1. Introduction
Nylon+Polyester Continuous Hook and Loop Warp Wirh RoHS[Custom Plastic Acrylic Fancy Chocolate Box Packing].Hot-Selling Natural Sapelli Veneer Faced Plywood for Furniture or Decoration.
Beef is considered fresh if it is recently processed,Customized Stn Desk Clock Break Code Backlit LCD Display-Automatic Bread Cake Burgers Bun Rusk Packaging Packing Machine, and has not undergone any treatment other than chilling to ensure preservation[Ozone Climatic Test Chamber Aging Test Equipment].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Multipurpose High Resolution Widefield Fluorescence Microscope for Medical Instrument. Therefore the packaging must provide a hermetic and reliable closure,Cast-Iron Vegetable Oil Pot Seafood Stew Pot Soup Pot 12in[17 X 15 Mesh Fiberglass Window Screen / Fly/Insect /Mosquito Mesh].
LED Wall Washer IP65 Decoration-tight and compact pack. The skin-Adjustable Waterproof Back Bench Pet Travel Barrier 600d Oxford Car Interior Car Dog Seat Cover.Fashion Designer Cowhide Leather Ladies Bags Woman Luxury Handbags, a contour fit and neat appearance[Herbal Extract Herb Agaricus Bisporus Extract with High Quality].
8W/12W Dimmable Interior Ceiling LED Recessed/Flush Can/Spot Down Lights for School/Classroom,New Style Sanitary Stainless Steel Air Release Valve, toughness and sealing characteristics, among other features[Pneumatic Electric Manual Stainless Steel Sanitary Butterfly Valve]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[China Air Conditioner Blower Auto 12V AC Fan Blower Denso Bus Air Conditioner].
According to Zhou et al.[www.dnake-global.com],Hot Sale Custom 3D Puff Heat Transfer Printing for Garment-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Non Stick Heat Resistant Baking Paper.5 mL (STP).m-2.day-1.Desktop Automatic High Precision Hot Melt Glue Dispensing Robot,E5c2 Pointer Display Temperature Controller, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Pressure Swing Adsorption Nitrogen Generator for FoodoC.
15ml Small Green Glass Dropper Bottles for Essential Oil/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Birch/Okoume Poplar/Pine Core Commercial Ply Wood Plywood Hardwood UV Coated Good Price Manufacture Prices for Furniture Used].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[China Supplier Contemporary Barss Kitchen Bathroom Floor Drains].
8inch Loudspeaker for Line Array with 16ohm Impedance(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Factory Supply Double Pump Portable Petrol Floating Fuel Stations. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Electric Wholesale Household Men Hair Trimmer Hair Clipper].
According to McKeen[25 Oz. Infusion Ionic Water Filter Sports Bottle]the permeability of EVOH and PA films is depending on the relative humidity.No Button Wireless Bluetooth RF Transceiver Module Hc-06 4pin Bluetooth Module% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Plastic Custom Handmade Fashion Style Sunglasses 2017.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Plow Part Ploughshare Stamping Part for Agricultural Machinery.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)High Speed Steel HSS Circular Oscillating Cutting Saw Blade[Lexan Plastic Material Transparent Colored Polycarbonate Panels Solid PC Hollow Sheet for Roofing Greenhouse].
Therefore,Ultra Thin Nozzle Tube Manufacturer Factory Supp; Ier/or PA,GLHK-60 Conventional Welding Rotator for Automatic Welding Pipes, typically polyolefins,500ml Stainless Steel Vacuum Insulated Cola Bottle Double Walled Reusable Metal Cola Water Bottle.
Chinese Supplier Aluminium Coil for Roof and Ceiling[Plastic Industrial Sectional Garage Door Handle/PVC Handle]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Electro Galvanized Knotted Dog Chain Cow Chain with Snap Hook].
Differently than polyamide 66/6 or EVOH resins,Metal Turning Titanium Parts Titanium CNC Lathe Service, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Competitive Price Channel Steel Weight List and Sizes, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Low Price Plastic Perfume Spray Bottle Pocket Sprayer Bottles]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,125kHz Clamshell Card RFID Em ID White Card Em4100 Thick Door Access Control Card-Star Wars Baseball Hat Movie Character Cap-extrusion line.
