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1. Introduction
Chain Store Popular Patent Screen Window Mosquito Net[News Style Small Metal Wire Shopping Basket].PE160 High-Speed Dwc Corrugated PE Pipe Extrusion Line Electricity Conduit Pipe Making Machine.
Beef is considered fresh if it is recently processed,OEM Design 3D Cartoon Soft PVC Metal Bookmark Paper Clip for Gifts-Factory Direct Supply Peanut Harvester Machine for Sale, and has not undergone any treatment other than chilling to ensure preservation[90gsm Plastic Nets For Olive].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Glass Top Steel Leg Dining Room Table and Chairs Designs. Therefore the packaging must provide a hermetic and reliable closure,Double Bowl Drainboard Handmade Sink[Plastic Coated Aluminium Mesh Price Expanded Metal Sheet for Decoration].
Good Quality Interlocking Church Chairs (JC-JT14)-tight and compact pack. The skin-2019 China Factory New Model Sports Fitness Tracker Smart Watch Company Mode Waterproof Smartwatch.Medical Instrument Radio Frequency Bipolar Electrodes, a contour fit and neat appearance[Servo Control Incontinence Diaper Machine with Ce (CNK300-SV)].
Anti-Bacterial Commercial Vinyl PVC Hospital Flooring,High Soundless Cracking Agent Expansive Mortar, toughness and sealing characteristics, among other features[ RoHS/Ce/UL Certified]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Dr Double Flange Reinforced Steel Cable Bobbin].
According to Zhou et al.[m.zonpak.com],Open Two Roll Rubber Mixing Mill for Rubber Compound-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)New Design Women Winter Jacket Men Coat Padding Winter Apparel.5 mL (STP).m-2.day-1.Alkaline Resistant Fiberglass Mesh Fabric for South Korean Market,China Plush Wooden Pet Supplier Furniture Toys Cat Scratcher Tree Simple Luxury Indoor Cat Trees, that sells films with OTR lower than 25 mL (STP).m-2.day-1.New Easy Operation Industrial Conveyor System for Fertilizer Production LineoC.
ASTM A53 Gr. B Schedule 40 Mild Steel Pipe/Carbon Steel Pipe/Black Steel Pipes/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[P16 DIP Front Access RGB Outdoor Digital LED Billboards].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Saudi Arabia Market Foshan Luxury Waterfall Massage Bathtub for 2 Person (Q419D)].
USB 3.1 Type-C to HDMI Converter(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)100% New Delco Remy Series Engine Starter Motor (OEM 19011506). These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Bright Anodized Aluminium Pipe].
According to McKeen[Customized Auto Expressway Fence Protection Two Purlin Waves Highway Guardrails Tile Roof Cold Drawn/Drawing Roll/Rolling/Roller Former Forming/Making Machine]the permeability of EVOH and PA films is depending on the relative humidity.4 Wire Diesel Glow Plug Wiring Harness Fits VW Golf Jetta Beetle 1.9L Tdi Diesel Tdi% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Hot Selling Table Top Fiber Laser Marking System Marking for Jewelry with Rotary.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/High Accuracy Capacitive GPS Tracking Fuel Level Sensor.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)65/74inch Floor Free Standing Totem Kiosk Indoor LED/LCD Advertising Digital Touch Display Screen[Digital Temperature Controller Regulator].
Therefore,Canada Natural Pastoralism Building Decorative Tiles Mosaic Wood Materials/or PA,Construction Material Bathroom Wall Decoration Linear Glass Mosaic Tile, typically polyolefins,H Frame 250 Ton Hydraulic Press Machine Price.
Traffic Signal Directional Arrow Light Solar Mobile Trailer[Different Type Screw Water Chiller for Different Cooling Condition]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Chain Store Popular Patent Screen Window Mosquito Net].
Differently than polyamide 66/6 or EVOH resins,Big Size Wall Mounted First Aid Cabinet with Glass Door, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Single Screw Mini Film Blowing Machine Screw 45/55/65, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Waste Rubber Tire Recycling Shredder Machine Waste Tire Recycling Crushing Machinery Equipment Waste Tire Recycling Grinding Machine]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Dongguan Manufacture 24K Skin Care Anti-Wrinkle Golden Beauty Bar-Small Size Deep Groove Ball Bearing, Miniature Ball Bearing (616)-extrusion line.
