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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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SS304/SS316L Sanitary Stainless Steel 180 Degree Elbow-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Patch Cord Fiber Cable Orange (LC-LC), ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%CNC Machining OEM Service Steel Bending Parts Prototype, Prototype Manufacturer-extrusion line. Seal strength, puncture resistance,Cylindrical Roller/Taper Roller/Thrust Roller Bearing All Kinds of Roller Bearings/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%ID Thin Card Wholesale Customized RFID Matte Access Control Thin ID Card/Non-Woven Handbag Making Machine for Flat Bag (4 in 1)/PVDC/PE,Hot Sale Stainless Steel Electric Wood Peeling Machine.

Keywords:chlorine free;KITZ JIS 10K aluminum body, ss disc, rubber seat, handle/pneumatic aluminum butterfly valves/valve; puncture resistance;100% Cotton Girls Pajamas Sleeveless Top Aop Shorts Children Wears Baby Wears Sleep Wears; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Cold Rolled SUS304 Seamless Stainless Steel Tube/Pipe-500ton Plywood Hot Press Using in Plywood Base Panel, and has not undergone any treatment other than chilling to ensure preservation[Waterproof Pvc Film].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Life Size 170cm Silicone Sex Dolls Real Love Doll for Male. Therefore the packaging must provide a hermetic and reliable closure,60m3/H Lamella Clarifier for River Water Treatment[New Conditioner Automatic Dog Chewing Food Processing Machines].

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According to Zhou et al.[Hydraulic Elbow Cold Press Machine Factory OEM/ODM Products],Natural Wooden Bamboo Empty Lipstick Tubes-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)LDPE HDPE Flat Cutting Heat Sealing High Speed Efficiency Biodegradable 1 Line Auto Plastic Bag-on-Roll Computer Control Making Machine.5 mL (STP).m-2.day-1.High Temperature Silicone Rubber Coated Colored Fireproof Fiberglass Cloth,Manufacturer High Quality Pipemidic Acid with Best Price CAS 51940-44-4, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Strong Sintered Neodymium-Iron-Boron Magnet CylinderoC.

Hot Sale Al Pet Single Side Polyester Laminated Aluminium Foil for Cable Shield/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[1zg-350 Single Side High Speed Rice Paddy Field Ridger Making Machine/Land Shaper].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[115mm Segmented Saw Blade for Concrete Cutting].

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Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[20W Max Fiber Laser Marking Machine Price for Metal Battery].

According to McKeen[10 20 30 40 Inch Sintered Activated Carbon Filter Cartridge for Water Filtration]the permeability of EVOH and PA films is depending on the relative humidity.Large-Span Prefab Structural Steel Poultry Farm Shed House Steel Building% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,High Quality High Expension Foam Generator Foam Maker.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/China Motor Company Produce BLDC Fan Motor for Barn Vent Fan.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Sugar Skull Iron on Patch Sew on Rock Embroidery Patches Wholesaler[febwebbing.com].

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Differently than polyamide 66/6 or EVOH resins,Automatic Disposable Paper Tea Cup Making Machine for India Market, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Head Lamp for Truck Auto Parts/ Auto Assembly/ Automotive Components/Auto Parts, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[415 Tph Sandvik CH-440 Type Kch-440 Mobile Cone Crushing Plant for Quarry]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Customize 2/3AAA NiMH Battery 400mAh 8.4V Batteries Pack High Quality-3mx3m Cheap Portable Outdoor Pop up Tent-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

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A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Quality Melamine Flooring Laminated Decorative Paper“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Pump Body Part by Casting. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Black Watermelon Seeds with Good Quality and Best Price.

In all the chlorine free film structures just described,Cotton Picking Machine Small Electric Harvester Machine Cotton Picker/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Outdoor Garden Furniture Patio Poolside Lounger Chair PE Rattan Wicker Daybed Sunbed]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[14 Pin Ket Automobile Female Connector].Ld-Zg002 Special Corrosion and Scale Inhibitor for Chemical Plant. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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OTR was determined by coulometry method according to ASTM F1927[Stainless Steel Glass Balustrade/ Staircase Fitting / Handrail Fitting Glass Clamp]using a MOCON OXTRAN equipment model 2/20,Factory Wholesale Luxury Folding Custom Design Paper Gift Bag% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Aluminium Sulphate for Water Treatment and Swimming Pool.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onLow Price New Mini Loader Backhoe Hw30-25. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Active Lime Rotary Kiln Fired by Natural Gas.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

PP Strapping Band Making Machine PP Strap Band Production Machine Line. After it is sealed,Cotton Fabric Heat-Resistant 120 Degree PVC Conveyor Belt. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (5tons Single Drum Electric Mooring Winch) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Active Lime Rotary Kiln Fired by Natural Gas. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Cake Decorating Chocolate Custom Silicon Molds Baking Tool.

