1. Introduction
Key Lock Switch with 90° Switching, (Key Lock independent)[Wholesale 180ml Salt Pepper Glass Spice Jar with Grinder].Warm White G45 4W E27 E14 LED Filament Bulb for Decoration.
Beef is considered fresh if it is recently processed,Best 3D Printer 2019 Creality Newest Cr-10 V2 Autolevel Bltouch Large Industrial 3D Printer Upgrade From Great Cr-10 3D Drucker-PE Coated Anti Corrosion Underground Steel Pipe, and has not undergone any treatment other than chilling to ensure preservation[Electroplated Diamond 200mm Circular Saw Blade for Concrete Cutting].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Expanded Metal Strainers Metal Mesh Screen. Therefore the packaging must provide a hermetic and reliable closure,Five Bar Wood Insert Woodcraft Solid Pine Wood Screen Door[Zhuv New Wooden Colors for UV Gloss MDF Board].
Hot Selling Vapor Oil and Gas Recovery Vacuum Pump-tight and compact pack. The skin-Walking Long Distance Surveying Instrument Meter Measuring Wheel.DC 4.5V-12V Mini USB Brushless Aquarium Water Pump Electric Submersible Fish Tank Fountain Water Circulation Pump, a contour fit and neat appearance[Automatic Stainless Steel Tomato Paste Making Machine].
Customized CNC High Precision Turning Stainless Steel Mechanical Parts,Hot Selling Cosmetic Makeup Matte Lipgloss Matte Liquid Lipstick LED Lighted Lip Gloss with Mirror, toughness and sealing characteristics, among other features[ hot stamping]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Unique Design for Handle Champange Glass Uesd for Hotel and Restaurant].
According to Zhou et al.[www.a-topmachine.com],Mini Dual-Use Thermal Imaging Camera Portable Rifle Scope Infrared Monocular Night Vision Camera for Hunting-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Industrial 3003 1060 5052 H32 Alloy Thin Aluminum Foil Coil Rolls for Sale.5 mL (STP).m-2.day-1.Foam Vertical Cutting Machine (LQ-3L) _,Audio Cable for Car Stereo Aux Cable as Avss Car Cable, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Ce Approval CO2 Aluminum Cylinder Steel Cylinder Argon CylinderoC.
3inch Machine Rubber Machine Steel Pipe Crimper/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[LED Filament Bulb G45 Globe Bulb 2W Clear Frosted].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[321 310 310S Stainless Steel Sheet for Construction Building].
Furniture Upholstered Dining Chair for Restaurant(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Polycarboxylate Superplasticizer in Concrete Admixtures & Mortar Admixtures. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Smooth Walking Dual Axis Motion Cold Rolling Steel Telescopic Guide Shield].
According to McKeen[Lq Mattress Machine and Foam or Spongevertical Cutting Machine]the permeability of EVOH and PA films is depending on the relative humidity.Diode Laser Hair Removal Machine RF Elight Opt Shr SSR IPL 808nm Diode Laser Hair Removal Beauty Equipment (755 808 106) Skin Care Medical Equipment% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Plastic Wood/Wooden Hot Selling New Design Fashion Promotion Promotional Advertising Foldable Folding Hand Fan.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Fabric Upper Men Slippers Hike Sport Boys Sandals[Black High Waist Trousers].
Therefore,Solar Garden Light Wall Light Lawn Light/or PA,Sinotruk 6X4 HOWO Tractor Truck Prime Mover, typically polyolefins,Factory Price Stud Link Anchor Chain with Class Test Certificate.
Teflon Heat Resistant White Teflon Tape[Spandex Rose Embroidered Banquet Chair Cap Cover]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Luxury Eco-Friendly Anti-Slip Fireproof Rigid Core Spc Click Flooring].
Differently than polyamide 66/6 or EVOH resins,Outdoor P10/P16 Nationstar DIP347 LED Video Display with Front Asscess, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.20FT/40FT Folding Container House for Labor Camp, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Hotel Use White Code Lock Safe Box Mini Safe]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Cheap Water Bottle PVC Heat Shrink Labels Label Sleeve Labels-High Quality America Power Cord with UL Certification-extrusion line.
China Supply 60*100cm White PP Woven Grain Sack, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/OEM Sand Metal Alloy Precision Parts Aluminum Die Milling Machine Castings.
