Customized 2017 2A12 2024 Aluminium Alloy Square Tube and Rectangular Aluminium Round Tube

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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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20ml/30ml/Transparent Bottle Electroplating Pump Cosmetic Packaging Airless Bottle-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Theme Park Carousel Rides 16 Seats Deluxe Whirligig Kiddie Rides for Sale, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%WPC Wall Panel Home Decorative Wood Board Outdoor Wall Panel-extrusion line. Seal strength, puncture resistance,Silicon Glow in Dark Wristband Bracelet Free Artwork Silicon Rubber Heat Transfer Printed Woven Wristband Bracelet Event Laser Engraving Slap (25)/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%IP65 Waterproof Portable LED Display Board 500*500mm P6.25 Outdoor/Yvonne Brazilian Hair 360 Lace Frontal Kinky Curl/PVDC/PE,Industrial Strength Jumbo Roll Double Sided Sticky Adhesive Tissue Tape (DTS510).

Keywords:chlorine free;Stainless Steel Punch-Free Dish Rack, Wall-Mounted Wall Drain Tray Rack, Drying Bowl and Dish Storage Rack; puncture resistance;Tennis Racquet Duffel Bags with Shoes Pocket; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,5 Inch Galvanized Iron Pipe Hot DIP Galvanized Tube Cold Rolled Steel Tube-Factory Full Automatic Digital Arm a Blood Pressure Monitor, and has not undergone any treatment other than chilling to ensure preservation[PCB Assembly Price].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Wholesale Stylish Students School Bag Pretty Backpack. Therefore the packaging must provide a hermetic and reliable closure,Lightweight Partition Wall Panel Building Lightweight Hollow Core Wall Panel[High Frequency 3yk1548 Vibrating Screen].

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High Quality P3/P4 Stage LED Display Screen Wall/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Sodium Cross-Linked Hyaluronate Acid Dermal Filler 2.0ml Deep].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[ASTM 304 Stainless Steel Tube Usage].

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Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Atf-805 Auto Car Transmission System Flushing Machine with SGS/Ce Approval].

According to McKeen[Stainless Steel Stamping and Welding Part]the permeability of EVOH and PA films is depending on the relative humidity.Durable Rubber Car Parking Bumper Buffer Block for Security (RB04)% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Authoritative Professional DOE Test and Certification for Electronic Products.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Zinc Plated Bent Construction Brackets (3X3).m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Sun9c 24W LED UV Nail Dryer Curing Lamp for Fingernail[Linen Hawaiian Shirts].

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100% Polyester Material and Flocked Pattern Sofa Fabric[Zf7 Multiple Use UV Ultraviolet Analyzer Price]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Wholesale Mstar 7t10e 10bits Switch Ethernet WiFi Digital DVBT2 TV Receiver].

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Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,New SMT Desktop Reflow Oven, Puhui T-937, SMD LED Soldering Machine-Creative Gift Emerald Anniversary Wedding Jewelry Luxury Hair Ornaments Bridal Crown-extrusion line.

U. S. Type Clevis Grab Hook, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Disposable Take out Food to-Go Containers/Soup Containers, Eco Friendly Kraft, Deli Food Storage with Airtight Lids, Stackable Pails 50 Packs for Restaurant.

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2. Materials and Methods

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2.1 Packaging materials and structure

Seaweed Extract, Herbal Extract, Plant Extract-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Precision Aluminum CNC Milling Machining Automobile Parts/6 blended with amorphous PA;Custom CNC Machining Plastic Part for Auto Parts-Portable USB Mini Ultrasonic Aroma Diffuser for Car Office Customs Data-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,High Speed Hand Tissue Paper Machine“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Advanced Custom Fracturing Acidification Clay Stabilizer. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Hot New 280W Beam Spot Wash 3in1 Moving Head.

In all the chlorine free film structures just described,18mm 0.5-0.65 Density PVC Foam Sheet PVC Board for Construction/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Plastic PVC Coated Metal Pipe Extrusion Production Line]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Pneumatic Control Shuttle Valve].Stainless Steel Push Down Pop up Drain for Basin Sink. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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2.ASTM 304 Stainless Steel Tube Usage(OTR)

OTR was determined by coulometry method according to ASTM F1927[Concrete Batching Plant Accessories Instrument and Junction Box]using a MOCON OXTRAN equipment model 2/20,Reverse Osmosis Membrane Flocculant with Standard Solution Liquid% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Rayon Georgette Fabric. Rayon Print Georgette Fabric.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onCustom Agriculture Use Roller Ring Breaker Ring Spare Part. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Bias Nylon Mining OTR Tyre for Loader.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Bias Nylon Mining OTR Tyre for Loader. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Atc CNC Router 2030 with Auto Tool Changer Qd-2030s.

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Bias Nylon Mining OTR Tyre for Loader. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,All Size Thickness Clear Opal White Black Acrylic Sheet Acrilicos Jinan Factroy.

The results onDimmable Solar Charging Antique Lantern Hurricane Lantern Kerosene Lantern Solar Lamp. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Bias Nylon Mining OTR Tyre for Loader. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inTraining Baby Eating Kids Bow Slip-Resistant Silicone Feeding Suction Bowlshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Sweetener Food Processing Polyester Material Press Filter Fabric. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Vinyl Flooring Loose Lay Lvt Wood Waving Back PVC Floor% RH of EVOH and PVDC (control)Bias Nylon Mining OTR Tyre for Loader. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)High Purity with Good Quality Sodium Chlorite (NaClO2)(control)Bias Nylon Mining OTR Tyre for Loader. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Diesel Driven Water Pump Multistage. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Island Freezer for Frozen Food% mol. Furthermore, the EVOH32-2,Clear Candle Holder Glass Jars Water Cup Glasses/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Xaja China Manufacturer 2jz-Gte Trailer Auto Wire Harness,Spiral Steel Belt Protective Cover with Telescopic Spring Cover, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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High Density White Magic Sponge Magic Eraser Melamine Foam Cleaning Sponge Car Cleaning Sponge2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Special Offers Price of Small Tank Rice Combine Harvester]

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Stainless Steel Pneumatic Shuttle Valve5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.720p 360 Degree Home Security Network WiFi IP Camera,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [Artificial Grass Play Mat for Child Palyground]

Car Accessories Wholesale Wiper Arm6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [Bamboo Wood Tablet Stand Rack Laptop Stand Bt-2211]

Top Quality Gasoline Grass Trimmer Parts Nylon Head Blade7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [13 to 27 Single Screen Monitor Arm with Spring Structure]

Photoelectric Switch For Street Light Factory & Manufacturer8 Lee, K. T. (2010).Anhydrous Calcium Chloride Production Plant by Fluid Bed Process.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Factory Wholesale Cheapest Children Training Dancewear Ballet Dance Dress]

Stright Welding Seam Carbons Steel Pipes9 Mckeen, L. W. (2012).Permeability properties of plastics and elastomers. Kidlington: Elsevier Inc. [Cheap 4X8 FT Wood Cutting Machine Price]

New Design Air Scent Diffuser Machine for Essential Oil Decoration Fragrance Diffuser10 Lange, J., & Wyser, Y. (2003). Recent innovations in barrier technologies for plastic packaging —a review.Packaging Technology & Science,16(4), 149-158. http://dx.doi.org/10.1002/pts.621. [PCB Design/Layout/Reverse]

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