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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

Whole Ozone Generating Apparatus for Meat Product Cleaning Plant 10g/H

Original Article

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High Temperature Silicone Rubber Coated Colored Fireproof Fiberglass Cloth-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Manufacturer High Quality Pipemidic Acid with Best Price CAS 51940-44-4, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Strong Sintered Neodymium-Iron-Boron Magnet Cylinder-extrusion line. Seal strength, puncture resistance,Hot Sale Al Pet Single Side Polyester Laminated Aluminium Foil for Cable Shield/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%China Best Selling of Electro Lifting Magnet for Steel Ball/New Technology Carbon Cleaning Tools Auto Accessories/PVDC/PE,Large-Span Prefab Structural Steel Poultry Farm Shed House Steel Building.

Keywords:chlorine free;High Quality High Expension Foam Generator Foam Maker; puncture resistance;China Motor Company Produce BLDC Fan Motor for Barn Vent Fan; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Wholesale Bamboo Microfiber Bed Sheet Cheap Microfiber Satin Bed Sheets-Ultrasonic Non Woven Outside Mask Ear Loop Welding Machine, and has not undergone any treatment other than chilling to ensure preservation[Wholesale Personalized Soild Color Sheer Silk Organza Ribbon with Satin Edged for Wedding Car Decoration/Gift Packing].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,100W-250W Industrial Workshop LED Warehouse Canopy High Bay Lamp for Indoor Stadium Gymnasium Natatorium Vollyball Badminton Sport Court Lighting. Therefore the packaging must provide a hermetic and reliable closure,Automatic Disposable Paper Tea Cup Making Machine for India Market[10kVA APC/Mge/Powerware/Ge/Libert/Chloride Alternative UPS].

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According to Zhou et al.[Oxy-Hydrogen Gas Generator Car Engine Carbon Clean],Custom Fashion Jewelry 925 Sterling Silver or Brass 18K Gold Plated Big Hoop Earrings for Women-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)CNC Plasma Cutting Machine & Pipe Beveling Machine.5 mL (STP).m-2.day-1.SUS201 Hex Thin Nut DIN439 (Building Hardware&fasteners),Popular Glass Candle Jar with Glass Lid for Bedroom, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Quality Melamine Flooring Laminated Decorative PaperoC.

Pump Body Part by Casting/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[HD-2 Hospital Furniture ABS Bedside Locker].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[500 Watts High Speed 20 Folder Big Foot Ebikes (JL-TDN05Z-FAT-3)].

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Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Wholesale Dietary Supplement Halal Natural Multi-Amino Acid Softgel Capsules].

According to McKeen[Rayon Georgette Fabric. Rayon Print Georgette Fabric]the permeability of EVOH and PA films is depending on the relative humidity.5# Big Teeth Plastic Resin Zipper for Luggage Bags% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Ld-Zg002 Special Corrosion and Scale Inhibitor for Chemical Plant.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Cleaning Tool Cotton Mop.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Factory Wholesale Luxury Folding Custom Design Paper Gift Bag[1060 CO2 Sealed Glass Tube100watt Acrylic Sheet Cutting Laser Machine].

Therefore,Aluminium Sulphate for Water Treatment and Swimming Pool/or PA,Wired Metal Roller Shutter Door Magnetic Contact Bsd-3011, typically polyolefins,China Supplier Contemporary Barss Kitchen Bathroom Floor Drains.

Single Face Printed Black Merry Christmas Ribbon[High Quality Pet Laminate Aluminium Foil/Pet+Alu+PE]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Hot Dipped Color Coated Galvanized PPGL PPGI Prepainted Steel Coils].

Differently than polyamide 66/6 or EVOH resins,Active Lime Rotary Kiln Fired by Natural Gas, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.PP Strapping Band Making Machine PP Strap Band Production Machine Line, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Miniature PCB Relay Power Relay for Household Appliances &Industrial Use]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Cotton Fabric Heat-Resistant 120 Degree PVC Conveyor Belt-Cake Decorating Chocolate Custom Silicon Molds Baking Tool-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

2019 High Technical Microwave EPDM/SBR/NBR/Silicone Rubber Extruding and Vulcanizing Machine-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Factory Price 201 304 316L 430 Stainless Steel Sheet/6 blended with amorphous PA;Waterproof Fireproof Commercial Vinyl PVC Bethroom Wall Tile-Landscape Grass Artificial Grass Yarn 4-Tone Pets Garden-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Hydraulic Motorcycle/Bike Stand Lifting Jack Stand“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-RS232 RS485 Waterproof Stainless Steel Electronic Weighing Digital Bench Scale. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Pen and Business Leather Notebook Gift Set.

