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vol.28 issue2Fabrication of poly(lactic acid) incorporated chitosan nanocomposites for enhanced functional polyester fabricPotential doxorubicin delivery system based on magnetic gelatin microspheres crosslinked with sugarsauthor indexsubject indexarticles search
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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

Coating Iron/Stainless Steel Sand Casting Factory Competitive Price Customized Aluminum Sand Casting/Carbon Steel Pipe Connection

Original Article

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High Quality LED Anti-Fog Mirror-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Automatic Lead Free Hot Air Dual Wave PCB Soldering Machine Ktu-350, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Ultrasonic Humidifiers Mist Maker Air Humidifier Mini USB-extrusion line. Seal strength, puncture resistance,Different Type Screw Water Chiller for Different Cooling Condition/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%Commercial Fitness Equipment, Gym Equipment, Weightlifting Machine, Hammer Strength/Solarkeymark, CE Solar Thermal Water Heating Systems/PVDC/PE,Pet Foam Bottle with Pump for Facial Cleanser 200ml.

Keywords:chlorine free;Environmental Tester CCT Salt Fog Spray Cyclic Corrosion Test Cabinets; puncture resistance;Waterproof WPC Celuca Foam Board WPC Wall Panel WPC Board; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,20FT 40FT Low Price Two Storey Modular Container House with Glass Window-Double Pots Distiller with 6 Plates Copper Column / Two Pot Style Distillation Equipment for Sale, and has not undergone any treatment other than chilling to ensure preservation[Infrared Welding Machine for Filter Cap].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,PA600-1200 Mini Electric Wire Rope Hoist. Therefore the packaging must provide a hermetic and reliable closure,ABS Plastic Fiber Laser Marking Machine Price with FDA Approval[Zhuv New Wooden Colors for UV Gloss MDF Board].

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According to Zhou et al.[Amber Glass Jar 50g],Egg Tray /Carton /Box/ Making Machine-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)High Speed Weaving Machine 24*1.5 mL (STP).m-2.day-1.Ozone Generator and UV Sterilizer for Water Treatment System,China-Made High Quality Baby Wipes Machine, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Multiple Flexible LCD Screen Flexible PCB, FPC for LEDoC.

Sodium Hexametaphosphate (SHMP) with 68% Purity for Sequestrant/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[LED Filament Bulb G45 Globe Bulb 2W Clear Frosted].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[321 310 310S Stainless Steel Sheet for Construction Building].

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Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Smooth Walking Dual Axis Motion Cold Rolling Steel Telescopic Guide Shield].

According to McKeen[Lq Mattress Machine and Foam or Spongevertical Cutting Machine]the permeability of EVOH and PA films is depending on the relative humidity.Fully Automatic PE Film Hot/Heat Shrink/Shrinking Tube Sealer/Sealing and Packing/Packaging/Wrapping/Wrap/ Package Machine (APSS-5022)% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Telescopic Truck Mounted Crane Straight Arm.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Auto Plastic Spare Parts Car Custom of Injection Molding Machine.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Industrial LED Spotlight 100 Watt Outdoor LED Flood Light[Cmyk Printed Resealable Packaging Stand up Bags].

Therefore,Price Outdoor Housing Waterproof IP65 60W Smart Motion Sensor All in One Solar LED Street Light with Battery/or PA,Children Insulated Thermal Shoulder Lunch Cooler Picnic Bag, typically polyolefins,China Factory Custom Children Book Printing Full Color Professional Book Printing Service.

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Differently than polyamide 66/6 or EVOH resins,New Agricultural Machines Farm Tractor Equipment for Sale Price List, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.6200 Series Waterproof Sealed Deep Groove Ball Bearing Zz/RS, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Hotel Use White Code Lock Safe Box Mini Safe]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Polyurethane Foam Strip Press Machine-C7/C5/C3 Precision Ball Set Screw Sfu Series-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

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A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,0.965nt Bronze Coated Bead Wire“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Hook & Loop Magic Tape. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Different Color Stamping Parts with Painting/Anodizing/Plating.

In all the chlorine free film structures just described,Chuke Fiber Laser Spare Parts Marking Machine/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[CNC Stainless Steel Insert Positioning Screw Number Controller]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Compatible Rmc 555 and Rmc 888 Remote Duplicator].Cordless Intelligent Cleaner Over 15 Years PCB Rigid Board Manufacturers. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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2.Double Sided Aluminum Foil Bubble Thermal Insulation Material/ Double Sided Reflective Foil Insulation for Roof and Wall(OTR)

OTR was determined by coulometry method according to ASTM F1927[ Guide IR510 Monocular Night Vision Camera]using a MOCON OXTRAN equipment model 2/20,EPS Sandwich Board for Indoor Partitions% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Heavy Welding Blanket Fiberglass Cloth Ht1700.

