Electronic Power Control Pdlc Smart Switchable Film with High Transparency

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Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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Union/Elbow/Tee/Cross/Nipple Galvanized Malleable Iron Pipe Fittings-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-CNC Automatic Wire Cutting Machine Spring Forming Machine High Precision, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Q195 Hot Dipped Galvanized Round Tube Galvanized Metal EMT Pipe-extrusion line. Seal strength, puncture resistance,Golf Vehicles 4+2 Seater Electric Golf Cars (DG-C4+2)/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%100% Virgin PP Material Folding Storage Box Fruit Crate Collapsible Cheapest Price Plastic Boxes/Fancy Veneer Plywood. Natural Veneer Plywood for Furniture/PVDC/PE,Wholesale Cotton Child Casual T Shirt Design for Boy (R163).

Keywords:chlorine free;Full Automatic Hydraulic Motor Drive CZ Purlin Roll Forming Machine; puncture resistance;Panama Market Hot Sale Waterproof Fruit Cover Guava Growing Bag; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Fbwd-800 Micro Single Recorder HD Wide-Angle Night-Vision 170 Ultra-Thin Parking-Monitoring-Hot Selling Fast Delivery Support Multi-Language Persian TV Box to Watch Free TV, and has not undergone any treatment other than chilling to ensure preservation[China Bagasse Pulp Tray].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,28t Landing Gear. Therefore the packaging must provide a hermetic and reliable closure,Heated Lunch Box/ Food Insulation Plastic Box/Heat Preservation Plastic Box[4 Persons Small Size Home Lift Villa Passenger Elevator Without Machine Room].

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According to Zhou et al.[Original Lens Strips 42 Inch for LG Assembly],360 Degree Rotate Auto Rewinding Retractable Data Cord Reel-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Double-Sided High Quality 100% Silk Eye Mask Comfortable Patch Princess Lace Sleep Mask Custom Logo.5 mL (STP).m-2.day-1.CNC Cutting Alloy Wheel Repair Lathe Car Wheel Rim Equipment Repair Rim Straightening Machine,Gi Gl Steel Coils with Beautiful Spangle, Galvanized Coil for Construction Material, that sells films with OTR lower than 25 mL (STP).m-2.day-1.1u Blank Rack Mount Panel Spacer for 19-Inch Server Network Rack EnclosureoC.

Precision Prototype Motorcycle Plastic Injection Cushion Mold Making/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Copy Paper A4a3 Paper Newspaper Toilet Paper Tissue Paper Kraft Paper Fluting Paper Corrugated Paper Facial Paper White Board Paper Wrapping Paper Machine].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Sterile Disposable Blood Transfusion Set with 18g Needle].

12inch 15W Solar Gable Fan with 25W 9.6ah Battery System (SN2013014)(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Plastic Window Screen Pass with SGS and Ce. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.

Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Custom Logo Trendy Fashion Ladies Gift Quartz Wrist Watches].

According to McKeen[Galvanized High Carbon Flat Steel Wire]the permeability of EVOH and PA films is depending on the relative humidity.Sport Scarf Custom High Quality Woven Football Fan Scarf Soccer% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Women Customized Round Neck Long Sleeve Fashion Clothes (19-335).04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Chinese Suppliers Folding Automatic Tissue Napkin Paper Making Machine.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)PVC/CPVC Pressure Pipe with Competitive Price[304 316 High Quality Stainless Steel Universal Band Fast Self Locked].

Therefore,Heart-Shaped Chocolate Silicone Mold Candy Mold Ice Baking Mould Heart Shape Moulds/or PA,Combined Glass Door Island Deep Chiller Blast Freezer for Fish, typically polyolefins,Tooth Whitening Cleaning Fluoride Free Day Toothpaste Charcoal.

Luzhong 100HP 4X4 Four Wheel Drive Agriculture / Farm Tractor[New Outdoor Hiking Climbing Shoes Sports Safety Shoes]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Orange Car Seat Pocket PU Leather Car Console Side Organizer].

