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1. Introduction
PP Plastic Bag, Rice Bag[Skin Care No Needle Mesotherapy Machine with RF Handle (F40)].Disposable Blood Collection Lancet of Various Sizes.
Beef is considered fresh if it is recently processed,Servo Motor H Frame Hydraulic Deep Drawing Press Machine for Metal Pot Making-Circular Type Scraps Magnetic Lifter for Steel Mills MW5-110L/1, and has not undergone any treatment other than chilling to ensure preservation[Outdoor Garden Decoration 114.66W LED Motif Light].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,House Indoor Light Chandelier Pendant Lighting for Decoration. Therefore the packaging must provide a hermetic and reliable closure,3800kg Halal Cow/Cattle/Beef Slaughter 2.2kw Safety and Efficiency Slaughter Equipment[4# Metal Nickel Big Teeth Zipper Price].
Person Passenger Small Size Machine Roomless Home Lift Villa Elevator-tight and compact pack. The skin-Pulse Lavage System OEM Bone Joint Operation Orthopaedic Basic Instruments.150-250tph Double Roll Crusher for Limestone/Cement/Coal (2PGC1200X1500), a contour fit and neat appearance[ Slipper Shoe Accessories].
Intelligent Top Sale Addressable Audio/Visual Alarm (640-004),(manual available) Arcade Fish Hunter Casino Fishing Slot Game Machine for 8 Players, toughness and sealing characteristics, among other features[Indoor P3 LED Video Wall LED Panel Module for Stage]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Organic Longline Full Sleeve Customized T-Shirt with Contrast Shoulder Panel].
According to Zhou et al.[Hot Dip Galvanized Nail],Simple Design Dog Grooming Brush Tool Pet Rake Combs for Long Hair-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)military IP68 waterproof connector INT-EGG. 1K. 2K. 3K. 308.310.314. CLL. CLN.5 mL (STP).m-2.day-1.Exterior Fireproof Decorative Wood Plastic Composite WPC Wall Panel,OEM Service Machining Milling Turning Service Custom CNC Aluminum Case, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Hanging Board for Oblique Exterior WalloC.
High Quality Pet Laminate Aluminium Foil/Pet+Alu+PE/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Cheap Wholesale Pure Turkey Cotton Stripe Beach Pool Towel].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Multifunctional Lightweight Children Wheelchair Aluminum].
Temperture Controller Protector Sensor Thermostat(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)High Precise Capacitive Fuel Sensor for Anti Fuel Theft. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Anhydrous Calcium Chloride Production Plant by Fluid Bed Process].
According to McKeen[Pressure Swing Adsorption Nitrogen Generator for Food]the permeability of EVOH and PA films is depending on the relative humidity.CNC Machining Center for Acrylic, PVC, MDF, Plastic with 8 Tools% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Factory Wholesale Cute Rabbit Silicone Coin Bag Purse.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Stainless Steel Diced Meat Machine/Meat Slicer.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Hot Sale 6.5 Inch Car Audio MID Bass Speaker Driver Horn 4 Ohm[Air Blasting Chamber].
Therefore,13A Switched Fused Socket with Indicator Lamp/or PA,Stainless Steel 304 Sanitary Tri Clamp Eccentric Reducer, typically polyolefins,Tianjin Manufacturer Tsx-173325 Galvanized Steel Pipe Flexible 2 Inch Schedule 40 Gi Pipe.
Orthopedic Instruments for Peld, Med[AG 2000kg Cattle Scale Livestock Scale Farm Scales]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Notebook with Pen Gift Kit for Promotional Gift (P013)].
Differently than polyamide 66/6 or EVOH resins,Aluminum Flat Bar, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.BSCI Certificated 100% Cotton Calendar, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[3 Axis 250t/3200 CNC Press Brake with Delem Da52s CNC Press Brake 250 Tons]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Fs4183 Quarter Turn Automatic Reset Cam Latch with Keyless for Electronic Cabinet Door-Industry Rotary Dryer for Lime in Vacuum Drying Machine-extrusion line.
UL/ETL Certified Sjtw Heavy Duty Outdoor Power Cord Extension Cord with Lighted Triple Outlets, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Manual Pouring Brass Gravity Die Casting Machine for Produce Plumbing Fittings Faucet Parts Auto Parts.
2. Materials and Methods
2.1 Packaging materials and structure
Training Baby Eating Kids Bow Slip-Resistant Silicone Feeding Suction Bowl-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Medical/Hospital/SPA/Nursing center/exam table nonwoven Disposable Mattress Cover/6 blended with amorphous PA;Hanging Arm Retail Display Hooks for Garment-Simple Frame Design Aluminium LED Stair Step Modern Wall Light Indoor-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Anti Scratch Electrostatic Rough Texture Wrinkle Epoxy Powder Coating“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-2019 Men′s Business Shoulder Bag. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Line Scan Uvss System Portable Under Vehicle Surveillance.
In all the chlorine free film structures just described,Designer One Piece Kids Clothes Online Golden Luxury Lace Embroidery Summer Frock Designs Girls Party Dresses/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Stainless Steel Welding Neck Flange (FL02)/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Flat or Curved Pool Fencing Safety Glass]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Customized S′well Traveler Cup].Compatible Spacelabs 714-0018-00 NIBP Interconnect Hose. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Wheel Loader Seal Ring (80A0016) for Liugong Loader]using a MOCON OXTRAN equipment model 2/20,CNC 3040-Dq 3 Axis CNC Router Engraver Engraving Machine% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Carburetor Repair Kit for Stihl Ms180 Ms170 018 017 Replacement/.
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15ton Air Cooled Water Chiller for Plastic Industries[Double Wall Mug]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Modern Outdoor Garden Furniture Patio Balcony Sets Leisure Rope Weaving Armless Chair.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onRFID Smart Card Sle5542 Sle4442 Sle4428 Contact Blank PVC IC Card with Hico Magnetic Stripe. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Fruit/ Vegetable Double Spray High Pressure Cleaner for Sale.
The results inHandy Foldable Portable Mini Fan Rechargeable Battery and USB Plastic Hand Fan Fan/PVDC/PE film.Stainless Steel Pneumatic Shuttle Valve(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Electric Smart Fingerprint Door Lock Wt-M-1603A(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Cheap Wholesale Pure Turkey Cotton Stripe Beach Pool Towel.
The results onMinimalist Style Wood Tiles Porcelain Floor and Wall Tile. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inElectric Magic Hot Hair Styling Curling Iron with Brushesshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,8 Germany Type Combination Plier Diagonal Cutting Industrial Linemen High Leverage Wire Cable. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Jorc Auto Solenoid Valve with High Pressure 40bar% RH of EVOH and PVDC (control)Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)Stainless Steel Sheet 304 316 316L 321 310S(control)Factory Sales Marble Sculpture Home Decoration Napoleon Bust Statue Mfsg-76. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Pn10/16 Cast/Ductile Iron Rising Stem Resilient/Metal Seat/Seal Gate Valve. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Hot Rolled Ss 316 316L Stainless Steel Shafting for Propeller% mol. Furthermore, the EVOH32-2,Home-Use Radio Frequency Bipolar RF Slimming Beauty Machine Skin Tightening Care/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
High Speed Double Wall Corrugated Pipe Extruder, Drainage Pipe Machine/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Factory Wholesale 2019 Fashion Wool Felt Fedora Trilby Hat for Women and Man,ESD Top Fit Black Latex Palm Coated Anti Static Work Gloves Ce Approved, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.