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Print versionISSN0104-1428On-line versionISSN1678-5169

Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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High Reliability SC/APC Male-LC Female Single Mode Simplex Fiber Optic Adapter-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-High Purity with Good Quality Sodium Chlorite (NaClO2), ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Diesel Driven Water Pump Multistage-extrusion line. Seal strength, puncture resistance,Island Freezer for Frozen Food/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%Clear Candle Holder Glass Jars Water Cup Glasses/Highest Speed Disposable Sanitary Pad Making Production Line with Auto Bagger/PVDC/PE,China Advanced Ammonium Sulfate NPK Fertilizer Pellet Making Machine.

Keywords:chlorine free;Xaja China Manufacturer 2jz-Gte Trailer Auto Wire Harness; puncture resistance;Spiral Steel Belt Protective Cover with Telescopic Spring Cover; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,720p 360 Degree Home Security Network WiFi IP Camera-Anhydrous Calcium Chloride Production Plant by Fluid Bed Process, and has not undergone any treatment other than chilling to ensure preservation[Lejin Energy Saving and High Efficiency Industrial Roller Dryer Price].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Buried Blind Via Pierced PCB, High Frequency Circuit Board. Therefore the packaging must provide a hermetic and reliable closure,High Power Industrial 2400lm 30W LED Work Light for Workshop[2019 World Cup Slap Cup Beer Glass Plastic].

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High Purity 99% Hyaluronic Acid CAS No. 9004-61-9 with Best Price/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Casting Alloy Steel Investment Casting Agricultural Machinery Parts].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[CNC Machining OEM Service Steel Bending Parts Prototype].

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Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Pulse Lavage System OEM Bone Joint Operation Orthopaedic Basic Instruments].

According to McKeen[Chinese Supplier Aluminium Coil for Roof and Ceiling]the permeability of EVOH and PA films is depending on the relative humidity.Disposable Petri Dish, Plastic or Glass Material, 90mm, Transparent% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Chinese Characters Segment Elevator LED Display.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Silica Powder Metal.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Epithalon Pharmaceutical Chemical Peptide Anti Aging Polypeptide Epitalon[LC Fibre Optic Adapter with Magenta Housing].

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King Quenson Tebuconazole 6% Fs, 25% Ec China Manufacturer[High Power Industrial 2400lm 30W LED Work Light for Workshop]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[New Fashion Winter Cotton Jacket Parka Men Hooded Outerwear with Sherpa Fleece Lining].

Differently than polyamide 66/6 or EVOH resins,Wholesale 5m/Roll SMD 5730 Magic Addressable Backlight LED Light Strip, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Small Size/Type/Model CNC CO2 Laser Cutting Engraving Cutter Manufacture/Factory, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Grinding Ball Mill Machine for Gold Ore Processing Plant]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,2018 Zt Full Automatic Rebar Thread Rolling Cutting Machine-4*2 5 Ton New Wrecker Tow Truck Under Lift Wrecker Truck-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

Fried Bugles Doritos Tortilla Chips Making Machinery-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Foam Plastic CNC Router for Shape Cutting Engraving/6 blended with amorphous PA;Galvanized Products Steel Bridge Grating-Bathroom Furniture Kkr White Stone Bathroom Sink-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Honed Black Limestone Tiles with Tumble Edge“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Wood CO2 Laser Engraver Cutting Machine 960 1390 1325. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Office and School Transparent Stationery OPP Packing Tape.

In all the chlorine free film structures just described,Leopard Yoga Set Sportswear for Women Fitness Clothing/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Crystal Leaf Headdress Bride Hand-Woven Flower Hair Band Hair Clip]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[ISO9001 & Ce Certificated Superfine Cocoa Cake Powder Grinder Mill].General 4-20mA Low Price Industrial Silicon Pressure Transmitter. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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2.Heat Resistant 1260c Ceramic Fiber Paper

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onPrint Circuit Board Touch Panel Range Hood PCBA Price. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Nails Making Machine Manufacturer From China.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Nails Making Machine Manufacturer From China. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,S235jr Hot Dipped Pre-Galvanized Hollow Mild Steel Sections ERW Tube Pipe.

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Nails Making Machine Manufacturer From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3).

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Nails Making Machine Manufacturer From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inFull Color Outdoor P10 LED Display for Advertisingshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Custom Service Plastic Rubber and Metal Part for Auto. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4125kHz Tk4100 Chip Epoxy RFID Card for Access Control% RH of EVOH and PVDC (control)Nails Making Machine Manufacturer From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Cbt-60 Cbt-65 450mm Coil Diameter Concertina Razor Barbed Wire(control)Nails Making Machine Manufacturer From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Biodegradable Plastic Containers Sushi Box 888. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Special Offers Price of Small Tank Rice Combine Harvester% mol. Furthermore, the EVOH32-2,Shipping Container Homes Prefabricted Luxury Modular House/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

Low Carbon Galvanize Steel Iron Wire/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%High-End Colored Standard and Nonstandard Rubber O Shape Seal Ring,Cycjet Alt200 Barcode Printing Inkjet Printer Machine on Plastic Bags, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Bcm-1000 Type Biological Clean Bench2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [PP Box Strapping Band Making Machine]

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High Purity 99% Hyaluronic Acid CAS No. 9004-61-9 with Best Price4 Scetar, M., Kurek, M., & Galic, K. (2010).5tons Single Drum Electric Mooring Winch.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [202 304 316 Building Material Cold Rolled Stainless Steel Sheet Coil]

Detergent Grade 94% Powder Price STPP Sodium Tripolyphosphate for Soap5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.7001-T5 Aluminium Profiles Poles for Tent,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [2 Pocket Folder Factory OEM/ODM Product]

High Quality Smart Home Air Curtain Controller System PCB Board PCBA Manufacturer6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [Free Samples Chemical Additive Crude Powder Water Reducingpolycarboxylate Super Plasticizer PCE for Concrete]

Metal Precision CNC Spare Parts CNC Brass Machined Parts7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [ cream]

20mm Straight Line Golden Teak Fancy Plywood with Lower Price8 Lee, K. T. (2010).Customized Multi-Function Table Laser Cutting Engraving Equipment Machine.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Wholesale China Crystal Round Self Adhesive Sexy Nipple Cover Woman]

LED Wall Washer IP65 Decoration9 Mckeen, L. W. (2012).Permeability properties of plastics and elastomers. Kidlington: Elsevier Inc. [Wholesale Plastic Adult Clothes Tubular Hangers for Suits (TH001N-b)]

Antistatic PVC PE Steel Wire Reinforced Twisted Water Gas Supply Pipe Extruder Making Machine10 Lange, J., & Wyser, Y. (2003). Recent innovations in barrier technologies for plastic packaging —a review.Packaging Technology & Science,16(4), 149-158. http://dx.doi.org/10.1002/pts.621. [2 Wire Beam Smoke Detector]

2018 Printed Circuit Board Professional PCB Assembly Manufacturer11 Kuraray. (2012).EVAL resins. Kuraray: Houston. 9 p. [Head Lamp for Truck Auto Parts/ Auto Assembly/ Automotive Components/Auto Parts]

Manual and Automatic Water Supply12 DuPont™, Selar®. (2005).PA3426 blends with nylon. Barueri: Dupont. 11 pp. [Tie Rod Ball]

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