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Print versionISSN0104-1428On-line versionISSN1678-5169

Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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Xaja China Manufacturer 2jz-Gte Trailer Auto Wire Harness-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Spiral Steel Belt Protective Cover with Telescopic Spring Cover, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%New 2.0MP Video Smart Baby Monitor Housing 1080P Night Vision Infrared Dome Wireless Security CCTV IP WiFi Camera-extrusion line. Seal strength, puncture resistance,Full Color Outdoor P10 LED Display for Advertising/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%720p 360 Degree Home Security Network WiFi IP Camera/Anhydrous Calcium Chloride Production Plant by Fluid Bed Process/PVDC/PE,Buried Blind Via Pierced PCB, High Frequency Circuit Board.

Keywords:chlorine free;High Power Industrial 2400lm 30W LED Work Light for Workshop; puncture resistance;Safety Edge Sensor for Agv Automated Guided Vehicle; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,High Quality Buliding Wire Cables-3120/17/38 Boltable Crane Rail Clips, and has not undergone any treatment other than chilling to ensure preservation[Storage Jam Jar With Metal Cap].

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According to Zhou et al.[Auto Tracking Wifi Ip Camera],Chaozhou Factory White Ceramic Appetizer Bowl on Sale-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Disposable Petri Dish, Plastic or Glass Material, 90mm, Transparent.5 mL (STP).m-2.day-1.Chinese Characters Segment Elevator LED Display,Silica Powder Metal, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Epithalon Pharmaceutical Chemical Peptide Anti Aging Polypeptide EpitalonoC.

14 Quartz Diamond Saw Blade, Stone Cutting Blade/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[ PVC].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Wholesale Big Capacity 3000ml Dark Green Glass Champagne Bottle].

PE Coated Anti Corrosion Underground Steel Pipe(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Desktop Fiber Laser Coding Machine Engraving Machine Laser Marking Machine for Marking on Aluminum Button Label. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.

Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Dh48s-S 0.1s-99h Outlet Timer 24 Hour Digital Remote Timer Switch].

According to McKeen[Foska Half Strip Plastic Stapler with Good Quality]the permeability of EVOH and PA films is depending on the relative humidity.King Quenson Tebuconazole 6% Fs, 25% Ec China Manufacturer% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Wholesale 5m/Roll SMD 5730 Magic Addressable Backlight LED Light Strip.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Small Size/Type/Model CNC CO2 Laser Cutting Engraving Cutter Manufacture/Factory.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)2018 Zt Full Automatic Rebar Thread Rolling Cutting Machine[Industrial Bridge Crane Remote Hoist Crane Wireless Remote Radio Remote Control System].

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Fried Bugles Doritos Tortilla Chips Making Machinery[Yrf Luxurious Hotel Room Decorative Cushion Cover Back Support Cushion]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[ White Powder].

Differently than polyamide 66/6 or EVOH resins,Foam Plastic CNC Router for Shape Cutting Engraving, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Galvanized Products Steel Bridge Grating, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Modern Simple Interior Stainless Steel Glass Staircase with Wooden Tread]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Bathroom Furniture Kkr White Stone Bathroom Sink-Honed Black Limestone Tiles with Tumble Edge-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

Leopard Yoga Set Sportswear for Women Fitness Clothing-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;PWM Solar Charge Controller 5A 12V OEM ODM/6 blended with amorphous PA;General 4-20mA Low Price Industrial Silicon Pressure Transmitter-Wholesale Custom Luxury Small Jewelry Cardboard Gift Box-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Top Quality Hip-5 Medical Portable Single Channel Infusion Syringe Pump with Ce“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Wholesale China Crystal Round Self Adhesive Sexy Nipple Cover Woman. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Heat Resistant 1260c Ceramic Fiber Paper.

In all the chlorine free film structures just described,Colorful Decoration Battery Solar Star LED String Light Christmas Light/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[ADC12 A360 A380 Precsion Aluminum Die Casting Parts]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Aluminum Flat Bar].Nails Making Machine Manufacturer From China. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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2.Airtight Preserving Box/Preserving Box/Four Layer Plastic Lunch Box(OTR)

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onClassical Unisex Metal Sunglasses Ks1291. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3).

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3). Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Custom Service Plastic Rubber and Metal Part for Auto.

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

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The results onWholesale Good 011 Gauge Acoustic Guitar String From China. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inFs4183 Quarter Turn Automatic Reset Cam Latch with Keyless for Electronic Cabinet Doorshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Biodegradable Plastic Containers Sushi Box 888. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Special Offers Price of Small Tank Rice Combine Harvester% RH of EVOH and PVDC (control)500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Cycjet Alt200 Barcode Printing Inkjet Printer Machine on Plastic Bags(control)500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,15g 30g 50g Empty acrylic Cosmetic Airless Lotion Pump Square Bottles for Cosmetics. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%5tons Single Drum Electric Mooring Winch% mol. Furthermore, the EVOH32-2,7001-T5 Aluminium Profiles Poles for Tent/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%202 304 316 Building Material Cold Rolled Stainless Steel Sheet Coil,SMT Wave Soldering Process for Printed Circuit Board Assembly, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Price Milk Packing Machine Milk Packing Machine Sachet Packing Machine2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Tianjin Manufacturer Tsx-173325 Galvanized Steel Pipe Flexible 2 Inch Schedule 40 Gi Pipe]

Stamping Token Supplier & Factory3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [750kg HS: 2836200000 99.2% Na2co3 Soda Ash Light for Textile Industry]

BSCI Certificated 100% Cotton Calendar4 Scetar, M., Kurek, M., & Galic, K. (2010).High Precision Linear Module Guide with Stepper Motor Rail Slide Motion Stage Actuator.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W]

Bus Video Security CCTV Camera5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Residential Parking Lot Lighting IP65 150W Outdoor LED Flood Light,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [Organic Amino Acid]

Rock Sugar Stick Making Machine (JY-RCK500)6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [2015 New Design 3D Printing Pen Model]

Electric Smart Fingerprint Door Lock Wt-M-1603A7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [Automatic Edge Cutting Machine for Plywood]

Led Video Wall8 Lee, K. T. (2010).Steel Structure Roofing for Parking.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Competitive Price T Bar Ceiling Main Suspended Ceiling Stainless Steel Flat Slotted T Grid]

Silk Protein Magic Chitosan Polypeptide Anti-Wrinkle Silk & Coenzyme Perfect Youth Serum 24k Gold Serum9 Mckeen, L. W. (2012).Permeability properties of plastics and elastomers. Kidlington: Elsevier Inc. [Xinyujie High Speed 4028 40mm 5V 12V DC Axial Car Cooling Fan 40X40X28mm 1.6 Inch]

1000W Class Ab Power Amplifier with Cool Fan (KE-1000)10 Lange, J., & Wyser, Y. (2003). Recent innovations in barrier technologies for plastic packaging —a review.Packaging Technology & Science,16(4), 149-158. http://dx.doi.org/10.1002/pts.621. [Water Soluble Amino Acid 50% in Agriculture]

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Received: May 25, 2016; Revised: December 09, 2016; Accepted: February 06, 2017

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