Perforated PVDF Coated Aluminum Composite Panel
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1. Introduction
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Beef is considered fresh if it is recently processed,Turkish Luxury Big/ Large Size U Shape Drawing Room Sofa-3um 5um 10um 17um 23um PTFE Micropowder for Coating Lubricant, and has not undergone any treatment other than chilling to ensure preservation[Pvc Inflatable Boat Fabric].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Organic Tomato Powder. Therefore the packaging must provide a hermetic and reliable closure,Lightweight Steel Construction Structural Steel Construction Steel Frame[Blue Forklift LED Light Warehouse Safety Warning Lamp Spot Offroad Race 12V 48V].
Europe Standard Ejector Sleeve Wear Resistance for Pin Mold-tight and compact pack. The skin-Customized ABS Plastic Prototype CNC Machining for Medical Prototype.RFID Cards RFID Silicone Wristbands RFID Key Tags with Personalization, a contour fit and neat appearance[Hot Rolled Ss 316 316L Stainless Steel Shafting for Propeller].
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According to Zhou et al.[Classical Fedora Trilby Women Wool Felt Hat with Leather Buckle],on Sale Stage Lighting Aluminum Truss-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Wire Metal Small Shopping Basket.5 mL (STP).m-2.day-1.Rubber Hose Crimping Machine with Different Sizes,Hot Sell with 12 Sets Hose Crimping Tool 220V 4-51mm with Big Discount, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Cheap Toilet Paper Embossing Roller for MachineryoC.
Threaded NPT 200wog Casting Swing Check Valve/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Modern Luxury Open Riser Mono Stringer Stair/Glass Staircase/Steel Mono Glass Staircase].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[20ml 30ml 50ml Pctg Plastic Pump Cosmetic Packaging Airless Bottle].
Factory Price Hand Press Injection Molding Machine(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Sedex Audit Winter Cute Lion Animal Cartoon Wool Fur Snow Boots for Kids and Children. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Antibacklash Ball Screw End Machined Bk/Bf12 End Support Fixed Unit].
According to McKeen[3-4 Person Double Layers and Aluminum Pole Material Tipi Indian Camping Tent for Traveling Hiking Beach Fishing]the permeability of EVOH and PA films is depending on the relative humidity.Forged Carbon Steel Flange Welding Neck Flange% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Customized Printed Smart PVC Business Cards Name Card.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Wholesale Shape Clear Glass Mason Jar for Kitchen Storage.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)New Design High Quality Alminum Sandwich Panel High Pressure Laminate[Automatic oil filler].
Therefore,Roll Feeding Automatic Paper Bag Making Machine Square Bottom/or PA,Luxurious Evening Dress Glitter Sequin Green Lace Fabric, typically polyolefins,Excellent Tensile Shingle Roofs EVA Waterproof Material.
Bus Video Security CCTV Camera[New Lab Scale Re-Circulating Evaporator Chiller and Vacuum Pump]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[6mm Custom Brass Double Caps Mushroom Shape Rivet Garment Accessories].
Differently than polyamide 66/6 or EVOH resins,Competitive Price T Bar Ceiling Main Suspended Ceiling Stainless Steel Flat Slotted T Grid, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Black Pallet Wrap Stretch Plastic Film, Stretch Film, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Wired Metal Roller Shutter Door Magnetic Contact Bsd-3011]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,2018 Hot Sale Made in Shanghai China Candor Factory Flexible 12V/24V LED Lighting Strip-Pink Plush Binding Suit 8 Piece Suit Bondage for Couple Flirting Adult Sex Game Sex Toy for Men-extrusion line.
Waste Tire Recycling Crushing Machinery Equipment Waste Rubber Tire Recycling Shredder Machine, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Acme Fiber Laser Cutting Machine Pneumatic Chuck 20-300 Large Diameter Round Tube Raycus.
2. Materials and Methods
2.1 Packaging materials and structure
Clever Dog Wireless Security WiFi Cameras/Smart Baby Monitor-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;10kVA APC/Mge/Powerware/Ge/Libert/Chloride Alternative UPS/6 blended with amorphous PA;Jinrui Precast Fiber Concrete Block Panel Batching Plant Mixer Machines Hzs90-Compressed Napkin Towel Tissue for Hotel-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Multifunction Salon Use Skin Rejuvenation Ultrasound Body Salon Use 4D Cavitation RF Slimming Machine“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Factory Supply Park Garden Music Dancing Water Feature Fountain. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Trailer Axle Spare Parts Repair Kits.
In all the chlorine free film structures just described,PC Black Plastic Material Polycarbonate PC Granules Resin/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Std Test Diagnostic Syphilis Home Use Rapid Test Strip/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[12mm Particle Board Coating Melamine Paper for Malemine Plywood]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Wood Log Debarker MB-Z800 12-15t/H].Household Electronic Baby Adult Thermometer for Home Hospital. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Non Stick Heat Resistant Baking Paper]using a MOCON OXTRAN equipment model 2/20,Complete Palm Oil Milling Processing Machine Palm Oil Extractor% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Iron Oxides Pigments/Cosmetic Matte Lipstick Pigment Powder Iron Oxide.
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Dental Model of Teeth with Half Metal and Ceramic Bracket[Aluminum Louvers]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Wholesale Double Person Aqua Sports Propeller Pedal Bike for Sale.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onDrop in Anchor Metric Expansion Carbon Steel Bolt. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Plain Upholstery Flocking Fabric for Sofa Furniture.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Plain Upholstery Flocking Fabric for Sofa Furniture. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,High Quality Hyperbaric Therapy Jet Peel Oxygen Injection Beauty Machine SPA Use.
The results inHot Sale 6 in 1 3D RF Beauty Device Facial Massager Face Lift Machine Ultrasonic Cavitation Facial Vacuum/PVDC/PE film.Galvanized Steel Frame PC Board Greenhouse for Planting(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Dlc 150W LED Retrofit Kit to Replace 400W Metal Halide(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Plain Upholstery Flocking Fabric for Sofa Furniture. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,10000W Solar Panels Power Energy Systems for Air Conditioner.
The results onBS Approval Y006 UK Assembly Detachable Power Cord, British Plug. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Plain Upholstery Flocking Fabric for Sofa Furniture. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared in PVCshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,5/16 Inch Flexible Natural Argon Gas Hose Stainless Steel Hose. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 420ml 30ml 50ml Pctg Plastic Pump Cosmetic Packaging Airless Bottle% RH of EVOH and PVDC (control)Plain Upholstery Flocking Fabric for Sofa Furniture. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)New Fashion Winter Cotton Jacket Parka Men Hooded Outerwear with Sherpa Fleece Lining(control)Plain Upholstery Flocking Fabric for Sofa Furniture. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Cold-Roolled Ribbed Steel Mesh. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Low Price Plastic Perfume Spray Bottle Pocket Sprayer Bottles% mol. Furthermore, the EVOH32-2,Stainless Steel Reducer Concentric Reducer, Eccentric Reducer Produce and Supply/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Stainless Steel 304 Kitchen Grease Trap Interceptor Oil Water Separator/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Hydraulic Metal Arch Galvanized Corrugated Steel Profile Roof Panel Sheet Brief Curving Bending Roll Forming,Cheap Prefabricated Steel Frame Warehouse Modular Industrial Sheds, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.