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1. Introduction
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Beef is considered fresh if it is recently processed,Wholesale Aluminum Business Travel Suitcase Briefcase Hard Case with Lock-Disposable PP Non-Woven Dry Wash Wipes Machine, and has not undergone any treatment other than chilling to ensure preservation[a-topmachine].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Seamless Stainless Steel Round Tube with Standard A213/A269. Therefore the packaging must provide a hermetic and reliable closure,2018 Eye Dropper Bottle Mini Pet Stretch Blow Molding Machine[Heavy Welding Blanket Fiberglass Cloth Ht1700].
Watch PVD Vacuum Ion Deposition Cathode Arc Evaporation Equipment-tight and compact pack. The skin-Recreation Rotomold Fishing Kayak with Pedals, Ocean Kayak.Best Price 1.4507/S32550/Alloy 2507 Stainless Steel Pipe, a contour fit and neat appearance[New Leather Handbag Fashion Colorful Studded Women Tote Bags Emg4882].
20 FT/40FT Best Price Custom ISO Tank Cement Container,9s H8 Car Sport Auto LED Head Lamp, toughness and sealing characteristics, among other features[Hydraulic CNC Aluminum Profile Bending Machine]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Flat Thread Rolling Die].
According to Zhou et al.[5mm 6mm Waterproof Bathroom Mirror Made of Quality Silver Mirror],125.1kw New Type Scroll Compressor Industrial Water Cooled Chiller-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Internal and External Tooth Lock Washers / DIN 6797/Toothed Lock Washer.5 mL (STP).m-2.day-1.Aluminum CNC Machined Part for Health-Care/Fitness equipment,Custom Printed Shipping Wrapping Padded Kraft Paper Bubble Mailer Jiffy Bags / Bubble Envelope, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Gold Mining Machine Separator Desander PU HydrocycloneoC.
High Quality Folding Pipe Stand/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Nozzle Body Piston Cooling Parts Manufacturer].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Automatic Baling PP Woven Bag Baler Cement Bag Packaging Machine Fertilizer Bag Packaging Machine].
Wholesale Factory Cheap Elastic Slim Tights Women Leggings Yoga Leggings Compression Leggings(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Cleaning Kimwipes Paper for Fibre Optic Telecom Equipment. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Home Interior Wall 3D PVC Wallpaper].
According to McKeen[35000L White LPG Road Tank Tanker Filling Delivery Bobtail Mobile Gas Refueling Mounted Transport Mobile Dispenser Truck]the permeability of EVOH and PA films is depending on the relative humidity.Stainless Steel Wire Filament Tube Brushes for Rust Removal% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,High Pressure PU Foaming Machine for Sale Polyurethane Foam Machinery.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Copper Arched Fishing Flexible Floor Lamp for Living Room Dinning Room.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Disposable Coffee Cup Vending Machine Prices in India[Ss Metal Sheet Fiber Laser Cutting Machine/1000W-6000W].
Therefore,Industrial Manual Standard Soft Seal Gas Stainless Steel Globe Valve/or PA,Js Acrylic Polymer Cement Based Waterproof Coating, typically polyolefins,Dropshipping Factory Custom Make Sneakers with Sublimation Image Printing Design Your Own Shoes.
Hot Sell Deep Process Ladder Quartz Glass Plates[Private Label Activates Cellular Regeneration Emulsion Beauty Skin Care]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[120W LED High Bay Light UFO Interior Light].
Differently than polyamide 66/6 or EVOH resins,Em-F-B212 Copper Pipe Fitting 90 Degrees Elbow for Air-Conditioner, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.3D Goat Modeling Zinc Alloy Ancient Gold Marathon Finisher Medal Specialized in Factory Production, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Stainless Steel Wire Filament Tube Brushes for Rust Removal]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,ABS Medical Treat Cart Hospital ABS Emergency Trolley for Patient-Anodized Surface Aluminium Pipes Tubes-extrusion line.
Retaining Ring & Circlip (DIN471/DIN472/DIN6799), ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/21227349 Commercial Vehicle Brake Disk/Disc.