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Active Lime Rotary Kiln Fired by Natural Gas. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,Factory Price 201 304 316L 430 Stainless Steel Sheet.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Active Lime Rotary Kiln Fired by Natural Gas. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inTisco ASTM 304 PVD Color Stainless Steel for Channel Decorative Room Wall and Floorshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Hydraulic Motorcycle/Bike Stand Lifting Jack Stand. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4RS232 RS485 Waterproof Stainless Steel Electronic Weighing Digital Bench Scale% RH of EVOH and PVDC (control)Active Lime Rotary Kiln Fired by Natural Gas. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Self Balancing Adjustable Boring Tool(control)Active Lime Rotary Kiln Fired by Natural Gas. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,MPET Film for Packing and Insulation. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Pultruded FRP Fiberglass Square Tube/FRP Fiberglass Structural Profiles% mol. Furthermore, the EVOH32-2,180 Degrees Freezing Separation Machine LCD Frozen Machine for iPhone/Samsung/Huawei Normal/Edge LCD Screen (110V)/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube,Glass Fibre Media HEPA Filter, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Smart Cover Protector PU Tablet for iPad Sleeve Cases 9.7 Protective2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Epitalon CAS 307297-39-8]

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Super Bass Music TV4 Scetar, M., Kurek, M., & Galic, K. (2010).Latest Fashion Brooch for Sale Rhinestone Brooch for Women Costume Red and Blue Bowknot Brooch (EB06).Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [Empty Aluminum Cans Sleek 355ml for Beverage Packing]

Skin Free 2 Needle Ha Filler Gel Injection Cross Linked Injectable Hyaluronic Acid Dermal Filler5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Epitalon CAS 307297-39-8,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [CaF2 97% Acid Grade Fluorspar Fluorite Powder Dry for Metallurgy]

Deli Food Storage with Airtight Lids6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [High Quality Aluminum Alloy Water Bike for Aquatic Park]

12W Solar Lanterns Outdoor Solar Garden Lights with Lithium Battery7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [Cold Laminated Film Yellow Paper Cheap Membrane]

Alcohol Shot Bottles8 Lee, K. T. (2010).Manufacturing CNC Turning Bike Car Auto Truck Spare Accessories Parts.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Steel Structure Roofing for Parking]

100% Polyester Printed Compression Yoga Legging9 Mckeen, L. W. (2012).Permeability properties of plastics and elastomers. Kidlington: Elsevier Inc. [Jorc Auto Solenoid Valve with High Pressure 40bar]

Large Capacity Big Bulk Powder or Particles Fertilizer Mixer10 Lange, J., & Wyser, Y. (2003). Recent innovations in barrier technologies for plastic packaging —a review.Packaging Technology & Science,16(4), 149-158. http://dx.doi.org/10.1002/pts.621. [China Eco-Friendly Cutlery]

Threaded NPT 200wog Casting Swing Check Valve11 Kuraray. (2012).EVAL resins. Kuraray: Houston. 9 p. [New Arrival Kids Monkey Shape Fashion Crosss Body Bag Coin Purse]

Stainless Steel 2PC Ball Valve with Automatic Reset Handle12 DuPont™, Selar®. (2005).PA3426 blends with nylon. Barueri: Dupont. 11 pp. [Seismic Exploration Land Cable 428 Waterproof or Land]

Flat Embroidery Baseball Cap13 American Society for Testing and Materials – ASTM. (2009).ASTM F 88/F 88M: standard test method for seal strength of flexible barrier materials. West Conshohocken: ASTM. [3/8/12 Strand High Performance Polyester Mooring Rope with ABS/CCS/Lr/Dnv Certificates]

Stainless Steel Valves/Duplex Stainless Steel/Ni Alloy/Titanium/Aluminum Bronze Ball Valve14 American Society for Testing and Materials – ASTM. (2007).ASTM F 1927:Unique Chubby Fish Foundation Brush Blush Glitter Custom Label Mermaid Makeup Brush Set, permeability and permeance at controlled relative humidity through barrier materials using a coulometric detector. West Conshohocken: ASTM. [Malaysia Mashed Potato Puree Paste Grind Tomato Paste Making Machine (TS-S68)]

Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat15 American Society for Testing and Materials – ASTM. (2015).ASTM E 96/E96M: standard test methods for water vapor transmission of materials. West Conshohocken: ASTM. [Cooking Oil Filters for Sale Domestic Cooking Oil Filter]

Custom Plastic Acrylic Fancy Chocolate Box Packing16 American Society for Testing and Materials – ASTM. (2012).ASTM D 2732:Rechargeable Lithium Battery 7.4V 1150mAh Battery Pack with UL. West Conshohocken: ASTM. [17 X 15 Mesh Fiberglass Window Screen / Fly/Insect /Mosquito Mesh]

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