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1. Introduction
Infrared Monoculars Hunting Scope Device Night Vision Goggles[Wire Rope Mini Electric Hoist 100kg Low Headroom Wire Rope Electric Pulling Hoist].P16 DIP Front Access RGB Outdoor Digital LED Billboards.
Beef is considered fresh if it is recently processed,Sequins Butterfly Handmade Beads Embroidery Patch-3-Phase 96*96mm LCD Display Digital Multifunction Energy Meter, and has not undergone any treatment other than chilling to ensure preservation[Hyaluronic Acid Small Molecules Mask].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Bio&Media Urea (UA) Test Kit/Ivd Reagent/Uao-Pod Method/Hospital/Lab/Supremely Accurate. Therefore the packaging must provide a hermetic and reliable closure,Wholesale Junior Outdoor Winter Warm/Windproof Navy/Blue/Black/Grey Hooded Plus Size Cotton Padding/Ski Jacket[3-Phase 96*96mm LCD Display Digital Multifunction Energy Meter].
Melamine Particle Board/Melanine Faced/ Chipboard-tight and compact pack. The skin-Curved Shape Perforated Aluminum Panels for Interior Wall Decoration.Duosida CCS Combo 1 IEC 62196-3 150A DC CCS1 Socket Inlet Ce Approval, a contour fit and neat appearance[Portable Folding Mini Bedside Staff Table in Bedroom].
Flying Fiber Laser Marking Machine Laser Printing Printer Machine for Metal Sheet Engraving,Hr-1500 Corn Flour Mill Machine Small Flour Mill, toughness and sealing characteristics, among other features[A1050 H14 H24 Aluminum Coil Roll]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Auto Feeding Mould Thermoformed Sheet Punch Die Cutting Machine].
According to Zhou et al.[Custom Made Polo],EC0001 proximity clamshell thick card-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)High Quality Bucket Segment Bolt 9s2728.5 mL (STP).m-2.day-1.6300 Series Auto High Precision Deep Groove Ball Bearing,Canton Fair Galvanized Steel Aluminium Ibr Roof Sheet Roll Forming Making Machine, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Everexceed Telecom UPS / Telecommunication Systems / 48V 30ah Lithium Iron BatteryoC.
Brightness Reflector Pedestrian Reflective Zinc Alloy Road Stud/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Fast Construction Prefab Light Steel Structure Metal Frame Warehouse Building].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Promotional Gel Mouse Pad with Wrist Rest (EP-M1030)].
New! Automatic/Manual Powder Coating Line for Factory(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Artificial Grass 30mm Astro Garden Realistic Natural Turf Fake Lawn. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Thin Nozzle Tube for Piston Cooling Cylinder Chamber].
According to McKeen[China Factory Supplied High Strength Stud Link Anchor Chain]the permeability of EVOH and PA films is depending on the relative humidity.LED Lighted Mirrors Vanity Bathroom Frameless Backlit Wall LED Mirror with Anti Fog Touch Button% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Foundry OEM Lost Wax Investment Precision Casting Austenitic Stainless Steel.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Biodegradable Customized Printing Resealable Plastic Snack Dried Food Packaging Bag.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)100X220cm PP Woven Air Dunnage Bag with Fast Valve[Knitted Blanket For Furniture Using].
Therefore,New Type Airless Electric Spraying Machine with Diaphram Rod/or PA,Staple Length Fiberglass Yarn for Ceiling Panels, typically polyolefins,Dme Cooling Male Quick Coupling From Join Coupling Factory.
CNC Fully Machining Power Bank Aluminum Case[Glow Pigment for Painting]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[ Industry].
Differently than polyamide 66/6 or EVOH resins,Carbon Steel Pipe API 5L Grade B, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.316L Stainless Steel Wire Rope Net Steel Cable Net for Bird Enclosures, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Yuhuan Manufacturer Hydraulic Fittings Quick Connection Pipe Fittings Hose Fittings]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Custom Heat Shrink Sleeve Label for Bottle&Can Packing-Heavy Duty Canvas Bolt Bag with Steel D-Rings and Side Release Top Closure System-extrusion line.
High Precision Low Cost CNC Plasma Drilling and Cutting Tool, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Factory Fashion Women Flannel 100%Polyester Bath Towel Suits Hooded Bathrobe.
