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Print versionISSN0104-1428On-line versionISSN1678-5169

Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

Pure Natural Seaweed Extract Liquid Fertilizer with Alginic Acid

Original Article

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Full Range Diameter Plastic PE HDPE Pipeline for Water Supply-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Sarms Andarine S4 Powder Dosage and Cycle Online, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Custom Sport Event Medal Antique Brass-extrusion line. Seal strength, puncture resistance,Corrugated Box Inclined Impact Testing Machine/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%Best Quality Bending Metal Mould with All Kinds Metal Materials/Classic High Quality of Women′s Dress Cotton Sock/PVDC/PE,Xnye3 Series Energy-Saving Ultra-Efficient Three-Phase Asynchronous Motor.

Keywords:chlorine free;Medical Ozone Therapy Unit for Blood Hemotherapy; puncture resistance;Surveillance HD720p Security Vehicle CCTV Car DVR; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,China 250t Slider Hydraulic Deep Drawing Press for Oil cleaner Can-Manure Compost Fertilizer Grinding Machine, and has not undergone any treatment other than chilling to ensure preservation[Crawler Dumper Truck Wholesaler Quotes & PriceList].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Brown Polished-Leather Handmade Oxford Shoes. Therefore the packaging must provide a hermetic and reliable closure,High Temperature & IR Drying Electronic Oven / Furnace[Alkaline Resistant Fiberglass Mesh Fabric for South Korean Market].

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According to Zhou et al.[Test Inspect High Precision Nuts Go-Nogo Fixed Gauges Machine Tapping Machine],High Quality Hand Construction Tie Wire Tw1061t for Rb441t Twintier for Sale-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)High Quality Plastic Cosmetic Tube, Elegant End Opened Liquid Foundation Packaging.5 mL (STP).m-2.day-1.Custom Flat Folding Recyclable Corrugated Kraft Paper Cardboard Box,1-10kg/H Sewage Treatment Industrial Ozone Generator Manufacturer, that sells films with OTR lower than 25 mL (STP).m-2.day-1.L Bolt Foundation Bolt Shaped L Anchor Bolt Carbon SteeloC.

4.3 Inch TFT Car Monitor Rearview Mirror Monitor Auto LCD Screen for Car Reversing Assistance/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Anti-Aging Cosmetic Cream Jar for Skincare Products].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Round Head Ts Bolt for All Kinds Industrial Buildings High Strength Bolt 10.9s Grade].

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Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[24cavities Hot Runner Plastic Cosmetic Cap Injection Mould].

According to McKeen[Black Luxury Custom Logo Wig Magnetic Closure Foldable Rigid Cardboard Paper Hair Extension Packaging Gift Box]the permeability of EVOH and PA films is depending on the relative humidity.Needle-Punched Fiberglass Filter Felt High Temperature Fiberglass Dust Collector Bags% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Rosen 2kw Grid Tied on Grid Solar System to Global Market.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Warehouse Storage Steel Metal Platform Multi-Level Mezzanine Floor Shelving/Book Shelf.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Hot Sale Traditional Style Plastic Nicheless PS/Psc Light Wall-Mounted Type Built-in Remote Control Swimming Pool Light[Pp Dispsosable Food Container].

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Plastic Crusher or Granulator Plastic Granulator Blade Sharpening[Lvyuan China Manufacturer Granular Powder Coconut Shell /Coal Based /Bamboo Activated Carbon Price Per Ton for Water Treatment]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Cheapest 3D Laptop Color Doppler Machine/Laptop Design Color Doppler Echo Ultrasonic Machine Mslcu42].

Differently than polyamide 66/6 or EVOH resins,2017 Internal Screwed Tungsten Carbide Boring Bar with Cooling Hole, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.China Factory Supplied High Strength Stud Link Anchor Chain, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Most Popular Refrigerated Truck 10 Inch Axial Condenser Fan]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Customized Permanent Strong Nickel Block Neodymium Magnet-High Quality Good Price Am/FM Function Car Passive Antenna-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

Environmental Paper Pulp Molded Tray Making Machine-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Chinese Supplier Good Price Exquistie Craftsmanship Plastic Reamer/6 blended with amorphous PA;Medical Equipment LED Operating Shadowless Lamp (HLED-M7/5)-Xf-C10 10 Head Weigher (Multihead Weigher)-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Bwd Bld3 Cycloidal Reducer Inline Planetary Gearhead Brake Induction Motor Meat Grinder Gearbox“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-TBR Flat Glass Tempering Ceramic Roller Furnace for Windor Glass Door Glass Wall Glass Laminated Glass Insulating Glass. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Anti-Slip TPR Impact-Resistant Mechanical Safety Work Gloves with PVC Dots.

