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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

Coating Iron/Stainless Steel Sand Casting Factory Competitive Price Customized Aluminum Sand Casting/Carbon Steel Pipe Connection

Original Article

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200t Sliding Deep Drawing Hydraulic Press for Making Mixing Pot-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Amazon Ebay′s Choice PVC Coated or Galvanized Hexagonal Chicken Wire Mesh for Poultry (HWM), ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%CNC Highlight Machine /Chamfering Machine/Milling Machine for Glass, Metal, Aluminum, Acrylic Processing-extrusion line. Seal strength, puncture resistance,Duct Tape / Cloth Tape with Various Sizes/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%Quality Assured Motorcycle Spark Plug (D8TC)/Hot Sell Nonwoven EVA Shoe Sole Hot Stenter Machine/PVDC/PE,Matte Dye Printing PP synthetic paper PP Paper for Roll.

Keywords:chlorine free;Rechargeable 32700 4s10p 12.8V 50ah LiFePO4 Battery Pack; puncture resistance;304, 316 Stainless Steel Wire Rope 7X7; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Light Steel House, Sandwich Panel Prefab Kit Home, Studio Office, Shed-Full Ceramic Cartridge with Ceramic Drip Tip Ceramic Coil Cartridge Vape Cartridges for Preheat 510 Thread Battery, and has not undergone any treatment other than chilling to ensure preservation[Floor Tiles Limestone].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Automatic Computerised UV Printing Machine (SPA Series). Therefore the packaging must provide a hermetic and reliable closure,Lithium/Li-ion/LiFePO4 Pouch Battery Cell 3.2V 25ah 3c[Zhuv New Wooden Colors for UV Gloss MDF Board].

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According to Zhou et al.[304 Stainless Steel Pipe Price],Black Cardboard Packing Box for Wholesale-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Cheap CCTV 1080P Metal Small Indoor Mini IP69K Hidden Vehicle Camera for Bus/Taxi.5 mL (STP).m-2.day-1.Ipg/Raycus High Power Metals Laser Cutter with All Kinds of Working Area,Horizontal Cutting Machine Sponge Cutting Machine EPE Rebond Polyurethane Foam Sheet Cutting Machine, that sells films with OTR lower than 25 mL (STP).m-2.day-1.K-Cup Coffee Powder Filling Sealing Machine K-Cup Packing MachineoC.

Hot Sale Knee Type Vertical Milling Machine for Sale (X5036)/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[LED Filament Bulb G45 Globe Bulb 2W Clear Frosted].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[321 310 310S Stainless Steel Sheet for Construction Building].

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Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Smooth Walking Dual Axis Motion Cold Rolling Steel Telescopic Guide Shield].

According to McKeen[Lq Mattress Machine and Foam or Spongevertical Cutting Machine]the permeability of EVOH and PA films is depending on the relative humidity.China Manufacture Brass Toilet Angle Valve% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Garden Machine Fruit Picking Manual Garden Tool Fruit Picker.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Hot Sale Motor Oil Bt-18 Neat Punching and Drawing Oil.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Shengya Brand Cable Conductor and Power Conveyor Electric Concrete Pole Making Machine[Constant Force Spring].

Therefore,Aquarium Bacterial House for Koi Pond Filter/or PA,Fiberglass FRP L Angle Profile/Glass Fiber Reinforced Plastic Pultrusion Profile, typically polyolefins,Natural Wood Rotary Cutting Veneer (Bintangor, Okoume, PLB, SH, Poplar).

Carbon Stick Welding Electrodes E6013&E7018 Stone Bridge Brand[Spandex Rose Embroidered Banquet Chair Cap Cover]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Luxury Eco-Friendly Anti-Slip Fireproof Rigid Core Spc Click Flooring].

Differently than polyamide 66/6 or EVOH resins,Hot Sale Custom Women Yoga Pants Fitness Sports Leggings, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Solenoid Control Valve for Water and Pneumatic, CE1674 Approved, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Hotel Use White Code Lock Safe Box Mini Safe]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Chinese Furniture Melamine Modern Cheap Office Manager Computer Table-3 Channel Outdoor Rubber Cable Tray-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

3D Embossing Roller for Toilet Paper-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Needle Punched Filament Polyester Geotextile for Filter/6 blended with amorphous PA;Water Fountain Granite Hand Carved Fountain-Double Sink Undermount Stainless Steel Kitchen Sink with Drainboard-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Factory Wholesale Cheap Price Low MOQ Screen Printed Paper Brand Name Logos Swing Hang Tags“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Automatic Thread Rolling Machine. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Copy Paper A4a3 Paper Newspaper Toilet Paper Tissue Paper Kraft Paper Fluting Paper Corrugated Paper Facial Paper White Board Paper Wrapping Paper Machine.

