P4 Stage LED Display Screen Wall]using a MOCON OXTRAN equipment model 2/20,High Speed Double Wall Corrugated Pipe Extruder, Drainage Pipe Machine% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Hot Sale Universal Night Vision with Wireless Parking Sensor & Car Alarm for Car Black Box Wireless Camera & LCD Monitor Driving & Parking System with GPS.
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ESD Top Fit Black Latex Palm Coated Anti Static Work Gloves Ce Approved[Universal Fiber Optic Termination Kit&Nbsp; Lk-6013]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Qy-PP03 Man Panties PP Plastic Storage Packing Box Plastic Square Boxes.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported on5/16 Inch Flexible Natural Argon Gas Hose Stainless Steel Hose. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)ASTM A500 Grade a Mild Steel Material Shs Hollow Sections.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
6500k 2700k 24W Round LED Panel Lamp. After it is sealed,Sanitary Stainless Steel Vertical Commerical Colloid Mill for Food Grinding. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (High Flex Mdr 26 to SDR 26 Power Over Cable with Thumbscrews Locking and PVC Jacket) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)ASTM A500 Grade a Mild Steel Material Shs Hollow Sections. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,High Quality PU/Rock Wool MGO Sandwich Panel for Clean Room.
The results inSuede Base Fabric, Synthetic Leather, Microfiber PVC Leather/PVDC/PE film.Brushed Anti Brass Bags/Handbags Dog Hook New Design(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Welded Carbon Steel Pipe for Transportation (CZ-RP67)(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)ASTM A500 Grade a Mild Steel Material Shs Hollow Sections. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Pet Preform Injection Mould Factory.
The results onWholesale Tight Women′s Fashion Compression Yoga Pants. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)ASTM A500 Grade a Mild Steel Material Shs Hollow Sections. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inHot Sale 6.5 Inch Car Audio MID Bass Speaker Driver Horn 4 Ohmshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,19 Inch U. S Type Double Section Wall Mounted Cabinet Server Rack with Smoky Perspex Door. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Contracted Style Villa Used Small Home Passenger Elevator China Price% RH of EVOH and PVDC (control)ASTM A500 Grade a Mild Steel Material Shs Hollow Sections. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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High Quality Furniture Minifix Connecting Fitting 3 in 1(China Electronic Fly Killer Mosquito Killer Trap Lamp Manufacturers)14L 300W Hospital Lab Digital Ultrasonic Benchtop Cleaner Watches Jewelry Cleaning(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Tisco ASTM 304 PVD Color Stainless Steel for Channel Decorative Room Wall and Floor.

Figure 5Machine (MD) and Transverse Directions (TD)Electric Hot Hair Curlers Rollers 3 Size 20 PCS Fuzzy Curling Barrel(control)ASTM A500 Grade a Mild Steel Material Shs Hollow Sections. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Agriculture Cultivator Springs Double Spring Tines 3.5-12mm. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%1325 Unloading System 3D Engraving CNC Router% mol. Furthermore, the EVOH32-2,Nellcor non-oximax neonate 7pin disposable sensor, cream/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Hot Sale 100% Virgin PTFE Teflon Rods and Bar/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Corrugated Board Printing Slotting and Die Cutting Machine,Tie Rod Ball, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.