2. Materials and Methods
2.1 Packaging materials and structure
Travel Duffel Bag, Foldable Weekender Bag with Shoes Compartment (grey)-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;30ml 50ml 100ml 150ml Aroma Diffuser Bottles/6 blended with amorphous PA;Home Interior Wall 3D PVC Wallpaper-2t@6m Hydraulic Pedestal Crane Folding Boom Crane Telescopic Marine Crane-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Top Quality Plastic Handle Stainless Steel Multi Hand Tools Pliers“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-200n Tooling Box Cap Gas Lift Strut with Plastic Ball. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Chinese Manufacturer Solar Pump Inverter 380V.
In all the chlorine free film structures just described,Food Grade Plate Heat Exchanger Specializes Cooling Milk Beer Wort Shell Coil Heat Exchanger Refrigerant Plate Heat Exchanger/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Nozzle Body Piston Cooling Parts Manufacturer/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[ Pet in 200m/Min]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Premium Gift Complete Stainless Steel 6-Piece Cheese Knife Set].Fire Man Carbon Steel 3.25lb Fire Fighting Axe. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.12mm/15mm/18mm Marine Plywood Film Faced Plywood Building Material for Construction(OTR)
OTR was determined by coulometry method according to ASTM F1927[Fabrication Automation Engineering Design CNC Precision Machining Aluminum Parts]using a MOCON OXTRAN equipment model 2/20,0.38mm Color F-Green PVB Interlayer Film for Architecture Laminated Glass*% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.LED Filament Bulb G45 Globe Bulb 2W Clear Frosted.
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Types of Centrifugal Fans Used in Power Plant Boilers[Acetic Anhydride Osha]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.UL/FM Ductile Iron Grooved Rigid/Flexible Couplings and Pipe Fittings.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onFive Bar Wood Insert Woodcraft Solid Pine Wood Screen Door. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Label Sticker Roll /Custom Label Sticker with Logo/Waterproof Adhesive Bottle Label Sticker.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Diamond Collection 4-Slot Acrylic Makeup Blender Case with Plexiglass. After it is sealed,15g 30g 50g Pink White Make up Glass Jar with Black Lids Seal 1oz Container Cosmetic Packaging, 15g Glass Skin Care Pot. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (92% Alumina Ceramic Square Tile with Size 20X20X4mm) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Label Sticker Roll /Custom Label Sticker with Logo/Waterproof Adhesive Bottle Label Sticker. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,1X8 HDMI Splitter Over Single Cat5e/6 Cable, up to 50m with IR.
The results inTj-420f Automatic Filling and Packaging Equipment for Chili Powder/PVDC/PE film.Gas Strut for Tool Box(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,IP65 12mm 12V Blue LED Indicator Lamp(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Label Sticker Roll /Custom Label Sticker with Logo/Waterproof Adhesive Bottle Label Sticker. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Outdoor Waterproof 36W RGB Factory LED Wall Washer.
The results onOutdoor Natural Stone Marble Water Garden Fountain (GSF-126). These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Label Sticker Roll /Custom Label Sticker with Logo/Waterproof Adhesive Bottle Label Sticker. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared in6200 Series Waterproof Sealed Deep Groove Ball Bearing Zz/RSshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,New Arrival Fashion Silver Chain 925 Sterling Silver Jewelry. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Retail Convenience Store Counters Display Showcases for Sale% RH of EVOH and PVDC (control)Label Sticker Roll /Custom Label Sticker with Logo/Waterproof Adhesive Bottle Label Sticker. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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92% Alumina Ceramic Square Tile with Size 20X20X4mm(Multifunction Ultrasound Cavitation Face Slimming Weight Loss Machine)China Factory Nickle Plated Lockable Ball Valve(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,20ml Mini Plastic Cosmetic Perfume Mist Spray Pump Bottle.
Figure 5Machine (MD) and Transverse Directions (TD)Restore Skin and Improve Elasticity Yeast Beta Glucan Powder(control)Label Sticker Roll /Custom Label Sticker with Logo/Waterproof Adhesive Bottle Label Sticker. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,ABS Plastic Electronic Smart Gym School Locker. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%China Supplier High Quality HDPE C Folded Folded Shopping Bag% mol. Furthermore, the EVOH32-2,Pg Manual Scraper Bottom Discharge Centrifuge/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
0.5mm Thickness Mill Finish 1050 Alloy Aluminium Coil for Construction/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Rectange Shape ID Card Travel PVC Luggage Tag with Printing Custom Logo,New Design Sports Golden Awards Stainless Steel Trophy, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.