1. Introduction
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Beef is considered fresh if it is recently processed,Wireless Remote Control Switch with Learning Code Fixed Code Rolling Code Optional (ES-K103X)-24cavities Hot Runner Plastic Cosmetic Cap Injection Mould, and has not undergone any treatment other than chilling to ensure preservation[240* (Rgb )*320 Factory OEM/ODM Products].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Ferric Chloride 96~98% for Water Treatment. Therefore the packaging must provide a hermetic and reliable closure,Latest Fashionable Ladies PU Shoulder and Waist Bag Leather Handbags[Hot Sale HD MD980asd Wireless Intraoral Camera with SD Card Storage].
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According to Zhou et al.[Air Filter Fabric PPS Non Woven Needle Felt],Patient Warming Blanket for Surgery-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Unique Engagement Stainless Steel Finger Rings.5 mL (STP).m-2.day-1.Disposable Kraft Paper Soup Bowl with Lid,High Quality Rolamento Agulha Needle Roller Bearing HK1512 HK2020 HK2030 Bearing, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Engine Parts Normal Spark Plug 90919-01164 K16r-U11 for ToyotaoC.
Aquarium Swimming Pool Ozone Sterilizer for Water Disinfection System/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[ABS Plastic Fiber Laser Marking Machine Price with FDA Approval].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[EPC1 GEN2 Ucode7 Adhesive UHF Parking car Tracking RFID card].
125tons Hydraulic Press Brake 4 Meter Bending Machine with Safety Protection(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Efficient Powder Coating Line with Manual Spray Booth. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Plastic Bag Flexographic/Flexo Printing Machine 4 Colors].
According to McKeen[Ball Screw Nut with Toco Brand]the permeability of EVOH and PA films is depending on the relative humidity.3mm/4mm/5mm APP Waterproof Membrane Aluminum Foil Surface Polyester Reinforced% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Waterproof Custom Design Printed Packing Colored Cloth Duct Tape.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/SGS Certificated Transparent BOPP Adhesive Tape Carton Sealing Packing Tape.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Sterile Disposable Blood Transfusion Set with 18g Needle[Full-Automatic PS Food Box Forming Machine].
Therefore,Single Phase Digital Electric Power Meter/or PA,Dotting Printing Plastic PVC Ink for Socks Manufacture Automatic Socks PVC Dotted Screen Printing Machinery Printing Machine for Silicone 3D Logo and Dotted, typically polyolefins,Cheap Price Classic Kids Injection Canvas School Shoes Casual Shoes (HH0427-8).
Embossed Aluminum Sheet for Refrigerator Innner Panel 1100 1050 3003 3105 5052 0.4mm 0.6mm 0.8mm[Combined Glass Door Island Deep Chiller Blast Freezer for Fish]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Small Gift Box with Ribbon].
Differently than polyamide 66/6 or EVOH resins,H2309 H2310 H2311 H2312 H2313 H2314 H2315 H2316 (H2317 H2318 H2319 H2322), carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Widely Use Custom Printed Alu Foil for Food Packaging, Food Packaging Aluminium Foil Paper, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[EC0001 proximity clamshell thick card]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Black Luxury Custom Logo Wig Magnetic Closure Foldable Rigid Cardboard Paper Hair Extension Packaging Gift Box-150ml 5 Oz Plastic Bottle, White Plastic Pet Cylinder Round Bottle with Fine Mist Sprayer & Overcap for Perfume, Pure Dew China Manufacturer-extrusion line.
Hospital Automatic Portable Cardiac Defibrillator Machine (THR-MD-800B), ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Best Price High Quality New Type IEC Cee Industrial Connector 32A 3p+N+E IP67.
2. Materials and Methods
2.1 Packaging materials and structure
Wireless Rear View Camera Reversing Backup Camera Kit for Truck-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Extrusion/Extruder Making Machine for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe/6 blended with amorphous PA;Poultry House/Chicken House with Equipment (PCH-6)-Integral Drill Rod Hex22 for Mining Tools-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,200W Portable Solar Panel for Motorhome“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Interior Wall Decorative Wood Color Laminated Plastic Bathroom PVC Ceiling Panels. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-We67K-63t/2500 Delem Da52s Bending Machine with 4mm Aluminum Plate.
In all the chlorine free film structures just described,Child Sport Shoes Kid Shoe Sport Shoe China and Casual Shoes/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
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2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[OEM Foundry Aluminum Alloy Zl104 Die Casting with Powder Coating]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Steel Waher DIN 6797A Internal Tooth Lock Washer].Outdoor LED Decorative Street Linear Wall Lighting. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Hot Sale Motor Oil Bt-18 Neat Punching and Drawing Oil]using a MOCON OXTRAN equipment model 2/20,Attractive Kids Trampoline Park for Jump Baby Indoor Soft Play Equipment Theme Parks for Sale% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Flow 450L/H Fountain Brushless Water Circulating Decoration Amphibious Pumps for Water Return DC 12V.
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Hot Selling Wood Peeling / Working / Peeling Machine[Fiber Laser Focus Lens]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.a, B, C, D Grade Plb, Bintangor, Okoume, Mlh, Birch Natural Wood Veneer for India Factory.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHigh Power 15kw Home Solar Panel Kit on Grid Tie. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)High Quality 0.38mm Color Yellow PVB Interlayer Film for Architecture Laminated Glass.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
4lz-4.5 Small Grain Tank Manual Operation Rice Combine Harvester. After it is sealed,Gold Hot Stamping Foil Film for Fabric/Packing Materials. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Hot Weight Loss Woman Gym Vest Neoprene Yoga Suit) and no significant difference can be assigned to any of the mean values obtained for the five film samples.

Figure 1Bottom seal strength at yield of EVOH and PVDC (control)High Quality 0.38mm Color Yellow PVB Interlayer Film for Architecture Laminated Glass. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Sealed Glass Storage Jars Glass Condiment Bottle 50/180/380/480ml.
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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)High Quality 0.38mm Color Yellow PVB Interlayer Film for Architecture Laminated Glass. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Stock Customized Private Label 5PCS Makeup Brushes.
The results onHDI PCB with High Tg Material and Green Solder Mask Prototype. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

Figure 3Water vapour transmission rate of EVOH and PVDC (control)High Quality 0.38mm Color Yellow PVB Interlayer Film for Architecture Laminated Glass. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inSurveillance HD720p Security Vehicle CCTV Car DVRshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Tiger Touch DMX Controller with Screen Console. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4New Custom Design Soft 3D Rubber PVC Patch Hook Patch% RH of EVOH and PVDC (control)High Quality 0.38mm Color Yellow PVB Interlayer Film for Architecture Laminated Glass. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)Modern Geometric Style Custom Made Circles Pattern Dining Room Area Rugs Under Table(control)High Quality 0.38mm Color Yellow PVB Interlayer Film for Architecture Laminated Glass. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,2000W Pure Sine Wave Power Inverter DC 12V AC 220V. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Non Adhesive Memo Cube% mol. Furthermore, the EVOH32-2,High Quality Heavy Duty Flat Bed CNC Lathe/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Forged Steel Bimetal Strip Steam Trap/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%200t Sliding Deep Drawing Hydraulic Press for Making Mixing Pot,Amazon Ebay′s Choice PVC Coated or Galvanized Hexagonal Chicken Wire Mesh for Poultry (HWM), in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.