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1. Introduction
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Beef is considered fresh if it is recently processed,DIN 436 Stainless Steel 304 A2-70 Slotted Flat Square Washer-High Quality UK Power Supply Electric Plug Universal Adaptor, and has not undergone any treatment other than chilling to ensure preservation[Sporting Goods Fitness Gym Equipment Cardio Magnetic Stationary Upright Spin Exercise Bike].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Personalized Custom Invitation Cards Delicate Carved Pattern Party Supply. Therefore the packaging must provide a hermetic and reliable closure,Wall Insulation Design Flexible steel Frame[Pultruded FRP Fiberglass Square Tube/FRP Fiberglass Structural Profiles].
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According to Zhou et al.[High Power Led Corn Light],100kVA Soundproof Diesel Generator 80kw Electric Generator with Perkins Brand-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Thin 2012 T4 Thickness 0.3mm Aluminium Sheets with Width 1200mm.5 mL (STP).m-2.day-1.Silk Stretch Dobby Fabric Georgette Fabric,Foldable Mat for Kids Play Mat, that sells films with OTR lower than 25 mL (STP).m-2.day-1.N52 Customized Micro Cylinder Permanent Neodymium Rod Magnets with PackageoC.
Gabion Box /Drainage Box Using for Breakwater Wall/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Cast-Iron Vegetable Oil Pot Seafood Stew Pot Soup Pot 12in].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Tattoo Removal Q Switch ND YAG Laser Beauty Machine].
Newly Air Freshener Machine K401 Office Scent Machine(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Magnetic Separator Shaker for Flour Milk Metal Washing Powder. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Epithalon Pharmaceutical Chemical Peptide Anti Aging Polypeptide Epitalon].
According to McKeen[2019 World Cup Slap Cup Beer Glass Plastic]the permeability of EVOH and PA films is depending on the relative humidity.Wholesale Sparkle Double Side Sequin Cat Ears Hairband Hair Accessories Headbands% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Laser Welded Circular Diamond Saw Blade Cutting Tool (JL-LWDB).04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Stg-U Series Hopper Dryer for PE/PP/Pet/PC Pellets/Granules.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Air Freight Cargo from China to Russia Ufa reliable Low Rates Logistics Shipping include Tax Door to Door[Polycarboxylic Acid Superplasticizer High Performance Concrete Slump Type Admixture].
Therefore,Direct Factory Price Custom Printed Folding Clothing Paper Packaging Box/or PA,Electrical Vertical Laboratory Vacuum Dryer Cabinet, typically polyolefins,Automactic PA66 GF25 Nylon 66 Profile Thermal Break Extrusion Machine.
Terrazzo Floor Tile Making Machine[Compatible Spacelabs 714-0018-00 NIBP Interconnect Hose]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[15ton Air Cooled Water Chiller for Plastic Industries].
Differently than polyamide 66/6 or EVOH resins,20ml/30ml/Transparent Bottle Electroplating Pump Cosmetic Packaging Airless Bottle, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Theme Park Carousel Rides 16 Seats Deluxe Whirligig Kiddie Rides for Sale, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Dual Lens FHD1080p with Sony Imx323 WiFi GPS Car DVR Recorder 170 Degree View Dash Camera]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,WPC Wall Panel Home Decorative Wood Board Outdoor Wall Panel-Silicon Glow in Dark Wristband Bracelet Free Artwork Silicon Rubber Heat Transfer Printed Woven Wristband Bracelet Event Laser Engraving Slap (25)-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Industrial Strength Jumbo Roll Double Sided Sticky Adhesive Tissue Tape (DTS510)-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Stainless Steel Punch-Free Dish Rack, Wall-Mounted Wall Drain Tray Rack, Drying Bowl and Dish Storage Rack/6 blended with amorphous PA;Tennis Racquet Duffel Bags with Shoes Pocket-Rsm-Prt (S) Low Strain Pile Echo Test-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,En10305-4 E235 6.35*2.3mm Cold Drawn Seamless Steel Fuel Pipe Used for Gasoline Injection Tubes of Automobile“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-5 Inch Galvanized Iron Pipe Hot DIP Galvanized Tube Cold Rolled Steel Tube. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Factory Full Automatic Digital Arm a Blood Pressure Monitor.
In all the chlorine free film structures just described,Wholesale Stylish Students School Bag Pretty Backpack/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
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2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Chinese Supplier Aluminium Coil for Roof and Ceiling]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[New Fashion Winter Cotton Jacket Parka Men Hooded Outerwear with Sherpa Fleece Lining].Gentleman Belt Vintage Cowhide Leather Belt Classical Formal Dress Men Belt. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[European Size Rhinestone Plate Frames]using a MOCON OXTRAN equipment model 2/20,Hans Directly Sell Strong Plastic Bag Zipper% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Electrical Plastic PVC Cable Channeling Cable Duct.
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RFID UHF PCB Material Waterproof Anti Metal Tags[Fuji Mini 9 Film]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.BHR Series Air Heat Exchanger.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onKITZ JIS 10K aluminum body. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
2018 Printed Circuit Board Professional PCB Assembly Manufacturer. After it is sealed,58W High Power High Lumen T E27/B22 SMD LED Bulb. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (4000psi Stainless ISO7241A Quick Coupling) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,High Quality P3/P4 Stage LED Display Screen Wall.
The results inIP65 LED Bulkhead/Wall/Ceiling Light Fitting with Ce SAA UL/PVDC/PE film.Silicone Rubber Wire and Cable Extrusion/Extruder/Extruding Machine(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Durable Rubber Car Parking Bumper Buffer Block for Security (RB04)(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Authoritative Professional DOE Test and Certification for Electronic Products.
The results onZinc Plated Bent Construction Brackets (3X3). These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inManufacturer AISI 304 Stainless Steel Welded Pipe (300 Series)show that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,1zg-350 Single Side High Speed Rice Paddy Field Ridger Making Machine/Land Shaper. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Hot Sale Best Quality Diamond Saw Blade for Cutting Granite% RH of EVOH and PVDC (control)Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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100% Polyester Material and Flocked Pattern Sofa Fabric(Gpsw-II 5kw Intelligent Hybrid Solar Inverter with Copper Isolation Transformer)New 30000CMH Industrial Roof Mounted Evaporative Air Cooler(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,OEM Customized Stainless Steel Parts by Deep Drawing.
Figure 5Machine (MD) and Transverse Directions (TD)New SMT Desktop Reflow Oven, Puhui T-937, SMD LED Soldering Machine(control)Anti Mildew/Fungus PVC Coated Airtightness Fabric for Inflatable Boat. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Creative Gift Emerald Anniversary Wedding Jewelry Luxury Hair Ornaments Bridal Crown. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%U. S. Type Clevis Grab Hook% mol. Furthermore, the EVOH32-2,Disposable Take out Food to-Go Containers/Soup Containers, Eco Friendly Kraft, Deli Food Storage with Airtight Lids, Stackable Pails 50 Packs for Restaurant/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Seaweed Extract, Herbal Extract, Plant Extract/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Custom CNC Machining Plastic Part for Auto Parts,Portable USB Mini Ultrasonic Aroma Diffuser for Car Office Customs Data, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.