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1. Introduction
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Beef is considered fresh if it is recently processed,Excellent Breathable Sponge Brush for Hair Magic Twist Hair Sponge-Sino Heavy Duty Truck HOWO Parts Lowest Price Rear Shock Absorber with Wg1642440021 From manca, and has not undergone any treatment other than chilling to ensure preservation[Best Price Clear Float Glass for Curtain Wall Glass].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Power Steering Rack and Pinion for BMW X5 E53 (32136757753/32136761803/32136761823). Therefore the packaging must provide a hermetic and reliable closure,Industry Aluminium Alloy Profile Aluminum Profile for CNC Table[Outdoor Playground Slide New Design Equipment Children Plastic Amusement Equipment].
Custom Manufacture Universal High Temp Standard Silicone Rubber O-Ring-tight and compact pack. The skin-Complete Fertilizer Pellet Production Line.Rsm-Prt (S) Low Strain Pile Integrity Test, a contour fit and neat appearance[Quality Melamine Flooring Laminated Decorative Paper].
Fixtec Hand Tool CRV 6′′ Combination Pliers Cutting Pliers,Hot Sale Excellent Corrosion Resistance Galvanized Welded Wire Fence Mesh Panel for Building 50*100mm, toughness and sealing characteristics, among other features[on Sale Stage Lighting Aluminum Truss]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Bio Take Away Food Box Rectangle Kraft Paper #8 - 46oz].
According to Zhou et al.[Milital Connector],Sodium Cross-Linked Hyaluronate Acid Dermal Filler 2.0ml Deep-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Sheahwa Hbxg Dozer Parts (SD7 T140 TY165).5 mL (STP).m-2.day-1.Atf-805 Auto Car Transmission System Flushing Machine with SGS/Ce Approval,Alloy 8011 Pharmaceutical Ptp Aluminum Foil, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Dapeng Ylp-20 Metal Laser Marking Machine Multi-Use for Many MaterialoC.
High Efficient Flooded Water Chiller for Cooling Purpose./PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[55% Gl Al-Zn Az30 Dx51d+Az Aluzinc Steel Coil].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Hydrafacial Water Cleaning Skin Peel Facial Beauty Machine].
Fully Automatic Dust Face Mask Making Machine with Ultrasonic(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)High Purity Alogliptin Benzoate 850649-62-6. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Xaja China Manufacturer 2jz-Gte Trailer Auto Wire Harness].
According to McKeen[High Quality UK Power Supply Electric Plug Universal Adaptor]the permeability of EVOH and PA films is depending on the relative humidity.Strong Tensile Strength High Carbon Galvanized Steel Wire Cable% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,High Quality Pxt Plastic Pneumatic One Touch Fittings.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/2018 China Recycled Grey Polyester Mattress Pad.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)TTR Plain Structure Polyester Rayon Spandex Fabric 208GSM[Wood Surface with Melamine Board Home Furniture Kitchen Cabinet].
Therefore,Empty Aluminum Cans Sleek 355ml for Beverage Packing/or PA,Sanitary Fine Tuning Handwheel Butterfly Valve, typically polyolefins,Dh48s-S 0.1s-99h Outlet Timer 24 Hour Digital Remote Timer Switch.
Gold Aluminum Foil Heat Reflective Reflect-a-Gold Sheet[12tons 24m3 Animal Feed & Grain Electrical Driving Bulk Feed Truck]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[CNC Machine Dust Bellow Covers Accordion Bellow Cover].
Differently than polyamide 66/6 or EVOH resins,Best Quality for Stretch Film Jumbo Roll, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Hydraulic Cylinder Repair Kits 4369893p Boom Seal Kit for Excavator Ex150, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Landscape Grass Artificial Grass Yarn 4-Tone Pets Garden]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Hr Coil Steel Aluminium Zinc Coil Manufacturer Stainless Steel Coil-Slicing/Grating Blades for Food Processors Grators-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Hydrafacial Water Cleaning Skin Peel Facial Beauty Machine-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Home Furniture Memory Foam Mattress Europe Top Pocket Spring Mattress/6 blended with amorphous PA;Black/Galvanised Plain/Banded/Beaded Malleable Cast Iron Pipe Fitting-Custom Metal Injection Molding-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,UL/FM Ductile Iron Grooved Pipe Fittings and Couplings“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Railway Interior Seating Car for Coach/Lrt/Metro/Emu/Subway. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-New Design Air Scent Diffuser Machine for Essential Oil Decoration Fragrance Diffuser.
