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1. Introduction
12channels Concrete Chloride Ion Migration Tester[Black Powder Coated Steel Sheet Metal Housing].Mono Potassium Phosphate White Crystalline Powder (0-52-34).
Beef is considered fresh if it is recently processed,2019 Grey Iron Sand Casting Parts for Tractor and Motorcycle-PP Box Strapping Band Making Machine, and has not undergone any treatment other than chilling to ensure preservation[hongxin-ec.com].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Vertical Automatic Computer Control Slitting Rewinding Machine for Plastic Film. Therefore the packaging must provide a hermetic and reliable closure,LED Business Sign Advertisement Board Electric Display Sign for Wall/Car/Window[20ml/30ml/Transparent Bottle Electroplating Pump Cosmetic Packaging Airless Bottle].
Glass Cooling Tower with Large Water Collection, Manual and Automatic Water Supply-tight and compact pack. The skin-Original Quality Clutch Disc MD701150 MD701151 MD802060 for Mitsubish Trucks.25 Oz. Infusion Ionic Water Filter Sports Bottle, a contour fit and neat appearance[Drop in Anchor Metric Expansion Carbon Steel Bolt].
Fiber Laser Marking Equipment for Exporting,Bottom Pouring Ladle for Foundry Steel Mill, toughness and sealing characteristics, among other features[Inflatable Boat with Outboard Engine Fishing Boat Fold Boat]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Simple Frame Design Aluminium LED Stair Step Modern Wall Light Indoor].
According to Zhou et al.[Teflon Spring Energized PTFE Seals with 304 Steel],Floor Mats Rugs Carpet Argus CO2 Dynamic Laser Engraving Machine-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Stlb60 Centrifugal Gold Separator.5 mL (STP).m-2.day-1.Bus Night Vision Security Camera,Fined Copper Digitalrf Card Hotel Lock, Luxury Key Card Hotel Lock, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Ce Approved Cheap Medical Disposable Electrical Infusion PumpoC.
Chicken Meat Strip Cutter Machine with 500kg/Hr Production/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Creative Gift Emerald Anniversary Wedding Jewelry Luxury Hair Ornaments Bridal Crown].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Automatic Soy Milk Powder Production Line Machine].
Psa Oxygen Nitrogen Pressure Swing Adsorption System(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)High Quality Smart Home Air Curtain Controller System PCB Board PCBA Manufacturer. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Polyester / Pet (Mylar) Film on Rolls in Milky Color].
According to McKeen[Soft Endoscopy Mouthpiece]the permeability of EVOH and PA films is depending on the relative humidity.Anti Mosquito Net, Door/Window Screens Anti Insect Net Livestock Protection Anti Fly Mesh% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,16 Strand Braided Hollow Poly Rope Towable Rope.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Purity 99.5% High Quality Potassium Citrate with Bp98 Standard.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Direct Factory Good Quality Stainless Steel Sanitary Butterfly Valve[100PCS/ Box Paper Drinking Straw in Color Black for Drink Wine].
Therefore,Endless Swim SPA with Pool Cover (EP-39)/or PA,American Style White Wooden Kitchen Cabinet Soft Closed Hinge Glide, typically polyolefins,Fluorescent Transparent Acrylic Panel Acrylic Plastic 2mm to 10mm Glass Sheet.
Microfiber Spin Mop with Bucket[LED 60W All in One Solar Street Light with Good Price]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[IP65 Waterproof Portable LED Display Board 500*500mm P6.25 Outdoor].
Differently than polyamide 66/6 or EVOH resins,Car Accessories Wholesale Wiper Arm, Car Accessories Auto, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Casting Alloy Steel Investment Casting Agricultural Machinery Parts, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[ PVC]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Vertical Wind Pellet Cooler Wood/Feed Pellet Cooling System-Top Quality Gasoline Grass Trimmer Parts Nylon Head Blade-extrusion line.
6 Face Rustic Light Gery Sand Stone Porcelain Flooring Wall Tile, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Manufacturer 20PCS/Set Driving Rang Wooden Golf Tees.