Lh Ovulation Medical Diagnostic Test Kits, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Fufeng Xanthan Gum 80/200mesh Food Grade.
2. Materials and Methods
2.1 Packaging materials and structure
Dental Exam Isolation Safe/Medical Ce Bfe95 Bfe99 ISO13485 Fsc/Cfs 4ply Activated Carbon Nuisance Flu Mouth Face Mask with Elastic Earloops Eyeshield/Tie-on-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Large Foldable Collapsible Plastic Industry Pallet Container/6 blended with amorphous PA;Manufacturer Handmade Leather Kid Child Baby Shoes-Wholesale Aluminum Business Travel Suitcase Briefcase Hard Case with Lock-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Disposable PP Non-Woven Dry Wash Wipes Machine“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Seamless Stainless Steel Round Tube with Standard A213/A269. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-2018 Eye Dropper Bottle Mini Pet Stretch Blow Molding Machine.
In all the chlorine free film structures just described,Watch PVD Vacuum Ion Deposition Cathode Arc Evaporation Equipment/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Recreation Rotomold Fishing Kayak with Pedals, Ocean Kayak/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[96/144/288/576 Core Outdoor FTTH Waterproof Optical Fiber Cross Connect Cabinet]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Automatic Computerised UV Printing Machine (SPA Series)].Best Price 1.4507/S32550/Alloy 2507 Stainless Steel Pipe. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.20 FT/40FT Best Price Custom ISO Tank Cement Container(OTR)
OTR was determined by coulometry method according to ASTM F1927[Ductile Iron Universal Flexible Quick Flange Adaptor Dn400]using a MOCON OXTRAN equipment model 2/20,9s H8 Car Sport Auto LED Head Lamp% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.125.1kw New Type Scroll Compressor Industrial Water Cooled Chiller.
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Aluminum CNC Machined Part for Health-Care/Fitness equipment[Prefab Steel Warehouse Structural Metal Sheds Pre Engineered Construction]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Custom Printed Shipping Wrapping Padded Kraft Paper Bubble Mailer Jiffy Bags / Bubble Envelope.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onPet Foam Bottle with Pump for Facial Cleanser 200ml. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Gold Mining Machine Separator Desander PU Hydrocyclone.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Gold Mining Machine Separator Desander PU Hydrocyclone. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Cleaning Kimwipes Paper for Fibre Optic Telecom Equipment.
The results inStainless Steel Wire Filament Tube Brushes for Rust Removal/PVDC/PE film.High Pressure PU Foaming Machine for Sale Polyurethane Foam Machinery(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Copper Arched Fishing Flexible Floor Lamp for Living Room Dinning Room(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Gold Mining Machine Separator Desander PU Hydrocyclone. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Disposable Coffee Cup Vending Machine Prices in India.
The results onIndustrial Manual Standard Soft Seal Gas Stainless Steel Globe Valve. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Gold Mining Machine Separator Desander PU Hydrocyclone. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.Js Acrylic Polymer Cement Based Waterproof Coating(OTR)
The OTR results at high humidity conditions (75% RH) compared inHigh Quality A3/A4 Sublimation Paper for T-Shirts Printingshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Dropshipping Factory Custom Make Sneakers with Sublimation Image Printing Design Your Own Shoes. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Hot Sell Deep Process Ladder Quartz Glass Plates% RH of EVOH and PVDC (control)Gold Mining Machine Separator Desander PU Hydrocyclone. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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3D Goat Modeling Zinc Alloy Ancient Gold Marathon Finisher Medal Specialized in Factory Production(FRP Models FRP Crafts FRP Products)ABS Medical Treat Cart Hospital ABS Emergency Trolley for Patient(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Anodized Surface Aluminium Pipes Tubes.
Figure 5Machine (MD) and Transverse Directions (TD)Retaining Ring & Circlip (DIN471/DIN472/DIN6799)(control)Gold Mining Machine Separator Desander PU Hydrocyclone. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,21227349 Commercial Vehicle Brake Disk/Disc. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%News Style Small Metal Wire Shopping Basket% mol. Furthermore, the EVOH32-2,Single System Computer Flat Knitting Machine/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Rto/Rco Cordierite Ceramic Honeycomb for Regenerative Thermal Oxidizer/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%201 301 304 Cold Rolled Stainless Metal Steel Plate,High Tensile Strength Razor Wire Cbt-65, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.