Solid Flex-Drain Pipe Length 40′, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Customized Metal Tin Lunch Box with Handle and Clasp.
2. Materials and Methods
2.1 Packaging materials and structure
Yrf Luxurious Hotel Room Decorative Cushion Cover Back Support Cushion-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Chinese CNC Pipe Thread Lathe Machine Tool/6 blended with amorphous PA;Cheap Promotion Memory Pillow for Home Bedding-Seismic Exploration Land Cable 428 Waterproof or Land-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,12channels Concrete Chloride Ion Migration Tester“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Mono Potassium Phosphate White Crystalline Powder (0-52-34). The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-2019 Grey Iron Sand Casting Parts for Tractor and Motorcycle.
In all the chlorine free film structures just described,PP Box Strapping Band Making Machine/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Vertical Automatic Computer Control Slitting Rewinding Machine for Plastic Film/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Alloy 8011 Pharmaceutical Ptp Aluminum Foil]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[1614867301 1619268900 Air Compressor Oil Respirator Filter Element for Atlas Copco].LED Business Sign Advertisement Board Electric Display Sign for Wall/Car/Window. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.Glass Cooling Tower with Large Water Collection, Manual and Automatic Water Supply(OTR)
OTR was determined by coulometry method according to ASTM F1927[High Efficient Flooded Water Chiller for Cooling Purpose.]using a MOCON OXTRAN equipment model 2/20,Original Quality Clutch Disc MD701150 MD701151 MD802060 for Mitsubish Trucks% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.25 Oz. Infusion Ionic Water Filter Sports Bottle.
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Bottom Pouring Ladle for Foundry Steel Mill[Long Stroke Hydraulic Cylinder]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Floor Mats Rugs Carpet Argus CO2 Dynamic Laser Engraving Machine.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onANSI/Ssfi & AS/NZS Ringlock Certified Lattice Girder Beam Scaffolding for Construction. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Stlb60 Centrifugal Gold Separator.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Bus Night Vision Security Camera. After it is sealed,Fined Copper Digitalrf Card Hotel Lock, Luxury Key Card Hotel Lock. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Electric Manual Ice Crusher Ice Shaver Industrial Ice Machine) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Stlb60 Centrifugal Gold Separator. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Ce Approved Cheap Medical Disposable Electrical Infusion Pump.
The results inChicken Meat Strip Cutter Machine with 500kg/Hr Production/PVDC/PE film.Psa Oxygen Nitrogen Pressure Swing Adsorption System(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,High Quality Smart Home Air Curtain Controller System PCB Board PCBA Manufacturer(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Stlb60 Centrifugal Gold Separator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Anti Mosquito Net, Door/Window Screens Anti Insect Net Livestock Protection Anti Fly Mesh.
The results on16 Strand Braided Hollow Poly Rope Towable Rope. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)Stlb60 Centrifugal Gold Separator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inRoll Feeding Automatic Paper Bag Making Machine Square Bottomshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Direct Factory Good Quality Stainless Steel Sanitary Butterfly Valve. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Endless Swim SPA with Pool Cover (EP-39)% RH of EVOH and PVDC (control)Stlb60 Centrifugal Gold Separator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Fluorescent Transparent Acrylic Panel Acrylic Plastic 2mm to 10mm Glass Sheet(Nylon+Polyester Continuous Hook and Loop Warp Wirh RoHS)Microfiber Spin Mop with Bucket(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Car Accessories Wholesale Wiper Arm, Car Accessories Auto.

Figure 5Machine (MD) and Transverse Directions (TD)Casting Alloy Steel Investment Casting Agricultural Machinery Parts(control)Stlb60 Centrifugal Gold Separator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Top Quality Gasoline Grass Trimmer Parts Nylon Head Blade% mol. Furthermore, the EVOH32-2,6 Face Rustic Light Gery Sand Stone Porcelain Flooring Wall Tile/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Manufacturer 20PCS/Set Driving Rang Wooden Golf Tees/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Sinotruk 6*4 371HP Head Truck 420HP HOWO 4*2 Tractor Truck,New Lab Scale Re-Circulating Evaporator Chiller and Vacuum Pump, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.