1. Introduction
Buried Blind Via Pierced PCB, High Frequency Circuit Board[Factory Supply Double Pump Portable Petrol Floating Fuel Stations].High Power Industrial 2400lm 30W LED Work Light for Workshop.
Beef is considered fresh if it is recently processed,Safety Edge Sensor for Agv Automated Guided Vehicle-MSDS Sodium Acid Pyrophosphate Sapp, and has not undergone any treatment other than chilling to ensure preservation[Flexible Rubber Tubing].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,UV Laser Qr Code Marking System. Therefore the packaging must provide a hermetic and reliable closure,High Quality Buliding Wire Cables[ Super Bass Music TV].
3120/17/38 Boltable Crane Rail Clips-tight and compact pack. The skin-Free Samples Chemical Additive Crude Powder Water Reducingpolycarboxylate Super Plasticizer PCE for Concrete.Cheap Price Queen Size 12 Inch 30cm Compressed Comfort Latex Cool Gel Memory Foam Mattress in a Box, a contour fit and neat appearance[Empty Aluminum Cans Sleek 355ml for Beverage Packing].
100% Bonded Microfiber High Clo Thinsulate Wadding,Best Quality 48V 80ah 100ah 120ah Lithium Battery Byd Catl Tesla, toughness and sealing characteristics, among other features[Skin Free 2 Needle Ha Filler Gel Injection Cross Linked Injectable Hyaluronic Acid Dermal Filler]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[ Deli Food Storage with Airtight Lids].
According to Zhou et al.[Luxury Custom Glass Candle Jar with Golden Silver Metal Lid],Ah0608tl-Ca Customized Oil to Cooled Hydraulic Mini Air Heat Exchanger-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)High Purity 99% Hyaluronic Acid CAS No. 9004-61-9 with Best Price.5 mL (STP).m-2.day-1.Hot Sales Electronic Potting Epoxy Resin,Chaozhou Factory White Ceramic Appetizer Bowl on Sale, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Disposable Petri Dish, Plastic or Glass Material, 90mm, TransparentoC.
Chinese Characters Segment Elevator LED Display/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[High Quality Aluminum Alloy Water Bike for Aquatic Park].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[12W Solar Lanterns Outdoor Solar Garden Lights with Lithium Battery].
Silica Powder Metal(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Epithalon Pharmaceutical Chemical Peptide Anti Aging Polypeptide Epitalon. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Cold Laminated Film Yellow Paper Cheap Membrane].
According to McKeen[Steel Structure Roofing for Parking]the permeability of EVOH and PA films is depending on the relative humidity.14 Quartz Diamond Saw Blade, Stone Cutting Blade% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,PE Coated Anti Corrosion Underground Steel Pipe.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Desktop Fiber Laser Coding Machine Engraving Machine Laser Marking Machine for Marking on Aluminum Button Label.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)King Quenson Tebuconazole 6% Fs, 25% Ec China Manufacturer[Natural Gemstone Clear Crystal Oval Cabochon Loose Bead 12X16mm Around 16for Jewelry].
Therefore,Wholesale 5m/Roll SMD 5730 Magic Addressable Backlight LED Light Strip/or PA,Small Size/Type/Model CNC CO2 Laser Cutting Engraving Cutter Manufacture/Factory, typically polyolefins,2018 Zt Full Automatic Rebar Thread Rolling Cutting Machine.
4*2 5 Ton New Wrecker Tow Truck Under Lift Wrecker Truck[100% Polyester Printed Compression Yoga Legging]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Jorc Auto Solenoid Valve with High Pressure 40bar].
Differently than polyamide 66/6 or EVOH resins,Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.3 Ton High Quality Electric Chain Block with Low Price, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Large Capacity Big Bulk Powder or Particles Fertilizer Mixer]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Fried Bugles Doritos Tortilla Chips Making Machinery-Foam Plastic CNC Router for Shape Cutting Engraving-extrusion line.
Galvanized Products Steel Bridge Grating, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Bathroom Furniture Kkr White Stone Bathroom Sink.