In all the chlorine free film structures just described,Hot Selling Laundry Detergent Powder, Washing Powder for Hand Wash&Machine/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Ifi-111 Flange Bolt (Zinc) Made From China]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[ Injection Mold].Ball Screw Support Linear Bearing Ballnut Fixed-Side Support. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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2.Self Balancing Adjustable Boring Tool(OTR)

OTR was determined by coulometry method according to ASTM F1927[14 Quartz Diamond Saw Blade]using a MOCON OXTRAN equipment model 2/20,MPET Film for Packing and Insulation% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Pultruded FRP Fiberglass Square Tube/FRP Fiberglass Structural Profiles.

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Low Price New Mini Loader Backhoe Hw30-25[16 Inch Folding Bicycle]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Colorful Sand Surface Bitumen Waterproof Material Factory Price.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.

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3. Results and Discussions

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3.1 Film thickness

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Latest Fashion Brooch for Sale Rhinestone Brooch for Women Costume Red and Blue Bowknot Brooch (EB06).

The results inEpitalon CAS 307297-39-8/PVDC/PE film.Manufacturing CNC Turning Bike Car Auto Truck Spare Accessories Parts(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Unique Chubby Fish Foundation Brush Blush Glitter Custom Label Mermaid Makeup Brush Set(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,Rechargeable Lithium Battery 7.4V 1150mAh Battery Pack with UL.

The results onWhite High-End Acrylic Plastic Cosmetic Packaging Emulsion Bottles and Cream Jar. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inWall Insulation Design Flexible steel Frameshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Electro Galvanized Knotted Dog Chain Cow Chain with Snap Hook. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Home Decorator 4 Side Free Standing Electric Fireplace with Heater% RH of EVOH and PVDC (control)One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.Chocolate Ball Mill Machine in Ss

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Figure 5Machine (MD) and Transverse Directions (TD)CNC Metal Sheet Fiber Laser Cutting Machine for Sale(control)One Wire Walkie Talkie Surveillance Earpiece with Acoustic Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,High Quality Custom Logo Leather Hardcover A5 Notebook New 2018 Personal Journals Wholesale Diary Paper notebook. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%High Quality Aluminum Alloy Water Bike for Aquatic Park% mol. Furthermore, the EVOH32-2,Wholesale Cheap Customized Colorful 500ml 16oz Glass Mason Jar with Lid/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%2018 Newest Sport Logo Custom Iron on Woven Embroidery Patches,2015 New Design 3D Printing Pen Model, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

Movely Lovable Panda Household Soft Plush Antiskid Indoor Home Slippers1 Sarantopoulos, C. I. G. L., Rego, R. A., Dantas, T. B. H., Dantas, F. H., Jaime, S. B. M., Mourad, A. L., & Padula, M. (2012). As tendências de embalagem. In C. I. G. L. Sarantopoulos & R. A. Rego (Eds.),Different Type Illuminated 12mm Mounting Electric Push Button Switch(pp. 67-83). Campinas: ITAL. [Cheap Promotion Memory Pillow for Home Bedding]

25mm Stainless Steel Waterproof Metal LED 12V 24V 220V Indicator Lamp Metal LED Indicator Lamp2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Plow Part Ploughshare Stamping Part for Agricultural Machinery]

Concrete3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [Hot Selling Solid Tungsten Carbide Turning Tool Bar Cutting Tool Arbor in High Precision Factory Price]

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DIP Wave Soldering Machine with Siemens PLC Control System5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.OEM Custom Challenge Coin Metal Medal Medallion Soft Enamel Zinc Alloy Military Gold Sport Running Award Souvenir Medallion for Event,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [15nm Torque Dc Gear Motor]

55 Inch Floor Stand Full 1080P LCD Advertising Display/Outdoor LCD Screen/Outdoor Digital Signage/Totem6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [PC Black Plastic Material Polycarbonate PC Granules Resin]

Stainless Steel Push Down Pop up Drain for Basin Sink7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [High-End Colored Standard and Nonstandard Rubber O Shape Seal Ring]

Wireless Windows Sensors Factory & Manufacturer8 Lee, K. T. (2010).Hotselling Zink Alloy Die Casting Shoe Buckles, Slipper Shoe Accessories.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Excellent Breathable Sponge Brush for Hair Magic Twist Hair Sponge]

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