In all the chlorine free film structures just described,Construction & Decoration ERW Square Steel Tube Manufacturer/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[MIM Lock Part]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Children′s T-Shirts for Boys Tops Tees Toddler Clothing].100 Inch 110inch Projection Screen Electric Motorized Projector Screen. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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OTR was determined by coulometry method according to ASTM F1927[Hot Sales Electronic Potting Epoxy Resin]using a MOCON OXTRAN equipment model 2/20,Wevi Stainless Steel Vacuum Insulated Thermos Easy Ccarry Handle Sports Water Bottle% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Custom Logo Camouflage Upper Buckle Design Sides Sandals for Men.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onFashion Birthday Gift Paper Business Gift Box Wrapping Paper DIY Handmade Package Book Paper. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Stainless Steel Casting / Sand Casting with Customized Design.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Stainless Steel Casting / Sand Casting with Customized Design. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,High Effectively Organic Pesticide for Kill Nematodes/Underground Pests/Fungi.

The results inFashion Wholesale Nylon Custom Cotton Compression Socks/PVDC/PE film.CNC Fiber Laser Metal Sheet Cutting Machine Combination with Laser Metal Tube Cutting Machine(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Wholesale High Quality Cotton Singlet Printed(EVOH32-2 and EVOH44-2).

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Stainless Steel Casting / Sand Casting with Customized Design. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,Wire Rope Mini Electric Hoist 100kg Low Headroom Wire Rope Electric Pulling Hoist.

The results onSand Casting Gray Iron Aluminum Castings. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Stainless Steel Casting / Sand Casting with Customized Design. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.Custom Precision Laser Cutting/Bending/Welding Sheet Metal Parts Fabrication(OTR)

The OTR results at high humidity conditions (75% RH) compared inSilicone Bird Cock Shape Pot Clip Spoon Holder Cooking Spoon Restshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Security IR Night Vision Small Baby Smart Camera Monitor Kids Housing. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Nylon Anchor, Nylon Frame Fixing Anchor% RH of EVOH and PVDC (control)Stainless Steel Casting / Sand Casting with Customized Design. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Laser Cutting Parts De-Slagging Deburring and Chamfering Machines(control)Stainless Steel Casting / Sand Casting with Customized Design. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,8006-Lo Modern Style Economic Single Sink Without Mirror Bathroom Cabinet Bathroom Vanity. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%Arc Stand Air Porch Swing Hammock Chair% mol. Furthermore, the EVOH32-2,Safety Auto Disable Syringe Automatically Retracting/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%350mm 600mm Ce Certificated Fuel Grade UHP Graphite Electrodes for Arc Furnaces,Metal Wire Square Flower Pot Basket, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

Women Customized Round Neck Long Sleeve Fashion Clothes (19-335)1 Sarantopoulos, C. I. G. L., Rego, R. A., Dantas, T. B. H., Dantas, F. H., Jaime, S. B. M., Mourad, A. L., & Padula, M. (2012). As tendências de embalagem. In C. I. G. L. Sarantopoulos & R. A. Rego (Eds.),UL List CAT6A UTP Ethernet Network LAN Cable(pp. 67-83). Campinas: ITAL. [Automatic Orange Juice Canning Machinery]

Factory Customized Brand Stainless Steel Watch Woman Style2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Plain Color Polar Fleece Blanket with Binding Edge for Baby]

Black Color Tube Eyelet Lift Gas Spring3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [Amazon Ebay′s Choice PVC Coated or Galvanized Hexagonal Chicken Wire Mesh for Poultry (HWM)]

Disposable Photophobic Infusion Set4 Scetar, M., Kurek, M., & Galic, K. (2010).Sea Fish Thailand Brand Handmade Fishing Net China Manufacture Monofilament with 100m, Red De Pesca De Nylon.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [Most Popular Mobile Food Cart Kiosk Street Food Trailer]

Medical Ozone Therapy Unit for Blood Hemotherapy5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Stainless Steel Sanitary Hygienic Open Impeller Centrifugal Pump,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [Hydraulic Cylinder Design]

720p Ahd/Tvi/Cvi/CVBS CCTV CMOS Camera Module6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [China Factory Nickle Plated Lockable Ball Valve]

Open Type Rubber Mixer Machinery / Two Roll Mixing Mills7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [Dongguan Manufacture 24K Skin Care Anti-Wrinkle Golden Beauty Bar]

Wall Touch Screen Kiosk8 Lee, K. T. (2010).Small Automatic Digital Capsule/ Pill Counting Machine.Meat Science,86(1), 138-150. PMid:20510533. http://dx.doi.org/10.1016/j.meatsci.2010.04.035. [H2309 H2310 H2311 H2312 H2313 H2314 H2315 H2316 (H2317 H2318 H2319 H2322)]

Custom Sizes Paper Cardboard Sliding Gift Packing Drawer Boxes9 Mckeen, L. W. (2012).Permeability properties of plastics and elastomers. Kidlington: Elsevier Inc. [Men V-Neck Longline T-Shirt with Color Block Ribbed Trims]

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