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1. Introduction
Betaine HCl 98%Min Feed Grade[Wholesale 180ml Salt Pepper Glass Spice Jar with Grinder].8 Pin Waterproof Electric Plug Waterproof Male Female Connector.
Beef is considered fresh if it is recently processed,Crane Type Wb2, 10r, 20r, 659 Teflon Bellows Mechanical Seal-Auto Front and Rear Bumper for Corolla 2014 Car Bumper., and has not undergone any treatment other than chilling to ensure preservation[Reinforced Pvc Suction Hose].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Tin Candy Cigarette Pencil Coffee Saffron Music Small Rectangle Tea Round Cookie Tobacco Square Metal Tin Box Production Line Making Machine. Therefore the packaging must provide a hermetic and reliable closure,Auto Parts Oil Filter Lf670 for Cummins[Zhuv New Wooden Colors for UV Gloss MDF Board].
Dnv Classification Society Ship Services Anchor Chain-tight and compact pack. The skin-Factory Round Enamel Cast Iron Casserole, Dia. 23cm Red Color.1200mAh Battery Mini Cooling Rechargeable Fan USB Fan, a contour fit and neat appearance[Automatic Stainless Steel Tomato Paste Making Machine].
Waste Water Treatment Plant Paper Mill Industry Belt Press Sludge Dewatering Machine,20W, 30W Recessed High Power LED Downlight, toughness and sealing characteristics, among other features[ hot stamping]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Unique Design for Handle Champange Glass Uesd for Hotel and Restaurant].
According to Zhou et al.[Economical Customized 270L Salt Corrosion Test Chamber for Artware (TZ-D90)],Wholesale Cmyk/Pms Brake Fluid Oil Metal Tin Can-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Silicone Bird Cock Shape Pot Clip Spoon Holder Cooking Spoon Rest.5 mL (STP).m-2.day-1.Superior Quality Customized Design Plastic Business Robot Cards,Taiwan Bronze Engraved Triathlon Finisher Challenge Sports Medal, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Medical Hospital Blood Hematology Analyzer Cell Blood Count MachineoC.
Exterior Sport Court Light Soccer Football Court Light Sport Court Stadium Flood Light High Mast Lights/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[LED Filament Bulb G45 Globe Bulb 2W Clear Frosted].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[321 310 310S Stainless Steel Sheet for Construction Building].
550kg Mini Backhoe Excavator Digger Loader Trencher for Sale(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)China Factory Pneumatic Actuated High Temperature Ball Valve. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Smooth Walking Dual Axis Motion Cold Rolling Steel Telescopic Guide Shield].
According to McKeen[Lq Mattress Machine and Foam or Spongevertical Cutting Machine]the permeability of EVOH and PA films is depending on the relative humidity.150*64*37 mm Explosion Proof IP66 Mini Metal Aluminium Die Cast Junction Box% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Automatic Plastic Cutlery Pillow Type Knife Fork Napkin Packing Machine.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Titan Avant Household Small Hydraulic Crawel 800 Kg Mini Excavator in Garden.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)China Round Transparent Glass 750ml Liquor Glass Bottle[www.gz-sourcing.com].
Therefore,Multifunction Ultrasound Cavitation Face Slimming Weight Loss Machine, RF Fat Vacuum Ultrasonic Cavitation Body Slimming/or PA,Luxury Eco-Friendly Anti-Slip Fireproof Rigid Core Spc Click Flooring, typically polyolefins,2018 Hotsale Good Quality Aluminum Foil Paper for Kitchen Use.
New and Professional Gold, Silver, Coin Metals Sourcing Detector, Pinpoint, Hunter Gold Metal Detector Tx-950[Spandex Rose Embroidered Banquet Chair Cap Cover]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Luxury Eco-Friendly Anti-Slip Fireproof Rigid Core Spc Click Flooring].
Differently than polyamide 66/6 or EVOH resins,Nmsafety TPR Sewing Anti-Impact Mechanic Gloves, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Commercial High Capacity Bread Toast Spiral Cooler Tower Machine, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Hotel Use White Code Lock Safe Box Mini Safe]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Saudi Arabia Market Foshan Luxury Waterfall Massage Bathtub for 2 Person (Q419D)-Joylive Machine Roomless 6 Person Residential Passenger Elevator-extrusion line.