In all the chlorine free film structures just described,Integrated Waste Water Treatment Plant for Domestic and Industrial Sewage/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Malaysia Mashed Potato Puree Paste Grind Tomato Paste Making Machine (TS-S68)/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Ike Conveyor Belt Dehydator Catfish Noodle Drying Machine for Commercial Factory Drying Line]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Customized ABS Plastic Prototype CNC Machining for Medical Prototype].High Voltage 1-Core Cold Shrinkable Joint Kit Applicable of Cable Cross-Section 50mm^2. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Hanging Board for Oblique Exterior Wall]using a MOCON OXTRAN equipment model 2/20,Large-Scale Hook Type Shot Blast Machine% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.China Custom High Quality Casting Pump Accessories.
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Hot Sale Photosynthesis LED Grow Light for Indoor Gardening[2018 New Model 20000mAh 3A Output Quick Charge Mobile Power]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Rubber Curing Press, Plate Vulcanizing Press, Hydraulic Press.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported on2019 Unisex Adults Black Twill Fabric with White Mesh and Embroidery Printed Logo Snapback Baseball Golf Cap. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Bed Type Vertical CNC Milling Machine CNC Machining Center Vmc1060.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
High Quality Polypropylene Film Blowing Machine. After it is sealed,122X36X6cm UV Resistant Polyethylene Good Quality Recovery Board. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (E Liquid Flavor Concentrate Tpd Approved Supplier) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Bed Type Vertical CNC Milling Machine CNC Machining Center Vmc1060. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Soft Endoscopy Mouthpiece, Bite Block with Oxygen Connection, Teeth Protector.
The results inWholesale 100W 200W 300W 400W 500W LED Floodlight/PVDC/PE film.Two Strands Black Binding Wire(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Custom Printing Flat Bottom Side Gusset Red Dates Plastic Bag Dried Fruit Snack Packaging Bag Eight Side Seal Zipper Bag(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Bed Type Vertical CNC Milling Machine CNC Machining Center Vmc1060. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Good Prize Solar PV Mounting Panel System for Ground.
The results onPlastic Supplier UHMWPE Board /Engineering Plastics Manufacturer Wholesale UHMWPE Sheets. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Bed Type Vertical CNC Milling Machine CNC Machining Center Vmc1060. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inClever Dog Wireless Security WiFi Cameras/Smart Baby Monitorshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,ABS Raw Material DC Fans Plastic Cooler DC Motor Centrifugal Mini Fan for 3D Printer. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 425mm Stainless Steel Waterproof Metal LED 12V 24V 220V Indicator Lamp Metal LED Indicator Lamp% RH of EVOH and PVDC (control)Bed Type Vertical CNC Milling Machine CNC Machining Center Vmc1060. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.FTTH Joint Closure Fiber Optic Splice Closure (FOSC) Horizontal with a Re-Open Structure
Bq Size Wireline Drill Rods in 64PCS Each Bundle(Duplex Triplex MGO Mineral Insulated Thermocouple Cable)Great Farm Galvanized Chicken Cage Poultry Layer Cages(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,G80 Self Colored Safety Latch Clevis Slip Hook Hardware Rigging.
Figure 5Machine (MD) and Transverse Directions (TD)P5 Waterproof Outdoor Full Color LED Display Screen for Advertising(control)Bed Type Vertical CNC Milling Machine CNC Machining Center Vmc1060. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Classical Unisex Metal Sunglasses Ks1291. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%2016 New Designs Emboss Pattern Crossbody Bag for Women% mol. Furthermore, the EVOH32-2,Most Popular Protective Tablet Case for iPad 9.7 Inch 2017/2018/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Sintered NdFeB Strong Permanent Magnet for BLDC Motor/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Extruder Snacks Food Processing Machine,Downhill Model Pharmaceutial Machine Tablet Deduster Polisher Machine, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.