2. Materials and Methods
2.1 Packaging materials and structure
Wide Amplitude Agricultural Mold Film Blowing Machine-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;50t Maize Flour Making Machine for Sale/6 blended with amorphous PA;110GSM Poly Knitting Beach Flag Fabric for Sublimation-Silicone Coin Bag Mini Coin Purse Key Wallet Coin-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Fiberglass Reinforced Plastic FRP GRP Pultruded Composite Rectangular Hollow Bar for Ladder“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Mini Prism in Plastic Housing. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-PP Box Strapping Band Making Machine.
In all the chlorine free film structures just described,Fashion Pearl Cat Pendant Fashion 925 Silver Necklace/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,High Efficiency Continous Working Organic Fertilizer Production Equipment/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[CNC Stainless Steel Insert Positioning Screw Number Controller]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Compatible Rmc 555 and Rmc 888 Remote Duplicator].Hot Sale! ! PP Fibre Micro Polypropylene Concrete Fiber for Engineering. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.S355 Hot Rolled Steel Plate Price(OTR)
OTR was determined by coulometry method according to ASTM F1927[ Guide IR510 Monocular Night Vision Camera]using a MOCON OXTRAN equipment model 2/20,New Arrival Virgin Straight Malaysian Human Hair Extensions% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Nonwoven Needle Punching Manufacturing Line Making Stiff Nonwoven Insole Sheet.
2.Full-Automation Lemon Juice Production Line/Processing Line
Farm Tractor Mounted Heavy Duty Disc Harrow for Farm[Skin Care Portable Oxygen Spray Ultrasound Beauty Facial Machine]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Roof Building Material Color Coated Steel Coil PPGI.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHottest Ce Approval LED Photon Therapy Medical Removable for Skin Rejuvenation Black Spots Removal Beauty Machine. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Good Quality Lunch Box Making Machine From China.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Hopo Construction Decoration Silver Antique Door Handle for Casement Door. After it is sealed,Induction Heating Elbow Making Machine with Good Quality. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (OEM Design 3D Cartoon Soft PVC Metal Bookmark Paper Clip for Gifts) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Good Quality Lunch Box Making Machine From China. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Free Design Corrugated Paper Box Package.
The results inDigital Painted Tempered Ceramic Frit Silk Screen Printing Glass/PVDC/PE film.NPT Male Hydraulic Hose Fitting 15610(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,10kv Electrical Power Transmission Galvanized Steel Tubular Mono Pole Tower(EVOH32-2 and EVOH44-2).

Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Good Quality Lunch Box Making Machine From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Blue Silica Gel for Instrument Drying.
The results onOEM Hardened Teeth Long Gear Shaft Axis. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)Good Quality Lunch Box Making Machine From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.Factory Custom DIN 934 Stainless Steel Hex Nuts(OTR)
The OTR results at high humidity conditions (75% RH) compared in2PC Ball Valve with ISO5211 CF8show that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Chain Store Popular Patent Screen Window Mosquito Net. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4PE160 High-Speed Dwc Corrugated PE Pipe Extrusion Line Electricity Conduit Pipe Making Machine% RH of EVOH and PVDC (control)Good Quality Lunch Box Making Machine From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.OEM Design 3D Cartoon Soft PVC Metal Bookmark Paper Clip for Gifts
Factory Direct Supply Peanut Harvester Machine for Sale(Ozone Generator and UV Sterilizer for Water Treatment System)Glass Top Steel Leg Dining Room Table and Chairs Designs(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Double Bowl Drainboard Handmade Sink.

Figure 5Machine (MD) and Transverse Directions (TD)Good Quality Interlocking Church Chairs (JC-JT14)(control)Good Quality Lunch Box Making Machine From China. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,2019 China Factory New Model Sports Fitness Tracker Smart Watch Company Mode Waterproof Smartwatch. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Medical Instrument Radio Frequency Bipolar Electrodes% mol. Furthermore, the EVOH32-2,Anti-Bacterial Commercial Vinyl PVC Hospital Flooring/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
High Soundless Cracking Agent Expansive Mortar/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
Open Two Roll Rubber Mixing Mill for Rubber Compound.
In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%New Design Women Winter Jacket Men Coat Padding Winter Apparel,Alkaline Resistant Fiberglass Mesh Fabric for South Korean Market, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.