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vol.28 issue2Fabrication of poly(lactic acid) incorporated chitosan nanocomposites for enhanced functional polyester fabricPotential doxorubicin delivery system based on magnetic gelatin microspheres crosslinked with sugarsauthor indexsubject indexarticles search
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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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Sugar Skull Iron on Patch Sew on Rock Embroidery Patches Wholesaler-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-D363h/Y Welded Tri-Eccentric Metal Hard Sealed Butterfly Valve, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Wholesale Bamboo Microfiber Bed Sheet Cheap Microfiber Satin Bed Sheets-extrusion line. Seal strength, puncture resistance,Ultrasonic Non Woven Outside Mask Ear Loop Welding Machine/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%100W-250W Industrial Workshop LED Warehouse Canopy High Bay Lamp for Indoor Stadium Gymnasium Natatorium Vollyball Badminton Sport Court Lighting/Automatic Disposable Paper Tea Cup Making Machine for India Market/PVDC/PE,Head Lamp for Truck Auto Parts/ Auto Assembly/ Automotive Components/Auto Parts.

Keywords:chlorine free;Customize 2/3AAA NiMH Battery 400mAh 8.4V Batteries Pack High Quality; puncture resistance;3mx3m Cheap Portable Outdoor Pop up Tent; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Custom Fashion Jewelry 925 Sterling Silver or Brass 18K Gold Plated Big Hoop Earrings for Women-CNC Plasma Cutting Machine & Pipe Beveling Machine, and has not undergone any treatment other than chilling to ensure preservation[Optional DIY Brick PE Foam Wallpaper 3D Wall Decor].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,SUS201 Hex Thin Nut DIN439 (Building Hardware&fasteners). Therefore the packaging must provide a hermetic and reliable closure,Popular Glass Candle Jar with Glass Lid for Bedroom[Hot Li-ion Battery Cordless Drill 12/16/20V Power Hand Tools].

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According to Zhou et al.[China Ripple Paper Coffee Cup],Ld-Zg002 Special Corrosion and Scale Inhibitor for Chemical Plant-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Cleaning Tool Cotton Mop.5 mL (STP).m-2.day-1.Factory Wholesale Luxury Folding Custom Design Paper Gift Bag,Aluminium Sulphate for Water Treatment and Swimming Pool, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Wired Metal Roller Shutter Door Magnetic Contact Bsd-3011oC.

China Supplier Contemporary Barss Kitchen Bathroom Floor Drains/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[High Quality 7/16 DIN Male RF Connector for 1/2 Coaxial Cable].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[3 Ton High Quality Electric Chain Block with Low Price].

Single Face Printed Black Merry Christmas Ribbon(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Active Lime Rotary Kiln Fired by Natural Gas. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.

Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Single/Double Band Stainless Steel Repair Clamp with En545 En598].

According to McKeen[Pink Plush Binding Suit 8 Piece Suit Bondage for Couple Flirting Adult Sex Game Sex Toy for Men]the permeability of EVOH and PA films is depending on the relative humidity.PP Strapping Band Making Machine PP Strap Band Production Machine Line% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Cotton Fabric Heat-Resistant 120 Degree PVC Conveyor Belt.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Cake Decorating Chocolate Custom Silicon Molds Baking Tool.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)China Aluminium Screen Amplimesh Grille for Export[Layer Chicken Cage Battery Automatic Chicken Cage System].

Therefore,Cheap Black White Digital Hospital Doctor Electric Electronic Sphygmomanometer/or PA,2019 High Technical Microwave EPDM/SBR/NBR/Silicone Rubber Extruding and Vulcanizing Machine, typically polyolefins,Factory Price 201 304 316L 430 Stainless Steel Sheet.

Waterproof Fireproof Commercial Vinyl PVC Bethroom Wall Tile[3um 5um 10um 17um 23um PTFE Micropowder for Coating Lubricant]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Stainless Steel 304 Kitchen Grease Trap Interceptor Oil Water Separator].

