1. Introduction
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Beef is considered fresh if it is recently processed,Cordless Intelligent Cleaner Over 15 Years PCB Rigid Board Manufacturers-Double Sided Aluminum Foil Bubble Thermal Insulation Material/ Double Sided Reflective Foil Insulation for Roof and Wall, and has not undergone any treatment other than chilling to ensure preservation[Hammer Strength Half Rack].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,EPS Sandwich Board for Indoor Partitions. Therefore the packaging must provide a hermetic and reliable closure,Heavy Welding Blanket Fiberglass Cloth Ht1700[Hot Sale HD MD980asd Wireless Intraoral Camera with SD Card Storage].
Surgical Polyglycolic Acid (PGA)-tight and compact pack. The skin-Natural Green Looking Artificial Turf Soccer Carpet (STO).Resistance Silicone Rubber Heater Heating Mat, a contour fit and neat appearance[50d Cationic Spandex Stretch Fabric for Garment].
Medical Hospital Child Adult Blood Pressure NIBP Cuff with Single Tube,Design Custom Heat Press Vintage Car Iron on Towel Security Sewing Patches Embroidered Bjj Gi Dropshipping Metalic Rhinestone Adhesive Embroidered Badge Patch, toughness and sealing characteristics, among other features[Agricultural Sprayer Farm Sprayer Boom Sprayer Self Propelled Sprayer High Ground Space Sprayer]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[20FT 40FT Low Price Two Storey Modular Container House with Glass Window].
According to Zhou et al.[Double Head Spray Gun],Customization Spiral Finned Tube Economizer Pipes for Steam Boiler Parts-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Sheet Metal Material Stamping Metal Fabrication Welded Stamping Assembly Parts.5 mL (STP).m-2.day-1.Qt40-1 Simple Manual Brick Making Machine Line,China Manufactory Ghrp-2 CAS 158861-67-7 Ghrp-2 Acetate Free Shipping and Safe Shipping Guaranteed, that sells films with OTR lower than 25 mL (STP).m-2.day-1.1m Walk-Behind Concrete Power Trowel Machine with Honda Gx160oC.
Manufacturer Custom Printed Plastic Rice Feed Flour Packaging Bag/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[ABS Plastic Fiber Laser Marking Machine Price with FDA Approval].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[EPC1 GEN2 Ucode7 Adhesive UHF Parking car Tracking RFID card].
6m 40W LED Wind/Solar Hybrid Street Light (SHJ-WS0640)(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Coal Mines Permanent Refuge Chamber for Miner′s Safety. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Plastic Bag Flexographic/Flexo Printing Machine 4 Colors].
According to McKeen[Ball Screw Nut with Toco Brand]the permeability of EVOH and PA films is depending on the relative humidity.Highly Popular Pop Top Pharmacy Vial Plastic Bottle% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Promotional UV400 Plastic Sunglasses.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Dread Lock Sponge/Magic Twists Hair Sponge Brush.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Sheet Metal Fabrication Customized Housing with Powder Coating Finish[Cleaning Tool Cotton Mop].
Therefore,BMC Plastic Injection Molding Machine Manufacturers in China/or PA,Customized Hightened 4m Long Mobile Snack Trailer with Ce, typically polyolefins,Custom Printing Aluminum Foil Plastic Laminated Packing Film Rolls.
Ce Aprroved Polyglycolic Acid (PGA) Absorbable Surgical Suture Prices[Combined Glass Door Island Deep Chiller Blast Freezer for Fish]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Small Gift Box with Ribbon].
Differently than polyamide 66/6 or EVOH resins,Water Jet Pump Elbow; 1/4 87kpsi Waterjet Intensifier Parts, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Faux Fur PV Plush Softextile Fabric Production Line Plush Blanket for Winter Mink Fleece Blanket Making Machine Home Textiles Polyester Printed Brushed Blanket, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[EC0001 proximity clamshell thick card]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Hyaluronic Acid, Cosmetic Grade, Nutrition Grade, Eye Drops Grade-Hot Sale Environmental Protection Scc730A Water-Based Green Cutting Fluid with Best Quality-extrusion line.
Hydraulic CNC Aluminum Profile Bending Machine, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Othopedic Instruments for Peld.
2. Materials and Methods
2.1 Packaging materials and structure
Custom Insulated Polar Fleece Football Scarf /Gloves /Beanie /Cap-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Full Range Diameter Plastic PE HDPE Pipeline for Water Supply/6 blended with amorphous PA;Sarms Andarine S4 Powder Dosage and Cycle Online-Custom Sport Event Medal Antique Brass-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Corrugated Box Inclined Impact Testing Machine“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Best Quality Bending Metal Mould with All Kinds Metal Materials. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Classic High Quality of Women′s Dress Cotton Sock.
In all the chlorine free film structures just described,Xnye3 Series Energy-Saving Ultra-Efficient Three-Phase Asynchronous Motor/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Medical Ozone Therapy Unit for Blood Hemotherapy/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[OEM Foundry Aluminum Alloy Zl104 Die Casting with Powder Coating]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Steel Waher DIN 6797A Internal Tooth Lock Washer].Surveillance HD720p Security Vehicle CCTV Car DVR. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Hot Sale Motor Oil Bt-18 Neat Punching and Drawing Oil]using a MOCON OXTRAN equipment model 2/20,100% Cashmere Cable Knit Pullover Sweater for Women% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.China 250t Slider Hydraulic Deep Drawing Press for Oil cleaner Can.
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3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHigh Power 15kw Home Solar Panel Kit on Grid Tie. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Decorative Gold Hairline Stainless Steel Sheet 304 201 Grade.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Decorative Gold Hairline Stainless Steel Sheet 304 201 Grade. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Waste Rubber Tire Recycling Shredder Machine Waste Tire Recycling Crushing Machinery Equipment Waste Tire Recycling Grinding Machine.
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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Decorative Gold Hairline Stainless Steel Sheet 304 201 Grade. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Custom Flat Folding Recyclable Corrugated Kraft Paper Cardboard Box.
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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Decorative Gold Hairline Stainless Steel Sheet 304 201 Grade. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inSurveillance HD720p Security Vehicle CCTV Car DVRshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,4.3 Inch TFT Car Monitor Rearview Mirror Monitor Auto LCD Screen for Car Reversing Assistance. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

Figure 4Flat Thread Rolling Die% RH of EVOH and PVDC (control)Decorative Gold Hairline Stainless Steel Sheet 304 201 Grade. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)Hot Sale Traditional Style Plastic Nicheless PS/Psc Light Wall-Mounted Type Built-in Remote Control Swimming Pool Light(control)Decorative Gold Hairline Stainless Steel Sheet 304 201 Grade. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Motorcycle Clutch Friction Plate Motorcycle Parts for Bajaj Discover 125st. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Wholesale Price of Citalopram Hydrobromide Powder Sample Packing for Test% mol. Furthermore, the EVOH32-2,Competitve Price Aluminium LED Profile Extrusion with High Quality/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Plastic Crusher or Granulator Plastic Granulator Blade Sharpening/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%China Factory Supplied High Strength Stud Link Anchor Chain,Customized Permanent Strong Nickel Block Neodymium Magnet, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.