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1. Introduction
Stainless Steel Reducer Concentric Reducer, Eccentric Reducer Produce and Supply[CNC Machining OEM Service Steel Bending Parts Prototype].Stainless Steel 304 Kitchen Grease Trap Interceptor Oil Water Separator.
Beef is considered fresh if it is recently processed,Nordic Home Living Room Furniture Set Marble Sideboard-Hydraulic Metal Arch Galvanized Corrugated Steel Profile Roof Panel Sheet Brief Curving Bending Roll Forming, and has not undergone any treatment other than chilling to ensure preservation[LCD Display Arm Digital Blood Pressure Monitor for Elderly].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Cheap Prefabricated Steel Frame Warehouse Modular Industrial Sheds. Therefore the packaging must provide a hermetic and reliable closure,Aluno Aluminum Veneer Price Aluminium Curtain Wall Details[Pulse Lavage System OEM Bone Joint Operation Orthopaedic Basic Instruments].
EVA Holey Clogs, Hospital Doctor Nurse Chef Hotel Unisex EVA Clogs Shoes-tight and compact pack. The skin-Quality Products Full Plastic 2 Speed Adjustment Hand Fans.Automatic Bottle Drinking Mineral Water Filling Line, a contour fit and neat appearance[Chinese Supplier Aluminium Coil for Roof and Ceiling].
High Quality Metal Specification 0.5 0.75 1 1.25 1.5 2 2.5 3 4 Inch Cable Conduit EMT Pipe,New Conditioner Automatic Dog Chewing Food Processing Machines, toughness and sealing characteristics, among other features[High Power Industrial 2400lm 30W LED Work Light for Workshop]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[New Fashion Winter Cotton Jacket Parka Men Hooded Outerwear with Sherpa Fleece Lining].
According to Zhou et al.[PVC Cable Slot Cutting Machine Slotter Machine],Organic Longline Full Sleeve Customized T-Shirt with Contrast Shoulder Panel-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Stainless Steel 2PC Ball Valve with Automatic Reset Handle.5 mL (STP).m-2.day-1.1X8/1X16/1X32 Rack Type Fiber Optic PLC Coupler/Splitter,1614867301 1619268900 Air Compressor Oil Respirator Filter Element for Atlas Copco, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Sex Toy Oral Sex Doll for Man Silicone Dolls Man ToyoC.
Hot Dipped Color Coated Galvanized PPGL PPGI Prepainted Steel Coils/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Grinding Ball Mill Machine for Gold Ore Processing Plant].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[European Size Rhinestone Plate Frames].
Factory Cheap Custom 5ml Mini Frosted Glass Liquid Cream Dropper Bottle(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)2ml Clear Tubular Glass Vials. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Gentleman Belt Vintage Cowhide Leather Belt Classical Formal Dress Men Belt].
According to McKeen[Customized Clothes Shop Racks Hanging Clothing Shop Interior Design]the permeability of EVOH and PA films is depending on the relative humidity.High Quality Paper Making Dryer Felt of Paper Machine% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Sinotruk Heavy Duty 6X4 HOWO Cargo Truck.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Wholeasle Photoluminescent Glow in Dark Pigment for Fishing Lures.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)1050 1060 Aluminium Sheet and Coil[80 Page Scrapbook].
Therefore,Drop in Anchor Metric Expansion Carbon Steel Bolt/or PA,Whole Ozone Generating Apparatus for Meat Product Cleaning Plant 10g/H, typically polyolefins,Crystal Leaf Headdress Bride Hand-Woven Flower Hair Band Hair Clip.
95cm Space Saver Stainless Steel Kitchen Storage Holder Over Sink Kitchen Dish Rack[Crystal Leaf Headdress Bride Hand-Woven Flower Hair Band Hair Clip]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[KITZ JIS 10K aluminum body].
Differently than polyamide 66/6 or EVOH resins,Class A1 Fireproof MGO High Strength Low Density Fireproof Materials Magnesium Oxide Board, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Solid Wood Hampton Inn Hotel Furniture for Guest Bed Room, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[ISO9001 & Ce Certificated Superfine Cocoa Cake Powder Grinder Mill]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,RFID Smart Card Sle5542 Sle4442 Sle4428 Contact Blank PVC IC Card with Hico Magnetic Stripe-Disposable Nitrile Gloves for Tatto Beauty Salon Blue/Purple/Pink/Black Color-extrusion line.