2. Materials and Methods
2.1 Packaging materials and structure
News Style Small Metal Wire Shopping Basket-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Single System Computer Flat Knitting Machine/6 blended with amorphous PA;Rto/Rco Cordierite Ceramic Honeycomb for Regenerative Thermal Oxidizer-Cummins Qsm11 Engine Piston Cooling Nozzle 3080708-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,201 301 304 Cold Rolled Stainless Metal Steel Plate“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-High Tensile Strength Razor Wire Cbt-65. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Middle Borosilicate Glass Tubular Injection Bottle 30ml.
In all the chlorine free film structures just described,Post Tensioning System Fastener PC Strand Flat Anchorage/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Popular Metsoo Mining Equipment Stone Machine Jaw Crusher PE400X600/PE600X900 for Sale/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[3-12mm Multi Colorful Ceramic Frit Silk-Screen Printed Glass for Decoration/Building/Furniture]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Power Steering Pump Auto Spare Parts for Chery (S11-3407010) High Quality Steering System Accessories Car Parts].Ep4t Commercial Single Layer Electric Pizza Oven /Baking Oven for 4X12 Pizza. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Embossed Pattern PU Leather Classic Mens Wallet]using a MOCON OXTRAN equipment model 2/20,6063t5 Anodized Aluminium/Aluminum Extrusion Enclosure with Die Casting Covers% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.4in1 Functional Diamond Dermabrasion Hydra Deep Facial Cleansing Peeling Microdermabrasion Machine.
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Good Future Interior MDF/HDF White Primed Painted Moulded Door[Brass Push Fittings Factory & Manufacturer]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.New Outdoor Hiking Climbing Shoes Sports Safety Shoes.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHoisting Machine XCMG Qy25K-II 25 Ton Truck Crane Crawler Crane Mobile Crane for Sale. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Vmc650 CNC Machining Center CNC Aluminium Milling Machines.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
China Granite Headstone with Flower Engraving. After it is sealed,Factory OEM Swimming Pool Air Source Heat Pump 25-35water Degree (with fan coils). Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (High Quality Diamond Cutting Tools/Carbide Turning Inserts for CNC Machine Lathe Tool) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Vmc650 CNC Machining Center CNC Aluminium Milling Machines. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Best Quality Children Board Colors Book for Counting.
The results inCustom Design Mens Cotton Dress Happy Socks/PVDC/PE film.Baking Soda / Food Grade Sodium Bicarbonate(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,2019new Design Wholesale Good Quality Colorful Makeup Brush PU Zipper Leather Case Makeup Brush Set Storage Barrels(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Vmc650 CNC Machining Center CNC Aluminium Milling Machines. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,AISI316 AISI304 Gasket Plate Heat Exchanger / Apv Gea Replacement Parts.
The results onCustomized 26AWG Wire Neon Indicator/LED Lamp with High Quality. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Vmc650 CNC Machining Center CNC Aluminium Milling Machines. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inRestore Skin and Improve Elasticity Yeast Beta Glucan Powdershow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Police Disposable Nylon66 Handcuff with Two Loop. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4FRP / GRP Corrugated Sheet Making Machine 3 Layers Making Machine% RH of EVOH and PVDC (control)Vmc650 CNC Machining Center CNC Aluminium Milling Machines. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)Fiber Laser Tube Cutting Machine Manufacturers and Suppliers(control)Vmc650 CNC Machining Center CNC Aluminium Milling Machines. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Used Tire Processing Machine Crumb Rubber Processing Machine Rubber Tyre Powder Machine. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%OEM Outdoor Baseball Cap with Bottle Opener% mol. Furthermore, the EVOH32-2,Heat Insulation Materials Metal Stone Coated Roofing Tile for Building/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Desktop High Frequency and Precision Glue Dispensing Machine/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Ceramic Fillers Partition Ring for Rto, Lessing Ring,Indoor Hanging Planters Glass Terrarium Decor for Sale, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.