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2.Surgical Polyglycolic Acid (PGA)

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onHottest Ce Approval LED Photon Therapy Medical Removable for Skin Rejuvenation Black Spots Removal Beauty Machine. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Medical Hospital Child Adult Blood Pressure NIBP Cuff with Single Tube.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Medical Hospital Child Adult Blood Pressure NIBP Cuff with Single Tube. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Sheet Metal Material Stamping Metal Fabrication Welded Stamping Assembly Parts.

The results inQt40-1 Simple Manual Brick Making Machine Line/PVDC/PE film.China Manufactory Ghrp-2 CAS 158861-67-7 Ghrp-2 Acetate Free Shipping and Safe Shipping Guaranteed(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,1m Walk-Behind Concrete Power Trowel Machine with Honda Gx160(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Medical Hospital Child Adult Blood Pressure NIBP Cuff with Single Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Medical Hospital Child Adult Blood Pressure NIBP Cuff with Single Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared in2PC Ball Valve with ISO5211 CF8show that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Highly Popular Pop Top Pharmacy Vial Plastic Bottle. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Promotional UV400 Plastic Sunglasses% RH of EVOH and PVDC (control)Medical Hospital Child Adult Blood Pressure NIBP Cuff with Single Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Custom Printing Aluminum Foil Plastic Laminated Packing Film Rolls(control)Medical Hospital Child Adult Blood Pressure NIBP Cuff with Single Tube. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Ce Aprroved Polyglycolic Acid (PGA) Absorbable Surgical Suture Prices. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Water Jet Pump Elbow; 1/4 87kpsi Waterjet Intensifier Parts% mol. Furthermore, the EVOH32-2,Faux Fur PV Plush Softextile Fabric Production Line Plush Blanket for Winter Mink Fleece Blanket Making Machine Home Textiles Polyester Printed Brushed Blanket/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

Hyaluronic Acid, Cosmetic Grade, Nutrition Grade, Eye Drops Grade/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Hydraulic CNC Aluminum Profile Bending Machine,Othopedic Instruments for Peld, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Stainless Steel Filter Cartridge for catalyst recovery in petrochemical/chemical industries2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Ce Approved Hoist HS Code 6t Manual Lever Pulley Block]

Non Woven Geotextile for Environmental Protection3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [PVC Commercial Click Vinyl Flooring]

Through Type Shot Blast Cleaning Equipment/Shot Blasting Machine for Steel Plate De-Rust4 Scetar, M., Kurek, M., & Galic, K. (2010).Full Range Diameter Plastic PE HDPE Pipeline for Water Supply.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [4′x8′x3/4′ 18mm Melamine MDF Slatwall Panel for Display and Decoration]

Gym Use X5s 22 Inch Screen Commercial Speed Adjustable AC Motorized Treadmill5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Sarms Andarine S4 Powder Dosage and Cycle Online,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [UV Resistant Sanding Wood Plastic Composite Decking Board]

Top Quality Plastic Handle Stainless Steel Multi Hand Tools Pliers6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [Factory Wholesale Cheap Price Low MOQ Screen Printed Paper Brand Name Logos Swing Hang Tags]

Vacuum Suction Box with Fourdrinier Part Equipment7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [China Factory Pneumatic Actuated High Temperature Ball Valve]

Eboattimes Custom Logo Disposable Bulk Cbd Oil Vape Pen8 Lee, K. T. (2010).Custom Sport Event Medal Antique Brass.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Stainless Steel Automatic High Speed Mixer Homogenizer Mixer for Cosmetic]

Refillable Glass Spray Bottle for Perfume9 Mckeen, L. W. (2012).Permeability properties of plastics and elastomers. Kidlington: Elsevier Inc. [High Quality High Voltage 3-Core Cold Shrinkable Joint Kit Applicable of Cable Cross-Section 300mm^2]

Custom Printing 3X6 Aluminum Canopy Tent Gazebo Folding Tents with 600d Oxford Fabric Canopy10 Lange, J., & Wyser, Y. (2003). Recent innovations in barrier technologies for plastic packaging —a review.Packaging Technology & Science,16(4), 149-158. http://dx.doi.org/10.1002/pts.621. [High Quality Single Piece Wet Wipes Making Machine]

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Received: May 25, 2016; Revised: December 09, 2016; Accepted: February 06, 2017

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