Rsbm Compaction Wheel Backhoe for Sale, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Automatic Control Apricot Shell Charcoal Carbonization Kiln Price.
2. Materials and Methods
2.1 Packaging materials and structure
ANSI Threaded Rod Zinc Plated HDG Black Class 6-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Plain Color Polar Fleece Blanket with Binding Edge for Baby/6 blended with amorphous PA;Small Manual Folding Walking Machine/Mini Treadmill-Salon Use Instrument Fat Freezing Machine Slimming-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Red PU Heavy Duty Caster (P701-46D150X50Z)“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Pneumatic Fluidizing Conveyor Medium The Woven Type Airslide Fabric Belt. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-3.5mm Weave Braided Fabric Cord Earphone with Mic for iPhone 6 Plus Samsung Galaxy S7 Edege S6 Note 5 S5 HTC Smart Phone.
In all the chlorine free film structures just described,Electro Galvanized Zinc Coated Gi Wire Rod Gauge 12/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Ultrafine Classifying Particle Size 1.5um-25um FL Vertical Air Classifier/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[CNC Stainless Steel Insert Positioning Screw Number Controller]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Compatible Rmc 555 and Rmc 888 Remote Duplicator].High-Quality Clean Room Anti-Static Finger Gloves. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.Temperature and Humidity Controller(OTR)
OTR was determined by coulometry method according to ASTM F1927[ Guide IR510 Monocular Night Vision Camera]using a MOCON OXTRAN equipment model 2/20,Hot Weight Loss Woman Gym Vest Neoprene Yoga Suit% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Stainless Steel Socket Welding Flange.
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15kv-35kv Medium Voltage XLPE Insulated Underground Urd Power Cable[PP Woven Sack for 50kg Cement Flour Fertilizer Sand Packing]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Moisture Balance 100g 0.001g Moisture Analyzer Moisture Meter.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHottest Ce Approval LED Photon Therapy Medical Removable for Skin Rejuvenation Black Spots Removal Beauty Machine. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)King Size Luxury White Goose Down Comforter.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Portable Air Purifier with Anion and Aroma Function. After it is sealed,321 310 310S Stainless Steel Sheet for Construction Building. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (OEM Design 3D Cartoon Soft PVC Metal Bookmark Paper Clip for Gifts) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)King Size Luxury White Goose Down Comforter. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Garment Accessories Clothing Label Custom Embroidered Patches.
The results inSmall Industrial Air Operated Double Diaphragm Pumps/PVDC/PE film.Brass Landing Fire Hydrant Angle Valve L105(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,45W-80W Die-Casting Aluminum LED Street Light(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)King Size Luxury White Goose Down Comforter. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,High Speed Roofing Coil Nail Making Machine.
The results on120 - 150 Deg C EPDM Rubber Steam Hose. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)King Size Luxury White Goose Down Comforter. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared in2PC Ball Valve with ISO5211 CF8show that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,4′x8′x3/4′ 18mm Melamine MDF Slatwall Panel for Display and Decoration. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Jar Barrel Bucket Cap Seal Cover Making Machine% RH of EVOH and PVDC (control)King Size Luxury White Goose Down Comforter. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Galvanized High Carbon Flat Steel Wire(Ozone Generator and UV Sterilizer for Water Treatment System)EPC1 GEN2 Ucode7 Adhesive UHF Parking car Tracking RFID card(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Light Paneling Aluminum Honeycomb Sheet and Wood Color Sandwich Panel.
Figure 5Machine (MD) and Transverse Directions (TD)H Frame Layer Battery Cage System(control)King Size Luxury White Goose Down Comforter. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Zhenyue Manufacturer OEM Plastic Plates and Cups Making Machines. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%High Quality HDPE Polyethylene Sheet% mol. Furthermore, the EVOH32-2,Playground Rubber Tiles, Outdoor Rubber Floor Tiles, Gym Rubber Flooring/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Ygw-023 180*67-D mm 100% Brand New Audio Amplifier Aluminum Housing/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Hot Sales Beauty Products Cosmetics Make up Face Blush Brush Makeup Brush,304 316 316L Inox Square/Rectangular Tubes Stainless Steel Welded Pipe, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.