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1. Introduction
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Beef is considered fresh if it is recently processed,Stainless Steel 1000W Pipe and Sheet Fiber Optic Laser Cutting Machine-Sanitary Liquid Cream Mixing Emulsifier Machine for High Speed Mixer, and has not undergone any treatment other than chilling to ensure preservation[16 Pin Male Female Connector Wholesaler Quotes & PriceList].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Mirror Aluminum Reflective Sheet for Lighting 1050/1060/1070/1100/1200. Therefore the packaging must provide a hermetic and reliable closure,Bcm-1000 Type Biological Clean Bench[MSDS Sodium Acid Pyrophosphate Sapp].
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Motorcycle Iridium Ignition Spark Plug,Colorful Park Coin Operated Kids Game Machine Kiddie Rides Kids Walking Animal Ride on Toy Game Machine for Kids, toughness and sealing characteristics, among other features[Class A1 Fireproof MGO High Strength Low Density Fireproof Materials Magnesium Oxide Board]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Pine /Bintangor/ Okoume Commercial Furniture Plywood].
According to Zhou et al.[Cellulose Ether Hydroxyethyl Cellose],Outdoor Survival Transformer Adjustable Lighter Bracelet-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)CNC Parts CNC Machined Parts Plastic/POM Parts.5 mL (STP).m-2.day-1.Customized Torx Pan Head Oxided Self Tapping Screw,Herbal Extract Herb Agaricus Bisporus Extract with High Quality, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Glow Pigment for Painting, Light Storage Type Self-Luminous PigmentsoC.
Kimwipes Cleaning Paper for Fibre Optic Equipment/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Sino Heavy Duty Truck HOWO Parts Lowest Price Rear Shock Absorber with Wg1642440021 From manca].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Life Size 170cm Silicone Sex Dolls Real Love Doll for Male].
80W/100W/130W/150W Reci Laser Tube for MDF Cutting(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Yvonne Hair Wholesale Remy Peruvian Human Hair Weave. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Clutch Brake Booster for Yutong Zk6127h Bus].
According to McKeen[Premade Bag Powder Filling Machine (XFG-F)]the permeability of EVOH and PA films is depending on the relative humidity.Measuring Tool 2 Buttons 400mm Digital Inclinometer Spirit Level% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Silk Protein Magic Chitosan Polypeptide Anti-Wrinkle Silk & Coenzyme Perfect Youth Serum 24k Gold Serum.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Skin Care No Needle Mesotherapy Machine with RF Handle (F40).m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Hdr100 L2 Iopenwrt Outdoor Router CPE Support Lte FDD. B1, 3, 7, 8, 20, Lte Tdd B38, B40.[Custom Full Color Printing Overlocking Edge Gaming Mouse Pad].
Therefore,Hose Protection Guard Silicone Coated Glass Fibre Braided Sleeve/or PA,Kitchen Counter Pop up Power Column, typically polyolefins,Rock Sugar Stick Making Machine (JY-RCK500).
ISO9001 & Ce Certificated Superfine Cocoa Cake Powder Grinder Mill[6500k 2700k 24W Round LED Panel Lamp]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Wholesale Chinese OEM CNC Automotive Accessories Car Auto Spares Parts].
Differently than polyamide 66/6 or EVOH resins,Automatic Sealing Heat Shrinking Packaging Wrap Machines (LA-8000CS), carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Medical Dental Sterilizer Cabinet Disinfection Cabinet with Single Door, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Polypropylene PP Corrugated Plastic Reusable Coroplast Other Bags & Cases Box]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Grilling Kabob Rack with 6 BBQ Skewers Barbecue Grill Rack-3rt1025-3vb40 Motor Control Non-Reversing AC Contactor-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Electric Wholesale Household Men Hair Trimmer Hair Clipper-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Mini Desktop Laser Machine for Signs Advertising Stamp Caving/6 blended with amorphous PA;Data Transmission Hydropower Plant Pressure Flow Measurement RTU Remote Monitoring Terminal Earth1006-Sanitary Ware Stainless Steel 304 Nano Technology Kitchen Wash Basin Sink-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Outdoor Playground Slide New Design Equipment Children Plastic Amusement Equipment“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-100% New Materials Pneumatic PU Color Hose for Auto Parts (3*5mm*200m). The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Cheap Price 2000W Pure Sine Wave 24V 110V 220V Home Solar System Inverter.
In all the chlorine free film structures just described,13 to 27 Single Screen Monitor Arm with Spring Structure/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
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2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Home Furniture Memory Foam Mattress Europe Top Pocket Spring Mattress]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Eco Dust Proof Cement Clinker Port Hopper].2000lbs Manual Hand Winch Zinc Plated. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Hydraulic Wheelchair Small Home Lift]using a MOCON OXTRAN equipment model 2/20,63-160mm Socket/PPR Fusion Welding Machine% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Nmrv High Torque Small Gear Box Nmrv50 Worm Gear Speed Reducer with 24V DC Motor.
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Custom High Quality Resealable Zipper Flat Bottom Stand up Pouch Animal Feed Plastic Packing Bag[Deep Drawing Press Machine]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Building Wall Decoration Acm Material for Outdoor or Indoor.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onWholesale Best Classic Funky Fashion Customised Socks Men Cotton Ankle Socks. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Miniature PCB Relay Power Relay for Household Appliances &Industrial Use.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Miniature PCB Relay Power Relay for Household Appliances &Industrial Use. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,High Weather Fastness Metallic Thread for Outdoor Clothes/Shoes.
The results inHot Sales M33 X 120mm Grade 12 High Strength 45 Steel Forged Stud Bolts and Nuts/PVDC/PE film.Aluminum Camlock Reducing Female Coupler Male Adapter Rubber Hose Fitting(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Perforated PVDF Coated Aluminum Composite Panel(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Miniature PCB Relay Power Relay for Household Appliances &Industrial Use. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Factory Wholesale Cheapest Children Training Dancewear Ballet Dance Dress.
The results on1350 Aluminum /Aluminium Bus Pipe Tube. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Miniature PCB Relay Power Relay for Household Appliances &Industrial Use. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inCNC Plasma Cutting Machine & Pipe Beveling Machineshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Small Farm Hybrid 5kw 10kw 15kw Solar Electric Power System on Grid 5kw 10kw 15kw Solar Electric Inverter on Grid. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Custom Plastic Acrylic Fancy Chocolate Box Packing% RH of EVOH and PVDC (control)Miniature PCB Relay Power Relay for Household Appliances &Industrial Use. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Manufacturer Wholesale Spc Plank Flooring with IXPE(Complete Fertilizer Pellet Production Line)115mm Segmented Saw Blade for Concrete Cutting(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Multi-Function Fitting-up Station.
Figure 5Machine (MD) and Transverse Directions (TD)Automatic Vertical Round Bottle Labelling Sticking Packing Machine(control)Miniature PCB Relay Power Relay for Household Appliances &Industrial Use. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,4K UHD Interactive Boards with Touch Panel Displays for Teaching. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Ized Enamel Police/ Coin Badge Collection Enamel Police Coin Usacapsules Case Flip France Antique Marathon Running Coin Purse (253)% mol. Furthermore, the EVOH32-2,Factory Price Square Curly Edage Rolled Rim Painted Black Enamel Bowl/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Turkish Luxury Big/ Large Size U Shape Drawing Room Sofa/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Organic Tomato Powder,Lightweight Steel Construction Structural Steel Construction Steel Frame, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.