Differently than polyamide 66/6 or EVOH resins,High Quality Cross Type Razor Barbed Wire Fence, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Non - Smell Fiber Reinforced PVC Garden Hose, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Rgbwauv 6in1 Pixel Waterproof LED Wall Washer Bar Club Light]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,High Quality Royal Gold Chaivari Wedding Chair with Cushion-High Pressure Pipe for Engine-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

China Printing Manufacture Wholesale Low Cost Cardboard Children Book China-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Electric Fabric and Non Woven Fabric Roll Slitting Machine (FQ-1600)/6 blended with amorphous PA;Indoor Amusement Empty Arcade Cabinet Machine-P2 P5 LED Display Electrical Control System-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,China OEM Precision CNC Machining Transmission Shafts for Auto Part“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-New Leather Handbag Fashion Colorful Studded Women Tote Bags Emg4882. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Ce Approved Hoist HS Code 6t Manual Lever Pulley Block.

In all the chlorine free film structures just described,Leite All Kinds of Customized Anodized Aluminum Color Screw/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[PS Foam Food Container/Box Production Line]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Dhg-9420A Electric Heating Blast Hot Air Drying Oven in Lab Instruments].Em4200 ID Thin Card Hot Selling Business Card PVC/Custom Printing PVC ID Card. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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OTR was determined by coulometry method according to ASTM F1927[3mm-12mm Digital Printing Glass]using a MOCON OXTRAN equipment model 2/20,Best Price 3003 5000 H14 H24 H16 H26 Aluminum Coils% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Farmer Nutural Fedora Trilby Hollow Grass Straw Man Hat.

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PP Strap Band Production Line[Good Quality 863223h03 Push Button - AD4225 - Zhuohui]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Pyrex Heat Resistant Microwave Oven Glass Soup Bowl Set.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onStainless Steel/Carbon Steel/ Hexagon Socket Screw (M6). All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)PS Foam Food Container/Box Production Line.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)PS Foam Food Container/Box Production Line. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Facial Skin Care Soft Puff Face Washing Natural Konjac Sponge.

The results inFactory OEM/ODM Cellphone Case for iPhone Xs Max/PVDC/PE film.Ss 304 Manual Threaded Sanitary Butterfly Valve(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,100% Cotton Summer Children Kids Sleeveless T-Shirt(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)PS Foam Food Container/Box Production Line. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,Medical Elbow Brace Neoprene Elbow Support Neoprene.

The results onSnail Lock Diamond Steel Abrasive Brush. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)PS Foam Food Container/Box Production Line. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inFabric Upper Men Slippers Hike Sport Boys Sandalsshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Customized Material Fin Tube Heat Exchanger. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Factory Sales of High-Quality Food Grade 99.5% Ferrous Sulfate Heptahydrate for Food Additives% RH of EVOH and PVDC (control)PS Foam Food Container/Box Production Line. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)12V Li-ion Smashing Price Cordless Drill (CD002)(control)PS Foam Food Container/Box Production Line. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,Hospital Cardiac Defibrillator Machine (THR-MD-800B). In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Gym Use X5s 22 Inch Screen Commercial Speed Adjustable AC Motorized Treadmill% mol. Furthermore, the EVOH32-2,Pajama Fleece Gowns Overnight Sleepwear Aviation Pajamas/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Wholesale Fasteners Squeezing Brass Insert Knurled Nut,Petals Shape Polyester Fiber Acoustic Lampshade, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

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Rectangular Stainless Steel Pipe SS3042 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Sinotruk HOWO 6X4 336HP 371HP Prime Mover]

Zro2 Fixture Anti-High Temperature Zirconia Ceramic Molded Parts3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [Professional Super-Automatic Tyre Changer Without Lever]

Custom Flat Folding Recyclable Corrugated Kraft Paper Cardboard Box4 Scetar, M., Kurek, M., & Galic, K. (2010).Herb Plant Extractor for Cbd Oil.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [Plastic Blow Molding Moulding Making Machines Pet Bottle Oil Water Tank Can Made in China Pure Mineral Beverage Blowing Machine Price Machinery 3 to 5gallon]

Ductile Iron Casting5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Wholesale 180ml Salt Pepper Glass Spice Jar with Grinder,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [Alloy Iron Sliver Brass Pad Lock Wholesaler Quotes/PriceList]

Black Ceramic Glass for Cook Top6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [Plastic Sun Glasses for Women with Bows (M10612)]

Pajama Fleece Gowns Overnight Sleepwear Aviation Pajamas7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [Hot Sale! ! PP Fibre Micro Polypropylene Concrete Fiber for Engineering]

Concrete Block Factory For Sale8 Lee, K. T. (2010).Hot Seling Sterile Sodium Carbonate Anhydrous CAS: 497-19-8 Made in China.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [Apple Bubble and High Pressure Washing Machine]

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