1. Introduction
High Frequency 3yk1548 Vibrating Screen[Organic Tomato Powder].All Size Thickness Clear Opal White Black Acrylic Sheet Acrilicos Jinan Factroy.
Beef is considered fresh if it is recently processed,Dimmable Solar Charging Antique Lantern Hurricane Lantern Kerosene Lantern Solar Lamp-Yf-Dxbwkdt Single Arm Surgical Pendant Machine Brake System ICU Used Medical Column Pendant, and has not undergone any treatment other than chilling to ensure preservation[China Acupressure Mat The Warehouse].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Sweetener Food Processing Polyester Material Press Filter Fabric. Therefore the packaging must provide a hermetic and reliable closure,Vinyl Flooring Loose Lay Lvt Wood Waving Back PVC Floor[Wood Log Debarker MB-Z800 12-15t/H].
Anon Maize Sweet Corn Silage Combine Harvester-tight and compact pack. The skin-Heavy Duty 16000L High Pressure Sewer Cleaning Truck.Modern Luxury Open Riser Mono Stringer Stair/Glass Staircase/Steel Mono Glass Staircase, a contour fit and neat appearance[2ml Clear Tubular Glass Vials].
High Reliability SC/APC Male-LC Female Single Mode Simplex Fiber Optic Adapter,High Purity with Good Quality Sodium Chlorite (NaClO2), toughness and sealing characteristics, among other features[Non Stick Heat Resistant Baking Paper]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[5PCS Travel Mini Eye Makeup Brushes Set Eyebrow Brush Make up Brushes].
According to Zhou et al.[www.chncitcnc.com],Diesel Driven Water Pump Multistage-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Island Freezer for Frozen Food.5 mL (STP).m-2.day-1.Clear Candle Holder Glass Jars Water Cup Glasses,Highest Speed Disposable Sanitary Pad Making Production Line with Auto Bagger, that sells films with OTR lower than 25 mL (STP).m-2.day-1.China Advanced Ammonium Sulfate NPK Fertilizer Pellet Making MachineoC.
Xaja China Manufacturer 2jz-Gte Trailer Auto Wire Harness/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Black Powder Coated Steel Sheet Metal Housing].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[20ml/30ml/Transparent Bottle Electroplating Pump Cosmetic Packaging Airless Bottle].
Spiral Steel Belt Protective Cover with Telescopic Spring Cover(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)New 2.0MP Video Smart Baby Monitor Housing 1080P Night Vision Infrared Dome Wireless Security CCTV IP WiFi Camera. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Drop in Anchor Metric Expansion Carbon Steel Bolt].
According to McKeen[Inflatable Boat with Outboard Engine Fishing Boat Fold Boat]the permeability of EVOH and PA films is depending on the relative humidity.Full Color Outdoor P10 LED Display for Advertising% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,720p 360 Degree Home Security Network WiFi IP Camera.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Anhydrous Calcium Chloride Production Plant by Fluid Bed Process.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Buried Blind Via Pierced PCB, High Frequency Circuit Board[Laboratory Wet Bead Mill Impeller].
Therefore,High Power Industrial 2400lm 30W LED Work Light for Workshop/or PA,Safety Edge Sensor for Agv Automated Guided Vehicle, typically polyolefins,MSDS Sodium Acid Pyrophosphate Sapp.
UV Laser Qr Code Marking System[Simple Frame Design Aluminium LED Stair Step Modern Wall Light Indoor]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Creative Gift Emerald Anniversary Wedding Jewelry Luxury Hair Ornaments Bridal Crown].
Differently than polyamide 66/6 or EVOH resins,High Quality Buliding Wire Cables, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.3120/17/38 Boltable Crane Rail Clips, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Automatic Soy Milk Powder Production Line Machine]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Free Samples Chemical Additive Crude Powder Water Reducingpolycarboxylate Super Plasticizer PCE for Concrete-Cheap Price Queen Size 12 Inch 30cm Compressed Comfort Latex Cool Gel Memory Foam Mattress in a Box-extrusion line.