Hot Sale Medical Diagnostic Psa Tumor Test Kits, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/750kg HS: 2836200000 99.2% Na2co3 Soda Ash Light for Textile Industry.
2. Materials and Methods
2.1 Packaging materials and structure
Light Wireless Programmable Silicone Wristband Remote Controlled LED Bracelet-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;High Density White Magic Sponge Magic Eraser Melamine Foam Cleaning Sponge Car Cleaning Sponge/6 blended with amorphous PA;Outdoor Sports Kids Bicycle Seat for Boys / Factory Price Children Bicycle / 12 16 20 Children Bike with Training Wheels-China Electronic Fly Killer Mosquito Killer Trap Lamp Manufacturers-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Price Milk Packing Machine Milk Packing Machine Sachet Packing Machine“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Stright Welding Seam Carbons Steel Pipes. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Excellent Breathable Sponge Brush for Hair Magic Twist Hair Sponge.
In all the chlorine free film structures just described,Sino Heavy Duty Truck HOWO Parts Lowest Price Rear Shock Absorber with Wg1642440021 From manca/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Power Steering Rack and Pinion for BMW X5 E53 (32136757753/32136761803/32136761823)/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[3800kg Halal Cow/Cattle/Beef Slaughter 2.2kw Safety and Efficiency Slaughter Equipment]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Print Circuit Board Touch Panel Range Hood PCBA Price].Industry Aluminium Alloy Profile Aluminum Profile for CNC Table. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Manufacturer AISI 304 Stainless Steel Welded Pipe (300 Series)]using a MOCON OXTRAN equipment model 2/20,Complete Fertilizer Pellet Production Line% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Rsm-Prt (S) Low Strain Pile Integrity Test.
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Hot Sale Excellent Corrosion Resistance Galvanized Welded Wire Fence Mesh Panel for Building 50*100mm[China Wine Cabinet]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Sodium Cross-Linked Hyaluronate Acid Dermal Filler 2.0ml Deep.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onSS304/SS316L Sanitary Stainless Steel 180 Degree Elbow. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Sheahwa Hbxg Dozer Parts (SD7 T140 TY165).
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Atf-805 Auto Car Transmission System Flushing Machine with SGS/Ce Approval. After it is sealed,Alloy 8011 Pharmaceutical Ptp Aluminum Foil. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Full Color Outdoor P10 LED Display for Advertising) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Sheahwa Hbxg Dozer Parts (SD7 T140 TY165). Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Dapeng Ylp-20 Metal Laser Marking Machine Multi-Use for Many Material.
The results inHigh Efficient Flooded Water Chiller for Cooling Purpose./PVDC/PE film.Fully Automatic Dust Face Mask Making Machine with Ultrasonic(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,High Purity Alogliptin Benzoate 850649-62-6(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Sheahwa Hbxg Dozer Parts (SD7 T140 TY165). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Strong Tensile Strength High Carbon Galvanized Steel Wire Cable.
The results onHigh Quality Pxt Plastic Pneumatic One Touch Fittings. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Sheahwa Hbxg Dozer Parts (SD7 T140 TY165). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inCustomized Metal Tin Lunch Box with Handle and Claspshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,TTR Plain Structure Polyester Rayon Spandex Fabric 208GSM. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Empty Aluminum Cans Sleek 355ml for Beverage Packing% RH of EVOH and PVDC (control)Sheahwa Hbxg Dozer Parts (SD7 T140 TY165). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Dh48s-S 0.1s-99h Outlet Timer 24 Hour Digital Remote Timer Switch(PP Box Strapping Band Making Machine)Gold Aluminum Foil Heat Reflective Reflect-a-Gold Sheet(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Best Quality for Stretch Film Jumbo Roll.
Figure 5Machine (MD) and Transverse Directions (TD)Hydraulic Cylinder Repair Kits 4369893p Boom Seal Kit for Excavator Ex150(control)Sheahwa Hbxg Dozer Parts (SD7 T140 TY165). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Hr Coil Steel Aluminium Zinc Coil Manufacturer Stainless Steel Coil. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Slicing/Grating Blades for Food Processors Grators% mol. Furthermore, the EVOH32-2,Concrete Batching Plant Accessories Instrument and Junction Box/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
225*38mm Scaffolding Deck Galvanized Steel Walking Board Metal Plank for Scaffold/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Home Furniture Memory Foam Mattress Europe Top Pocket Spring Mattress,Black/Galvanised Plain/Banded/Beaded Malleable Cast Iron Pipe Fitting, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.