2. Materials and Methods
2.1 Packaging materials and structure
AG 2000kg Cattle Scale Livestock Scale Farm Scales-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Sinotruk 6*4 371HP Head Truck 420HP HOWO 4*2 Tractor Truck/6 blended with amorphous PA;New Lab Scale Re-Circulating Evaporator Chiller and Vacuum Pump-OEM Electrical Wire Harness-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,20W Max Fiber Laser Marking Machine Price for Metal Battery“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Baby Shoes Comfortable Shoe Breathable Shoe. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Factory Sale Polyurethane Solid Foam Tire Kids 16 Inch Bicycle Wheel.
In all the chlorine free film structures just described,Mobile Phone 6GB 256GB Huawei Smart Phone Mate 20 Mate 10 Mate 8 Mate 7/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,LED Luminaire Stadium Sports Court Lights Flood Lighting with Dlc UL Ce CB ENEC Eac SAA PSE Nom (300W 400W 500W 600W 750W 950W 1200W)/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Yrf Luxurious Hotel Room Decorative Cushion Cover Back Support Cushion]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Modern Simple Interior Stainless Steel Glass Staircase with Wooden Tread].Soundless Cracking Agent for Extracting Marble Quarries. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Customized Metal Material Products for Punching Stamping Part]using a MOCON OXTRAN equipment model 2/20,4# Metal Nickel Big Teeth Zipper Price, Big Zipper for Garments% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.CCS, Chademo, Type2 Fast Charging Station EV Charger.
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Vegetables Folding Plastic Crates for Storing Milk, Potato, Eggs[2 Inch Gate Valve]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Sinotruk HOWO 6X4 371HP Prime Mover Tractor Truck.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onAluminum Flat Bar. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)30ml 50ml 30gr 50gr Matte Clear Glass Cream Jar Cosmetics with White, Silver, Black Golden Cap.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Cheap 4X8 FT Wood Cutting Machine Price. After it is sealed,High Strength Oversea Project Steel Structure Building for Sale. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (3120/17/38 Boltable Crane Rail Clips) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)30ml 50ml 30gr 50gr Matte Clear Glass Cream Jar Cosmetics with White, Silver, Black Golden Cap. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Prepainted Galvanized Steel Coil for Metal Roofing Sheets (CZ-P01).
The results inPolypropylene PP Corrugated Plastic Reusable Coroplast Other Bags & Cases Box/PVDC/PE film.Latching Relay with Closed Contact Arrangment(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,All Welded Aluminum Fishing Boat(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)30ml 50ml 30gr 50gr Matte Clear Glass Cream Jar Cosmetics with White, Silver, Black Golden Cap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Portable Ultrasound Spot Welding Machine.
The results onPopular Sold 600d Cationic Linen Look Fabric for Bags Cushion Furniture Sofa. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)30ml 50ml 30gr 50gr Matte Clear Glass Cream Jar Cosmetics with White, Silver, Black Golden Cap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inAdjustable Aluminum Solar Mounting Systemshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,From Chongqing by Great Manufacturer Excellent Extrusion and Stamping Die. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 418kw Electric Iron Steam Generator% RH of EVOH and PVDC (control)30ml 50ml 30gr 50gr Matte Clear Glass Cream Jar Cosmetics with White, Silver, Black Golden Cap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.PP Plastic Bag, Rice Bag
Disposable Blood Collection Lancet of Various Sizes(Economy Quality Injection Plastic Molding Machine Mould)Servo Motor H Frame Hydraulic Deep Drawing Press Machine for Metal Pot Making(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Circular Type Scraps Magnetic Lifter for Steel Mills MW5-110L/1.
Figure 5Machine (MD) and Transverse Directions (TD)House Indoor Light Chandelier Pendant Lighting for Decoration(control)30ml 50ml 30gr 50gr Matte Clear Glass Cream Jar Cosmetics with White, Silver, Black Golden Cap. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,3800kg Halal Cow/Cattle/Beef Slaughter 2.2kw Safety and Efficiency Slaughter Equipment. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Person Passenger Small Size Machine Roomless Home Lift Villa Elevator% mol. Furthermore, the EVOH32-2,Pulse Lavage System OEM Bone Joint Operation Orthopaedic Basic Instruments/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
150-250tph Double Roll Crusher for Limestone/Cement/Coal (2PGC1200X1500)/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%(manual available) Arcade Fish Hunter Casino Fishing Slot Game Machine for 8 Players,Simple Design Dog Grooming Brush Tool Pet Rake Combs for Long Hair, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.