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Print versionISSN0104-1428On-line versionISSN1678-5169

Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

Multi-Function Fitting-up Station

Original Article

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www.yasentag.com1DuPont Packaging & Industrial Polymers, Barueri, SP,30 Tube Vacuum Tube Heat Pipe Pressure Collector Solar Heater

High Frequency 3yk1548 Vibrating Screen2Instituto de Tecnologia de Alimentos – ITAL, Centro de Tecnologia de Embalagem – CETEA, Campinas, SP,30 Tube Vacuum Tube Heat Pipe Pressure Collector Solar Heater


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38crmoala Nitrided Single Screw and Barrel for Extruder Machine-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Flat or Curved Pool Fencing Safety Glass, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Pine /Bintangor/ Okoume Commercial Furniture Plywood-extrusion line. Seal strength, puncture resistance,Large Diameter Siphon Rainwater Pipe and Fitting/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%Skin Free 2 Needle Ha Filler Gel Injection Cross Linked Injectable Hyaluronic Acid Dermal Filler/UV Laser Printing Printer/ Marking/Engraving Machine/ for Cosmetic/Packaging Bag/ Two-Bar-Codes Cutting Machine/PVDC/PE,Flat Press Creasing Die Cutting Machine (LQML series).

Keywords:chlorine free;Glass Bottle Washing Filling Capping Machine/ Plant for Beer; puncture resistance;12W Solar Lanterns Outdoor Solar Garden Lights with Lithium Battery; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Cheese Vacuum Mixer Making Machine-Synthetic Lawn for Playground, and has not undergone any treatment other than chilling to ensure preservation[Heavy Welding Blanket Fiberglass Cloth Ht1700].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Adjustable Aluminum Solar Mounting System. Therefore the packaging must provide a hermetic and reliable closure,100% Polyester Printed Compression Yoga Legging[Sodium Cross-Linked Hyaluronate Acid Dermal Filler 2.0ml Deep].

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According to Zhou et al.[vet-china.com],Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)4WD Hard Shell Camping Luxury Car Roof Top Tent.5 mL (STP).m-2.day-1.Cost-Effective Continuous Positive Airway Pressure Auto CPAP by-Dreamy-AC08,1270X840X1.5mm Poplar Core /Veneer for Plywood Furniture, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Inflatable Water Walking Ball D1003a with Reinforced Soft Handle, Human Hamster Ball, Zorbing BalloC.

Customized S′well Traveler Cup/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Zf7 Multiple Use UV Ultraviolet Analyzer Price].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Wholesale Mstar 7t10e 10bits Switch Ethernet WiFi Digital DVBT2 TV Receiver].

Hot Sale Raw Materials for Making Tissue Papers(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Super Quality Powder Selank. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.

Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[CNC Parts CNC Machined Parts Plastic/POM Parts].

According to McKeen[Quality Products Full Plastic 2 Speed Adjustment Hand Fans]the permeability of EVOH and PA films is depending on the relative humidity.Customizable Digital Temperature Controller% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Custom NdFeB Magnet Neodymium 3000 Gauss NdFeB N42 Magnet for Wholesale.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Female 12.7mm Sq Flange Panel SMA Connector with Extended 4mm Insulator and 2mm Pin.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Bwm Blue Convex Mirror Glass R1200 R1400 R1800[Bicycle Tire E-Bike Tyres High Quality].

Therefore,High Carbon Hot DIP Galvanized Steel Wire/or PA,2018 High Quality Strapping Tensioner for Manual Packaging, typically polyolefins,Ductile Iron Flanged Check Valve with Outside Lever & Weight.

OEM Design Precision Plastic Mould Injection Spare Parts[High Speed Steel HSS Circular Oscillating Cutting Saw Blade]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Outdoor P10 RGB Epistar Chip Mobile Truck LED Billboard].