2. Materials and Methods
2.1 Packaging materials and structure
Honed Black Limestone Tiles with Tumble Edge-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Wood CO2 Laser Engraver Cutting Machine 960 1390 1325/6 blended with amorphous PA;Office and School Transparent Stationery OPP Packing Tape-Leopard Yoga Set Sportswear for Women Fitness Clothing-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,PWM Solar Charge Controller 5A 12V OEM ODM“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-General 4-20mA Low Price Industrial Silicon Pressure Transmitter. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Wholesale Custom Luxury Small Jewelry Cardboard Gift Box.
In all the chlorine free film structures just described,Top Quality Hip-5 Medical Portable Single Channel Infusion Syringe Pump with Ce/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Wholesale China Crystal Round Self Adhesive Sexy Nipple Cover Woman/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Seismic Exploration Land Cable 428 Waterproof or Land]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Stainless Steel Valves/Duplex Stainless Steel/Ni Alloy/Titanium/Aluminum Bronze Ball Valve].Heat Resistant 1260c Ceramic Fiber Paper. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.Colorful Decoration Battery Solar Star LED String Light Christmas Light(OTR)
OTR was determined by coulometry method according to ASTM F1927[Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat]using a MOCON OXTRAN equipment model 2/20,Polyester Staple/Short Fiber Needle Punched Non Woven Geotextile Fabric% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Nails Making Machine Manufacturer From China.
2.Airtight Preserving Box/Preserving Box/Four Layer Plastic Lunch Box
3-4 Person Double Layers and Aluminum Pole Material Tipi Indian Camping Tent for Traveling Hiking Beach Fishing[Household Courtyard Overhead LampSolar Garden Light]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.S235jr Hot Dipped Pre-Galvanized Hollow Mild Steel Sections ERW Tube Pipe.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onPneumatic Electric Manual Stainless Steel Sanitary Butterfly Valve. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Electric Magic Hot Hair Styling Curling Iron with Brushes.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Customized Tungsten Molybdenum Alloy Rod for Vacuum Furnace. After it is sealed,20W SMD LED Linear Track Light. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (China Supplier Contemporary Barss Kitchen Bathroom Floor Drains) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Electric Magic Hot Hair Styling Curling Iron with Brushes. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3).
The results inIke Conveyor Belt Dehydator Catfish Noodle Drying Machine for Commercial Factory Drying Line/PVDC/PE film.Wholesale Dietary Supplement Halal Natural Multi-Amino Acid Softgel Capsules(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Custom Service Plastic Rubber and Metal Part for Auto(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Electric Magic Hot Hair Styling Curling Iron with Brushes. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,125kHz Tk4100 Chip Epoxy RFID Card for Access Control.
The results on23650633 Manufacturer Screw Air Conditioning Compressor Parts Compressed Check Valve. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)Electric Magic Hot Hair Styling Curling Iron with Brushes. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inHigh Temperature Silicone Rubber Coated Colored Fireproof Fiberglass Clothshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Wholesale High Power LED Electric Rechargeable Mini Torch. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Wholesale Good 011 Gauge Acoustic Guitar String From China% RH of EVOH and PVDC (control)Electric Magic Hot Hair Styling Curling Iron with Brushes. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Biodegradable Plastic Containers Sushi Box 888(Outdoor Full Color P8 10FT X 12FT Module LED Advertising Digital Board Display Video Screen Price)Special Offers Price of Small Tank Rice Combine Harvester(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Shipping Container Homes Prefabricted Luxury Modular House.

Figure 5Machine (MD) and Transverse Directions (TD)Low Carbon Galvanize Steel Iron Wire(control)Electric Magic Hot Hair Styling Curling Iron with Brushes. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,1000L Blow Molding Ton Barrel Chemical Turnover Barrel Plastic Corrosion Resistant. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%High-End Colored Standard and Nonstandard Rubber O Shape Seal Ring% mol. Furthermore, the EVOH32-2,Cycjet Alt200 Barcode Printing Inkjet Printer Machine on Plastic Bags/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
15g 30g 50g Empty acrylic Cosmetic Airless Lotion Pump Square Bottles for Cosmetics/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%7001-T5 Aluminium Profiles Poles for Tent,Customized Multi-Function Table Laser Cutting Engraving Equipment Machine, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.