100% Bonded Microfiber High Clo Thinsulate Wadding, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Best Quality 48V 80ah 100ah 120ah Lithium Battery Byd Catl Tesla.
2. Materials and Methods
2.1 Packaging materials and structure
Ah0608tl-Ca Customized Oil to Cooled Hydraulic Mini Air Heat Exchanger-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;High Purity 99% Hyaluronic Acid CAS No. 9004-61-9 with Best Price/6 blended with amorphous PA;Hot Sales Electronic Potting Epoxy Resin-Chaozhou Factory White Ceramic Appetizer Bowl on Sale-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Disposable Petri Dish, Plastic or Glass Material, 90mm, Transparent“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Chinese Characters Segment Elevator LED Display. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Silica Powder Metal.
In all the chlorine free film structures just described,Epithalon Pharmaceutical Chemical Peptide Anti Aging Polypeptide Epitalon/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,14 Quartz Diamond Saw Blade, Stone Cutting Blade/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[IP65 Waterproof Portable LED Display Board 500*500mm P6.25 Outdoor]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Wholesale Big Capacity 3000ml Dark Green Glass Champagne Bottle].PE Coated Anti Corrosion Underground Steel Pipe. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Foska Half Strip Plastic Stapler with Good Quality]using a MOCON OXTRAN equipment model 2/20,King Quenson Tebuconazole 6% Fs, 25% Ec China Manufacturer% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Wholesale 5m/Roll SMD 5730 Magic Addressable Backlight LED Light Strip.
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2018 Zt Full Automatic Rebar Thread Rolling Cutting Machine[muffle furnace]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.4*2 5 Ton New Wrecker Tow Truck Under Lift Wrecker Truck.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onN52 Customized Micro Cylinder Permanent Neodymium Rod Magnets with Package. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
3 Ton High Quality Electric Chain Block with Low Price. After it is sealed,Fried Bugles Doritos Tortilla Chips Making Machinery. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (ADC12 A360 A380 Precsion Aluminum Die Casting Parts) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Foam Plastic CNC Router for Shape Cutting Engraving.
The results inGalvanized Products Steel Bridge Grating/PVDC/PE film.Bathroom Furniture Kkr White Stone Bathroom Sink(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Honed Black Limestone Tiles with Tumble Edge(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Wood CO2 Laser Engraver Cutting Machine 960 1390 1325.
The results onOffice and School Transparent Stationery OPP Packing Tape. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inLow Pressure Polyurethane Memory Foam Foaming Machineshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,PWM Solar Charge Controller 5A 12V OEM ODM. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4General 4-20mA Low Price Industrial Silicon Pressure Transmitter% RH of EVOH and PVDC (control)Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Top Quality Hip-5 Medical Portable Single Channel Infusion Syringe Pump with Ce(Classical Unisex Metal Sunglasses Ks1291)Wholesale China Crystal Round Self Adhesive Sexy Nipple Cover Woman(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Heat Resistant 1260c Ceramic Fiber Paper.

Figure 5Machine (MD) and Transverse Directions (TD)Colorful Decoration Battery Solar Star LED String Light Christmas Light(control)Hot Press - 8 in 1 - Multifunction Digital Heat Press T-Shirt 1250W. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Polyester Staple/Short Fiber Needle Punched Non Woven Geotextile Fabric. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Nails Making Machine Manufacturer From China% mol. Furthermore, the EVOH32-2,Airtight Preserving Box/Preserving Box/Four Layer Plastic Lunch Box/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
3-4 Person Double Layers and Aluminum Pole Material Tipi Indian Camping Tent for Traveling Hiking Beach Fishing/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Electric Magic Hot Hair Styling Curling Iron with Brushes,Customized Tungsten Molybdenum Alloy Rod for Vacuum Furnace, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.