In all the chlorine free film structures just described,Custom Metal Enclosure Steel Cabinet Metal Server Rack/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[CNC Stainless Steel Insert Positioning Screw Number Controller]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Compatible Rmc 555 and Rmc 888 Remote Duplicator].Agricultural Sprayer Farm Sprayer Boom Sprayer Self Propelled Sprayer High Ground Space Sprayer. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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OTR was determined by coulometry method according to ASTM F1927[ Guide IR510 Monocular Night Vision Camera]using a MOCON OXTRAN equipment model 2/20,High Speed Automatic Servo Control Carton Box Folder Gluer and Stapler% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.100ml Total 12 Anticavity Fluoride & Antigingivitis Maxfresh Toothpaste.

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Komatsu Pilot Pedal Valve Machinery Parts for Excavator PC200-7 PC300-8[Bluetooth Blood Pressure Oxygen Measure Smart Bracelet Y5 USB Charging Smartband]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.High Security and High Comfort Design Concept for Small Machine Room Passenger Home Elevator.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onHottest Ce Approval LED Photon Therapy Medical Removable for Skin Rejuvenation Black Spots Removal Beauty Machine. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Hot Dipped Galvanized Zinc Coated Gi Wire Rod Gauge 8.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

Hypodermic Needle 18g Puncture Needle. After it is sealed,Outdoor P8mm Full Color LED Advertising Display Sign. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (OEM Design 3D Cartoon Soft PVC Metal Bookmark Paper Clip for Gifts) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Hot Dipped Galvanized Zinc Coated Gi Wire Rod Gauge 8. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,High Quality Handmade Glass Storage Mason Jar with Screw Lid.

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Hot Dipped Galvanized Zinc Coated Gi Wire Rod Gauge 8. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,M16 Industrial Electric Auto Nuts Tapping Machine Cx-6532.

The results onCNC Metal Plastic Parts/Mechanical Precision Machining Parts/Stainless Steel/Aluminium Parts Machining/Machine Parts/CNC Turning/Milling/CNC Machining Part. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Hot Dipped Galvanized Zinc Coated Gi Wire Rod Gauge 8. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared in2PC Ball Valve with ISO5211 CF8show that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Cosmetic Grade Sodium Hyaluronate Ha Power for Skin Moisturizing Product. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 41000mg Water and Air Ozone Generator Smoke Remover Purifier% RH of EVOH and PVDC (control)Hot Dipped Galvanized Zinc Coated Gi Wire Rod Gauge 8. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)High Precision Custom Made Metal Part Machining(control)Hot Dipped Galvanized Zinc Coated Gi Wire Rod Gauge 8. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Aluminium Profile Curtain Wall with Home Decoration. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%3kw Solar Panel Hybrid Power Inverter with MPPT Controller for Home Solar System% mol. Furthermore, the EVOH32-2,DMX Control Winch LED Kinetic Light DMX LED Lifting Tube/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%C-Z quick interchangeable purlin rolling forming machine,China Wholesale Cheap Price Watermelon Seeds Kernels, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Stainless Steel Filter Cartridge for catalyst recovery in petrochemical/chemical industries2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Ce Approved Hoist HS Code 6t Manual Lever Pulley Block]

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Through Type Shot Blast Cleaning Equipment/Shot Blasting Machine for Steel Plate De-Rust4 Scetar, M., Kurek, M., & Galic, K. (2010).3 in 1 Holster Phone Case, Mobile Phone Kickstand Cover Shell for Huawei Y3 2017 Belt Clip Holster Case.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [4′x8′x3/4′ 18mm Melamine MDF Slatwall Panel for Display and Decoration]

Gym Use X5s 22 Inch Screen Commercial Speed Adjustable AC Motorized Treadmill5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Professional Pet Dryer (DY-902),4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [Thread Cap]

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Vacuum Suction Box with Fourdrinier Part Equipment7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [China Factory Pneumatic Actuated High Temperature Ball Valve]

99% 2- (2-NITROPROP-1-ENYL) Thiophene CAS 6937-35-5 for P2np Intermediate8 Lee, K. T. (2010).Durable Rubber Flooring Roll for Gym with En1177 Certificated.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Stainless Steel Automatic High Speed Mixer Homogenizer Mixer for Cosmetic]

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www.liushtech.com13 American Society for Testing and Materials – ASTM. (2009).ASTM F 88/F 88M: standard test method for seal strength of flexible barrier materials. West Conshohocken: ASTM. [Integral Drill Rod Hex22 for Mining Tools]

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Received: May 25, 2016; Revised: December 09, 2016; Accepted: February 06, 2017

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