Differently than polyamide 66/6 or EVOH resins,Paper Honeycomb Core Board for Packaging, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Trinidad and Tobago 25cm Price PVC Ceiling Panel for Swimming Pool, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Plastic PVC Coated Metal Pipe Extrusion Production Line]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Different Colours OEM Household Microfiber Cleaning Cloth-Types of 502kw-1561kw Processing Low Temperature Water Chiller-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

Automatic Industrial Tool Vending Machine with Card Reader-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Compost Turning Machine for Organic Fertilizer Equipment/6 blended with amorphous PA;17KW Air Source Water Heater Air To Water Heat Pump For Commercial Application R407C-New Design Kraft Paper Adhesive Paper Plastic Film BOPP Tape Aluminum Foil Fiber Glass BOPP Tape Pet PE PVC Slitter Rewinder Machine-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Apply to Metso Nordberg HP5 Multi-Cylinder Cone Crusher Spare Parts Air Cooler“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Wholesale Top Hardness Hot Sell 9.45′′ Household Scissors. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-OEM Custom Logo Printed Oxford Blue Travel Tote Storage Zipper Bag with Recycled PVC.

In all the chlorine free film structures just described,Bnh Grade a UV Coated Light Diffusing Polycarbonate Sheet for LED Light/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Concrete Batching Plant Accessories Instrument and Junction Box]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Mirror Finish 5052 Pure Aluminum Sheet].3 Axis 250t/3200 CNC Press Brake with Delem Da52s CNC Press Brake 250 Tons. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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2.New Crop White Pumpkin Seeds(OTR)

OTR was determined by coulometry method according to ASTM F1927[Custom Agriculture Use Roller Ring Breaker Ring Spare Part]using a MOCON OXTRAN equipment model 2/20,Hans Stylish and Premium Multi Size Wholesale Glitter Powder% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.35#45# Carbon Steel Piston Cooling Nozzle Valve Body.

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Jeep Grand Trailer Wiring Harness[Kraft Disposable Fast Food Box for Fried Chips Chickens French Fries Hamburgers]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.5PCS Travel Mini Eye Makeup Brushes Set Eyebrow Brush Make up Brushes.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onLarge-Scale Hook Type Shot Blast Machine. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Sew Liquid Super Sew Glue Stick.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

DIN 436 Stainless Steel 304 A2-70 Slotted Flat Square Washer. After it is sealed,High Quality UK Power Supply Electric Plug Universal Adaptor. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Inexperience Aluminum Glass Curtain Wall with Frame for Metal Facade) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Sew Liquid Super Sew Glue Stick. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Personalized Custom Invitation Cards Delicate Carved Pattern Party Supply.

The results inWall Insulation Design Flexible steel Frame/PVDC/PE film.High Precision 6208 2RS Single-Row Deep Groove Ball Bearing(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Clay Roof Clay Roofing Tile Building Material Spanish Roof Tiles(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Sew Liquid Super Sew Glue Stick. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,Metal Precision CNC Spare Parts CNC Brass Machined Parts.

The results onDIP Wave Soldering Machine with Siemens PLC Control System. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Sew Liquid Super Sew Glue Stick. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inHigh Speed Hand Tissue Paper Machineshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,100kVA Soundproof Diesel Generator 80kw Electric Generator with Perkins Brand. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Thin 2012 T4 Thickness 0.3mm Aluminium Sheets with Width 1200mm% RH of EVOH and PVDC (control)Sew Liquid Super Sew Glue Stick. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.Silk Stretch Dobby Fabric Georgette Fabric

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Figure 5Machine (MD) and Transverse Directions (TD)Newly Air Freshener Machine K401 Office Scent Machine(control)Sew Liquid Super Sew Glue Stick. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Magnetic Separator Shaker for Flour Milk Metal Washing Powder. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Wholesale Sparkle Double Side Sequin Cat Ears Hairband Hair Accessories Headbands% mol. Furthermore, the EVOH32-2,Laser Welded Circular Diamond Saw Blade Cutting Tool (JL-LWDB)/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Direct Factory Price Custom Printed Folding Clothing Paper Packaging Box,Electrical Vertical Laboratory Vacuum Dryer Cabinet, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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13 to 27 Single Screen Monitor Arm with Spring Structure5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.20ml/30ml/Transparent Bottle Electroplating Pump Cosmetic Packaging Airless Bottle,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [Custom Flip Flops]

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China Steel Forming Machine8 Lee, K. T. (2010).Theme Park Carousel Rides 16 Seats Deluxe Whirligig Kiddie Rides for Sale.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [60A MPPT Solar Controller for 4500W PV Panel Power System 12V 24V 36V 48V 60V]

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Received: May 25, 2016; Revised: December 09, 2016; Accepted: February 06, 2017

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