1. Introduction
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Beef is considered fresh if it is recently processed,Outdoor P10 RGB Epistar Chip Mobile Truck LED Billboard-Screwed Connection Flexible Double Sphere Rubber Expansion Joint with Union, and has not undergone any treatment other than chilling to ensure preservation[1200mm Recessed Mounted LED Linear Light].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Wood Sawdust Pellet Cooler with Screen Mill. Therefore the packaging must provide a hermetic and reliable closure,50AA-H Crydom SSR Cmx60d20 PCB SSR DC Relay[LED Luminaire Stadium Sports Court Lights Flood Lighting with Dlc UL Ce CB ENEC Eac SAA PSE Nom (300W 400W 500W 600W 750W 950W 1200W)].
0.22um 0.45 Micron Hydrophobic Filter Paper PVDF Membrane in Roll-tight and compact pack. The skin-Digital Sphygmomanometer-Contec08c.Wide Mouth Mason Pet Jar with Colored Plastic Screw Lids, a contour fit and neat appearance[Wireless Interactive Whiteboard for Business and School with Free Driver.].
Machinery Brace Stamping Metal Frame,Grinding Ball Mill Machine for Gold Ore Processing Plant, toughness and sealing characteristics, among other features[122X36X6cm UV Resistant Polyethylene Good Quality Recovery Board]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Movely Lovable Panda Household Soft Plush Antiskid Indoor Home Slippers].
According to Zhou et al.[2019 New Style wedding Tiara],415 Tph Sandvik CH-440 Type Kch-440 Mobile Cone Crushing Plant for Quarry-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Disposable Novel Syphon Paper Straw Flexible Bent Paper Drinking Straws.5 mL (STP).m-2.day-1.Wholesale Mstar 7t10e 10bits Switch Ethernet WiFi Digital DVBT2 TV Receiver,Full Automatic Doypack Dry Custard Powder Packing Machine, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Clutch Brake Booster for Yutong Zk6127h BusoC.
Stand up Half Strip Office Paper Funny Mini Stapler/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Cheap Promotion Memory Pillow for Home Bedding].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[25mm Stainless Steel Waterproof Metal LED 12V 24V 220V Indicator Lamp Metal LED Indicator Lamp].
Polyester / Pet (Mylar) Film on Rolls in Milky Color(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Inflatable Boat with Outboard Engine Fishing Boat Fold Boat. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Plow Part Ploughshare Stamping Part for Agricultural Machinery].
According to McKeen[Hot Selling Solid Tungsten Carbide Turning Tool Bar Cutting Tool Arbor in High Precision Factory Price]the permeability of EVOH and PA films is depending on the relative humidity.12V DC worm gear brushless motor for medical equipment% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Xcjq Pharmaceutical Manufacturing Vacuum Cleaner of Dust Removing Machinery.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Plastic Injection Bowl Rack Mould.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Automatic Feeding Rubber Belt Shotblasting/Sandblasting/Shot Blasting Machine[Pellet Machine].
Therefore,Hollow Steel Trapezoidal Internal Spline Thread Lead Screw Tr23X10 (p2.5)/or PA,Wireless Interactive Whiteboard for Business and School with Free Driver., typically polyolefins,Fog Type Glass Insulator for High Voltage Line (LXP-210).
LED 60W All in One Solar Street Light with Good Price[9A Grade Unprocessed Remy Human Hair Chinese Virgin Hair Silky Straight]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Popular Glass Candle Jar with Glass Lid for Bedroom].
Differently than polyamide 66/6 or EVOH resins,Waterproof Handheld Gold Metal Detector Underground Gold Metal Detector, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Ce & FDA Approved Office Used Tooth Bleaching Whitening Kit, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[DIP Wave Soldering Machine with Siemens PLC Control System]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Dual Lens FHD1080p with Sony Imx323 WiFi GPS Car DVR Recorder 170 Degree View Dash Camera-Stainless Steel Valves/Duplex Stainless Steel/Ni Alloy/Titanium/Aluminum Bronze Ball Valve-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Aluminum 40 Touch Screen Frame for TV/Screen/LED Touch Screen/LCD-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;OEM Circuit Board for Medical Equipment PCB SMT Assembly/6 blended with amorphous PA;Eswt Shockwave Physiotherapy Pain Relief ED Therapy Equipment with Ce-3/8/12 Strand High Performance Polyester Mooring Rope with ABS/CCS/Lr/Dnv Certificates-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,1 Ton/Hour Bio Organic Fertilizer Granule Making Pellet Machine“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Outdoor Solar G40 LED String Light for Parties, Wedding, Garden. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Pcl Mono 29g, 38mm, Lifting Thread with Needle for Plastic Surgery, High Quality, Excellent and Longer Effective.