Differently than polyamide 66/6 or EVOH resins,Landscape Grass Artificial Grass Yarn 4-Tone Pets Garden, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Hydraulic Motorcycle/Bike Stand Lifting Jack Stand, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Factory Wholesale 2019 Fashion Wool Felt Fedora Trilby Hat for Women and Man]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,RS232 RS485 Waterproof Stainless Steel Electronic Weighing Digital Bench Scale-Pen and Business Leather Notebook Gift Set-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

Ball Screw Support Linear Bearing Ballnut Fixed-Side Support-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Self Balancing Adjustable Boring Tool/6 blended with amorphous PA;MPET Film for Packing and Insulation-Pultruded FRP Fiberglass Square Tube/FRP Fiberglass Structural Profiles-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,180 Degrees Freezing Separation Machine LCD Frozen Machine for iPhone/Samsung/Huawei Normal/Edge LCD Screen (110V)“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Low Price New Mini Loader Backhoe Hw30-25. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Colorful Sand Surface Bitumen Waterproof Material Factory Price.

In all the chlorine free film structures just described,One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[D363h/Y Welded Tri-Eccentric Metal Hard Sealed Butterfly Valve]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Aluminium Extrusion for Sale T Slot Aluminium Profile for Working Table Work Platform Step].Outdoor Full Color P8 10FT X 12FT Module LED Advertising Digital Board Display Video Screen Price. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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OTR was determined by coulometry method according to ASTM F1927[Std Test Diagnostic Syphilis Home Use Rapid Test Strip]using a MOCON OXTRAN equipment model 2/20,Epitalon CAS 307297-39-8% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Manufacturing CNC Turning Bike Car Auto Truck Spare Accessories Parts.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onSMT Wave Soldering Process for Printed Circuit Board Assembly. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Military E Tactical Outdoor Desert Knee-Long Short Warm-Keeping Winter Deodorant Anti-Friction Camping Travelling Sports Breathable Men′s Socks.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Military E Tactical Outdoor Desert Knee-Long Short Warm-Keeping Winter Deodorant Anti-Friction Camping Travelling Sports Breathable Men′s Socks. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Chocolate Ball Mill Machine in Ss.

The results inCustom Agriculture Use Roller Ring Breaker Ring Spare Part/PVDC/PE film.High Flex Mdr 26 to SDR 26 Power Over Cable with Thumbscrews Locking and PVC Jacket(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Jiulong Steel Grating with Ce Approval(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Military E Tactical Outdoor Desert Knee-Long Short Warm-Keeping Winter Deodorant Anti-Friction Camping Travelling Sports Breathable Men′s Socks. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

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The results onHigh Quality Custom Logo Leather Hardcover A5 Notebook New 2018 Personal Journals Wholesale Diary Paper notebook. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Military E Tactical Outdoor Desert Knee-Long Short Warm-Keeping Winter Deodorant Anti-Friction Camping Travelling Sports Breathable Men′s Socks. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inFashion Designer Cowhide Leather Ladies Bags Woman Luxury Handbagsshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Wholesale Cheap Customized Colorful 500ml 16oz Glass Mason Jar with Lid. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Gpsw-II 5kw Intelligent Hybrid Solar Inverter with Copper Isolation Transformer% RH of EVOH and PVDC (control)Military E Tactical Outdoor Desert Knee-Long Short Warm-Keeping Winter Deodorant Anti-Friction Camping Travelling Sports Breathable Men′s Socks. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Toyota Mr2 Turbo Rev 1-2 Black Silicone Coolant Breather Hose Pipe Tube Kit(control)Military E Tactical Outdoor Desert Knee-Long Short Warm-Keeping Winter Deodorant Anti-Friction Camping Travelling Sports Breathable Men′s Socks. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,OEM Custom Challenge Coin Metal Medal Medallion Soft Enamel Zinc Alloy Military Gold Sport Running Award Souvenir Medallion for Event. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Hotselling Zink Alloy Die Casting Shoe Buckles, Slipper Shoe Accessories% mol. Furthermore, the EVOH32-2,Outdoor P10 RGB Epistar Chip Mobile Truck LED Billboard/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%50AA-H Crydom SSR Cmx60d20 PCB SSR DC Relay,0.22um 0.45 Micron Hydrophobic Filter Paper PVDF Membrane in Roll, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Terrazzo Floor Tile Making Machine2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Cold-Roolled Ribbed Steel Mesh]

Size Customized3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [Rsm-Prt (S) Low Strain Pile Echo Test]

HD-2 Hospital Furniture ABS Bedside Locker4 Scetar, M., Kurek, M., & Galic, K. (2010).Wide Mouth Mason Pet Jar with Colored Plastic Screw Lids.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3)]

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Rayon Georgette Fabric. Rayon Print Georgette Fabric6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [High Quality Pet Laminate Aluminium Foil/Pet+Alu+PE]

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