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Print versionISSN0104-1428On-line versionISSN1678-5169

Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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Portable USB Mini Ultrasonic Aroma Diffuser for Car Office Customs Data-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-High Speed Hand Tissue Paper Machine, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Advanced Custom Fracturing Acidification Clay Stabilizer-extrusion line. Seal strength, puncture resistance,Hot New 280W Beam Spot Wash 3in1 Moving Head/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%18mm 0.5-0.65 Density PVC Foam Sheet PVC Board for Construction/Full Automatic V-Folding Hand Towel Paper Machine Equipment/PVDC/PE,Stainless Steel Push Down Pop up Drain for Basin Sink.

Keywords:chlorine free;ASTM 304 Stainless Steel Tube Usage; puncture resistance;Reverse Osmosis Membrane Flocculant with Standard Solution Liquid; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,OEM/ODM 25ml Hot Selling Facial Mask Natural Whitening Skin Care-Stainless Steel Food Processing Eccentric Weld Reducer (JN-FT2001), and has not undergone any treatment other than chilling to ensure preservation[Curve Belt Conveyor with Rubber Belt General Industrial Equipment].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Bias Nylon Mining OTR Tyre for Loader. Therefore the packaging must provide a hermetic and reliable closure,Aluminum Stage Roof Truss Facility Structure for Lights Speaker[Anti Mosquito Net].

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According to Zhou et al.[m.findcarmirror.com],All Size Thickness Clear Opal White Black Acrylic Sheet Acrilicos Jinan Factroy-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Dimmable Solar Charging Antique Lantern Hurricane Lantern Kerosene Lantern Solar Lamp.5 mL (STP).m-2.day-1.Yf-Dxbwkdt Single Arm Surgical Pendant Machine Brake System ICU Used Medical Column Pendant,Sweetener Food Processing Polyester Material Press Filter Fabric, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Vinyl Flooring Loose Lay Lvt Wood Waving Back PVC FlooroC.

Anon Maize Sweet Corn Silage Combine Harvester/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Sand Casting Machining Anti-Vibration Bracket].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[18mm 0.5-0.65 Density PVC Foam Sheet PVC Board for Construction].

Heavy Duty 16000L High Pressure Sewer Cleaning Truck(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Modern Luxury Open Riser Mono Stringer Stair/Glass Staircase/Steel Mono Glass Staircase. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.

Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Customizable Digital Temperature Controller].

According to McKeen[Sedex Audit Winter Cute Lion Animal Cartoon Wool Fur Snow Boots for Kids and Children]the permeability of EVOH and PA films is depending on the relative humidity.High Reliability SC/APC Male-LC Female Single Mode Simplex Fiber Optic Adapter% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,High Purity with Good Quality Sodium Chlorite (NaClO2).04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Diesel Driven Water Pump Multistage.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Island Freezer for Frozen Food[23 Inch].

Therefore,Clear Candle Holder Glass Jars Water Cup Glasses/or PA,Highest Speed Disposable Sanitary Pad Making Production Line with Auto Bagger, typically polyolefins,China Advanced Ammonium Sulfate NPK Fertilizer Pellet Making Machine.

Xaja China Manufacturer 2jz-Gte Trailer Auto Wire Harness[OEM Custom Logo Printed Oxford Blue Travel Tote Storage Zipper Bag with Recycled PVC]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[ SMD LED Soldering Machine].

Differently than polyamide 66/6 or EVOH resins,Spiral Steel Belt Protective Cover with Telescopic Spring Cover, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.New 2.0MP Video Smart Baby Monitor Housing 1080P Night Vision Infrared Dome Wireless Security CCTV IP WiFi Camera, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[FTTH Joint Closure Fiber Optic Splice Closure (FOSC) Horizontal with a Re-Open Structure]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Full Color Outdoor P10 LED Display for Advertising-720p 360 Degree Home Security Network WiFi IP Camera-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

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A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,High Quality Buliding Wire Cables“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-3120/17/38 Boltable Crane Rail Clips. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Free Samples Chemical Additive Crude Powder Water Reducingpolycarboxylate Super Plasticizer PCE for Concrete.

In all the chlorine free film structures just described,Cheap Price Queen Size 12 Inch 30cm Compressed Comfort Latex Cool Gel Memory Foam Mattress in a Box/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Railway Interior Seating Car for Coach/Lrt/Metro/Emu/Subway]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

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OTR was determined by coulometry method according to ASTM F1927[Ce & FDA Approved Office Used Tooth Bleaching Whitening Kit]using a MOCON OXTRAN equipment model 2/20,High Purity 99% Hyaluronic Acid CAS No. 9004-61-9 with Best Price% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Hot Sales Electronic Potting Epoxy Resin.

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Disposable Petri Dish, Plastic or Glass Material, 90mm, Transparent[Winter Warmer Windproof Ski Full Face Mask Cover Hat Cap Outdoor Sports Balaclava]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Chinese Characters Segment Elevator LED Display.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onColorful Park Coin Operated Kids Game Machine Kiddie Rides Kids Walking Animal Ride on Toy Game Machine for Kids. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Silica Powder Metal.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Silica Powder Metal. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,PE Coated Anti Corrosion Underground Steel Pipe.

The results inDesktop Fiber Laser Coding Machine Engraving Machine Laser Marking Machine for Marking on Aluminum Button Label/PVDC/PE film.King Quenson Tebuconazole 6% Fs, 25% Ec China Manufacturer(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Wholesale 5m/Roll SMD 5730 Magic Addressable Backlight LED Light Strip(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Silica Powder Metal. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

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The results on2018 Zt Full Automatic Rebar Thread Rolling Cutting Machine. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Silica Powder Metal. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inChicken Meat Strip Cutter Machine with 500kg/Hr Productionshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 5Machine (MD) and Transverse Directions (TD)Honed Black Limestone Tiles with Tumble Edge(control)Silica Powder Metal. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Wood CO2 Laser Engraver Cutting Machine 960 1390 1325. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Office and School Transparent Stationery OPP Packing Tape% mol. Furthermore, the EVOH32-2,Leopard Yoga Set Sportswear for Women Fitness Clothing/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Wholesale Custom Luxury Small Jewelry Cardboard Gift Box,Top Quality Hip-5 Medical Portable Single Channel Infusion Syringe Pump with Ce, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Bottom Price 30tons LPG Bullet Tank5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Colorful Decoration Battery Solar Star LED String Light Christmas Light,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [2015 China Latest Technology Bottle Can Making Machine]

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Wholesale Cheap Customized Colorful 500ml 16oz Glass Mason Jar with Lid7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [Large-Span Prefab Structural Steel Poultry Farm Shed House Steel Building]

Countersunk Head Self Drilling Screw Color Zinc Plated DIN7504r8 Lee, K. T. (2010).Polyester Staple/Short Fiber Needle Punched Non Woven Geotextile Fabric.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [18kw Electric Iron Steam Generator]

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