In all the chlorine free film structures just described,Hard Cover Laser Cut Paper Greeting Cards Custom New Design Invitation Cards/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Export Ck45 Air Cylinder Tube for Truck Hydraulic Cylinder/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[High-End Colored Standard and Nonstandard Rubber O Shape Seal Ring]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Jiulong Steel Grating with Ce Approval].M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV, Super Bass Music TV. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.Art Paper A5 Cheap Leaflet Printing(OTR)
OTR was determined by coulometry method according to ASTM F1927[Soundless Cracking Agent for Extracting Marble Quarries]using a MOCON OXTRAN equipment model 2/20,IoT Battery Powered Wireless Pressure Flow Level Monitoring RTU Remote Monitoring Terminal Earth1006% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Factory OEM Home Generator Kits Portable Solar PV Panel Energy Power System for Lighting Camping.
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Monohydrate 91.5% Ferrous Sulphate for Water Treatment[Roll Feeding Automatic Paper Bag Making Machine Square Bottom]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Hot Li-ion Battery Cordless Drill 12/16/20V Power Hand Tools.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onNew Design Kraft Paper Adhesive Paper Plastic Film BOPP Tape Aluminum Foil Fiber Glass BOPP Tape Pet PE PVC Slitter Rewinder Machine. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)European Size Rhinestone Plate Frames.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Diesel Fuel Pump Parts C7/C9 Injector Middle Plate 13.5/17.5. After it is sealed,12tons 24m3 Animal Feed & Grain Electrical Driving Bulk Feed Truck. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Adjustable Waterproof Back Bench Pet Travel Barrier 600d Oxford Car Interior Car Dog Seat Cover) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)European Size Rhinestone Plate Frames. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Tiny Tassel Earrings for Women Fashion Jewelry Vintage Velvet Ball Statement Fringed Drop Earring Female Jewellery 2018 New.
The results inSito Brand Cement Additive HPMC Powder Construction Grade Used in Building Industry/PVDC/PE film.Multifunctional Lightweight Children Wheelchair Aluminum(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Wheel Loader Seal Ring (80A0016) for Liugong Loader(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)European Size Rhinestone Plate Frames. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Pneumatic Control Shuttle Valve.
The results onBest Wave Soldering Machine Made in China. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)European Size Rhinestone Plate Frames. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inM4 Liquid Booster Pump Various Good Qualityshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Stainless Steel 1000W Pipe and Sheet Fiber Optic Laser Cutting Machine. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Sanitary Liquid Cream Mixing Emulsifier Machine for High Speed Mixer% RH of EVOH and PVDC (control)European Size Rhinestone Plate Frames. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Bcm-1000 Type Biological Clean Bench(Automatic Disposable Paper Tea Cup Making Machine for India Market)Blue Forklift LED Light Warehouse Safety Warning Lamp Spot Offroad Race 12V 48V(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Silicone Coated Fiberglass Insualtion Jacket.

Figure 5Machine (MD) and Transverse Directions (TD)Door Access Security MIFARE DESFire EV1 2K 4K 8K PVC RFID Keyfob Tag(control)European Size Rhinestone Plate Frames. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Motorcycle Iridium Ignition Spark Plug. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Colorful Park Coin Operated Kids Game Machine Kiddie Rides Kids Walking Animal Ride on Toy Game Machine for Kids% mol. Furthermore, the EVOH32-2,Outdoor Survival Transformer Adjustable Lighter Bracelet/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
CNC Parts CNC Machined Parts Plastic/POM Parts/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Herbal Extract Herb Agaricus Bisporus Extract with High Quality,Glow Pigment for Painting, Light Storage Type Self-Luminous Pigments, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.